16,233 research outputs found
GaAs(111)A and B in hydrazine sulfide solutions : extreme polarity dependence of surface adsorption processes
Chemical bonds formed by hydrazine-sulfide treatment of GaAs(111) were
studied by synchrotron photoemission spectroscopy. At the B surface, the top
arsenic atoms are replaced by nitrogen atoms, while GaAs(111)A is covered by
sulfur, also bonded to underlying gallium, despite the sulfide molar
concentration being 103 times smaller than that of the hydrazine. This extreme
dependence on surface polarity is explained by competitive adsorption processes
of HS- and OH- anions and of hydrazine molecules, on Ga- adsorption sites,
which have distinct configurations on the A and B surfaces
Formation of van der Waals molecules in buffer gas cooled magnetic traps
We show that a large class of helium-containing cold polar molecules form
readily in a cryogenic buffer gas, achieving densities as high as 10^12 cm^-3.
We explore the spin relaxation of these molecules in buffer gas loaded magnetic
traps, and identify a loss mechanism based on Landau-Zener transitions arising
from the anisotropic hyperfine interaction. Our results show that the recently
observed strong T^6 thermal dependence of spin change in buffer gas trapped
silver (Ag) is accounted for by the formation and spin change of AgHe, thus
providing evidence for molecular formation in a buffer gas trap.Comment: 4 pages, 4 figure
Collaboration and contestation in further and higher education partnerships in England: a Bourdieusian field analysis
Internationally, âCollege for Allâ policies are creating new forms of vocational higher education (HE), and shifting relationships between HE and further education (FE) institutions. In this paper, we consider the way in which this is being implemented in England, drawing on a detailed qualitative case study of a regional HEâFE partnership to widen participation. We focus on the complex mix of collaboration and contestation that arose within it, and how these affected socially differentiated groups of students following high- and low-status routes through its provision. We outline Bourdieuâs concept of âfieldâ as a framework for our analysis and interpretation, including its theoretical ambiguities regarding the definition and scale of fields. Through hermeneutic dialogue between data and theory, we tentatively suggest that such partnerships represent bridges between HE and FE. These bridges are strong between higher-status institutions, but highly contested between lower-status institutions competing closely for distinction. We conclude that the trajectories and outcomes for socially disadvantaged students require attention and collective action to address the inequalities they face, and that our theoretical approach may have wider international relevance beyond the English case
L\'evy-type diffusion on one-dimensional directed Cantor Graphs
L\'evy-type walks with correlated jumps, induced by the topology of the
medium, are studied on a class of one-dimensional deterministic graphs built
from generalized Cantor and Smith-Volterra-Cantor sets. The particle performs a
standard random walk on the sets but is also allowed to move ballistically
throughout the empty regions. Using scaling relations and the mapping onto the
electric network problem, we obtain the exact values of the scaling exponents
for the asymptotic return probability, the resistivity and the mean square
displacement as a function of the topological parameters of the sets.
Interestingly, the systems undergoes a transition from superdiffusive to
diffusive behavior as a function of the filling of the fractal. The
deterministic topology also allows us to discuss the importance of the choice
of the initial condition. In particular, we demonstrate that local and average
measurements can display different asymptotic behavior. The analytic results
are compared with the numerical solution of the master equation of the process.Comment: 9 pages, 9 figure
A Titanium Nitride Absorber for Controlling Optical Crosstalk in Horn-Coupled Aluminum LEKID Arrays for Millimeter Wavelengths
We discuss the design and measured performance of a titanium nitride (TiN)
mesh absorber we are developing for controlling optical crosstalk in
horn-coupled lumped-element kinetic inductance detector arrays for
millimeter-wavelengths. This absorber was added to the fused silica
anti-reflection coating attached to previously-characterized, 20-element
prototype arrays of LEKIDs fabricated from thin-film aluminum on silicon
substrates. To test the TiN crosstalk absorber, we compared the measured
response and noise properties of LEKID arrays with and without the TiN mesh.
For this test, the LEKIDs were illuminated with an adjustable, incoherent
electronic millimeter-wave source. Our measurements show that the optical
crosstalk in the LEKID array with the TiN absorber is reduced by 66\% on
average, so the approach is effective and a viable candidate for future
kilo-pixel arrays.Comment: 7 pages, 5 figures, accepted for publication in the Journal of Low
Temperature Physic
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