Efficient, robust surface functionalization and stabilization of gold nanorods with quaternary ammonium-containing ionomers as multidentate macromolecular ligands

Surface functionalization of gold nanorods (GNRs) is critical to their applications in various fields. While there are several existing strategies, we report in this article a new general strategy for the surface functionalization of GNRs with quaternary ammonium-containing ionomers as a novel class of multidentate macromolecular surface ligands. A range of tetralkylammoniumcontaining hyperbranched polyethylene- and linear poly(n-butyl acrylate)-based ionomers has been specifically designed and employed in the strategy. Acting as multidentate macromolecular analogues of cetyltrimethylammonium bromide (CTAB), the ionomers have been demonstrated to bind onto the GNR surface by displacing the surface-bound CTAB species via ligand exchange to render CTAB-free ionomer-modified GNRs. By properly designing the enabling ionomers, we have shown that the modified GNRs can be endowed with some desired properties, such as excellent dispersibility in various organic solvents, robust stability under multiple rounds (up to 12 investigated) of high-speed centrifugation in organic solvents, amphiphilicity with dispersibility in both aqueous and organic media, fluorescence, and capability in carrying hydrophobic guest species. This strategy thus provides potential new ways for the construction of novel multifunctional GNR nanocomposites

Impact of Climate Change on Hydrologic Extremes in the Upper Basin of the Yellow River Basin of China

To reveal the revolution law of hydrologic extremes in the next 50 years and analyze the impact of climate change on hydrologic extremes, the following main works were carried on: firstly, the long duration (15 d, 30 d, and 60 d) rainfall extremes according to observed time-series and forecast time-series by dynamical climate model product (BCC-CSM-1.1) were deduced, respectively, on the basis that the quantitative estimation of the impact of climate change on rainfall extremes was conducted; secondly, the SWAT model was used to deduce design flood with the input of design rainfall for the next 50 years. On this basis, quantitative estimation of the impact of climate change on long duration flood volume extremes was conducted. It indicates that (1) the value of long duration rainfall extremes for given probabilities (1%, 2%, 5%, and 10%) of the Tangnaihai basin will rise with slight increasing rate from 1% to 6% in the next 50 years and (2) long duration flood volume extremes of given probabilities of the Tangnaihai basin will rise with slight increasing rate from 1% to 6% in the next 50 years. The conclusions may provide technical supports for basin level planning of flood control and hydropower production

Direct structural identification of carbenium ions and investigation of host-guest interaction in the methanol to olefins reaction obtained by multinuclear NMR correlations

Probing and determining the intermediates formed during catalytic reactions in heterogeneous catalysis are strong challenges. Using C-13 labelling and two dimensional C-13-C-13 through-bond NMR correlations, we directly reveal the structures of a range of carbenium ion species formed during the conversion of methanol to olefins on acidic H-ZSM-5 zeolite by mapping the carbon-carbon bond connectivities. Additionally, we use C-13-Al-27 and Si-29-C-13 through-space NMR experiments to probe the interactions between the confined carbon species (including carbenium ions) and the framework of the zeolite, which quantitatively provide an estimate for the carbon-aluminium and carbon-silicon distances, respectively

The Promotion of Mechanical Properties by Bone Ingrowth in Additive-Manufactured Titanium Scaffolds

Although the initial mechanical properties of additive-manufactured (AM) metal scaffolds have been thoroughly studied and have become a cornerstone in the design of porous orthopaedic implants, the potential promotion of the mechanical properties of the scaffolds by bone ingrowth has barely been studied. In this study, the promotion of bone ingrowth on the mechanical properties of AM titanium alloy scaffolds was investigated through in vivo experiments and numerical simulation. On one hand, the osseointegration characteristics of scaffolds with architectures of body-centred cubic (BCC) and diamond were compared through animal experiments in which the mechanical properties of both scaffolds were not enhanced by the four-week implantation. On the other hand, the influences of the type and morphology of bone tissue in the BCC scaffolds on its mechanical properties were investigated by the finite element model of osseointegrated scaffolds, which was calibrated by the results of biomechanical testing. Significant promotion of the mechanical properties of AM metal scaffolds was only found when cortical bone filled the pores in the scaffolds. This paper provides a numerical prediction method to investigate the effect of bone ingrowth on the mechanical properties of AM porous implants, which might be valuable for the design of porous implants

Choice of hydrogen uptake (Hup) status in legume-rhizobia symbioses

Publisher's Version/PDFThe H2 is an obligate by-product of N-fixation. Recycling of H2 through uptake hydrogenase (Hup) inside the root nodules of leguminous plants is often considered an advantage for plants. However, many of the rhizobium-legume symbioses found in nature, especially those used in agriculture are shown to be Hup− , with the plants releasing H2 produced by nitrogenase activity from root nodules into the surrounding rhizosphere. Recent studies have suggested that, H2 induces plant-growth-promoting rhizobacteria, which may explain the widespread of Hup− symbioses in spite of the low energy efficiency of such associations. Wild legumes grown in Nova Scotia, Canada, were surveyed to determine if any plant-growth characteristics could give an indication of Hup choice in leguminous plants. Out of the plants sampled, two legumes, Securigera varia and Vicia cracca, showed Hup+ associations. Securigera varia exhibited robust root structure as compared with the other plants surveyed. Data from the literature and the results from this study suggested that plants with established root systems are more likely to form the energy-efficient Hup+ symbiotic relationships with rhizobia. Conversely, Hup− associations could be beneficial to leguminous plants due to H2-oxidizing plant-growth-promoting rhizobacteria that allow plants to compete successfully, early in the growing season. However, some nodules from V. cracca tested Hup+, while others were Hup−. This was similar to that observed in Glycine max and Pisum sativum, giving reason to believe that Hup choice might be affected by various internal and environmental factors

Response of cucumber to timing of fertilizer application in southwest Nigeria

Publisher's version/PDFA field trial was conducted at the experimental farm of the Department of Crop Protection and Environmental Biology, University of Ibadan, Nigeria, to determine the growth and yield response of cucumber (cv. Poinsett) to timing of fertilizer application. Fertilizer (20:10:10), at the rate of 150 kg N ha[superscript–1], was applied at: planting, 3 weeks after planting (WAP) and 6 WAP. Similarly, split applications were given at planting + 3 WAP, at planting + 6 WAP and at 3 WAP + 6 WAP. The experimental design was a randomized complete block with seven treatments (six fertilizer application treatments plus a non fertilizer control) and four replications. Means were separated using Duncan’s Multiple Range Test at the 5% level of significance. In general, plants that were fertilized performed better than control plants in terms of vegetative growth and yield. A split application at 3 WAP + 6 WAP performed the best in terms of vegetative growth and fruit yield. Fertilizer applied once-over at 6 WAP was the least beneficial; application of fertilizer once-over at planting, or a split application at planting + 3 WAP, resulted in a high level of vegetative growth but lower fruit yield compared with the split application at 3 WAP + 6 WAP

Fast detection and structural identification of carbocations on zeolites by dynamic nuclear polarization enhanced solid-state NMR

Acidic zeolites are porous aluminosilicates used in a wide range of industrial processes such as adsorption and catalysis. The formation of carbocation intermediates plays a key role in reactivity, selectivity and deactivation in heterogeneous catalytic processes. However, the observation and determination of carbocations remain a significant challenge in heterogeneous catalysis due to the lack of selective techniques of sufficient sensitivity to detect their low concentrations. Here, we combine 13C isotopic enrichment and efficient dynamic nuclear polarization magic angle spinning nuclear magnetic resonance spectroscopy to detect carbocations in zeolites. We use two dimensional 13C–13C through-bond correlations to establish their structures and 29Si–13C through-space experiments to quantitatively probe the interaction between multiple surface sites of the zeolites and the confined hydrocarbon pool species. We show that a range of various membered ring carbocations are intermediates in the methanol to hydrocarbons reaction catalysed by different microstructural β-zeolites and highlight that different reaction routes for the formation of both targeted hydrocarbon products and coke exist. These species have strong van der Waals interaction with the zeolite framework demonstrating that their accumulation in the channels of the zeolites leads to deactivation. These results enable understanding of deactivation pathways and open up opportunities for the design of catalysts with improved performances

Improvement of affine iterative closest point algorithm for partial registration

In this study, partial registration problem with outliers and missing data in the affine case is discussed. To solve this problem, a novel objective function is proposed based on bidirectional distance and trimmed strategy, and then a new affine trimmed iterative closest point algorithm is given. First, when bidirectional distance measurement is applied, the ill‐posed partial registration problem in the affine case is prevented. Second, the overlapping percentage is solved by using trimmed strategy which uses as many correct overlapping points as possible. The authors’ method computes the affine transformation, correspondence and overlapping percentage automatically at each iterative step. In this way, it handles partially overlapping registration with outliers and missing data in the affine case well. Experimental results demonstrate that their method is more robust and precise than the state‐of‐the‐art algorithms. It also has good convergence and similar running time with traditional algorithms