Combining phosphate species and stainless steel cathode to enhance hydrogen evolution in microbial electrolysis cell (MEC)

Microbial electrolysis cells (MEC) must work around neutral pH because of microbial catalysis at the anode. To develop a hydrogen evolution cathode that can work at neutral pH remains a major challenge in MEC technology. Voltammetry performed at pH 8.0 on rotating disk electrodes showed that the presence of phosphate species straightforwardly multiplied the current density of hydrogen evolution, through the so-called cathodic deprotonation reaction. The mechanism was stable on stainless steel cathodes whereas it rapidly vanished on platinum. The phosphate/stainless steel system implemented in a 25 L MEC with a marine microbial anode led to hydrogen evolution rates of up to 4.9 L/h/m2 under 0.8 V voltage, which were of the same order than the best performance values reported so far. Keywords: Hydrogen; Microbial electrolysis cell (MEC); Stainless steel; Phosphat

State-of-the-art all-silicon sub-bandgap photodetectors at telecom and datacom wavelengths

Silicon-based technologies provide an ideal platform for the monolithic integration of photonics and microelectronics. In this context, a variety of passive and active silicon photonic devices have been developed to operate at telecom and datacom wavelengths, at which silicon has minimal optical absorption - due to its bandgap of 1.12 eV. Although in principle this transparency window limits the use of silicon for optical detection at wavelengths above 1.1 μm, in recent years tremendous advances have been made in the field of all-silicon sub-bandgap photodetectors at telecom and datacom wavelengths. By taking advantage of emerging materials and novel structures, these devices are becoming competitive with the more well-established technologies, and are opening new and intriguing perspectives. In this paper, a review of the state-of-the-art is presented. Devices based on defect-mediated absorption, two-photon absorption and the internal photoemission effect are reported, their working principles are elucidated and their performance discussed and compared

The Living Rainforest Sustainable Greenhouses

The Living Rainforest (www.livingrainforest.org) is an educational charity that uses rainforest ecology as a metaphor for communicating general sustainability issues to the public. Its greenhouses and office buildings are to be renovated using the most sustainable methods currently available. This will be realised through construction of a high insulating greenhouse covering with a k-value of less than 2 Wm-2K-1, passive seasonal storage of excess summer solar energy in the ground by a ground source heat exchanger and exploitation of this low grade solar energy for heating in winter by a heat pump. In winter the heat pump will produce cold water to cool the ground allowing a passive cooling function in summer via the GSHE. It will be demonstrated that a GSHE is an alternative for an open aquifer in regions with no aquifer availability. The heat pump will deliver the heating baseload, the peak load will be delivered by a biomass boiler, fired with locally-sourced low-cost wood chips. It is expected that the energy saving will be about 75%, resulting in a major cost reduction. The low k-value of the covering is linked to a light transmission of 75 %. This is high enough for the demands of the vegetation in The Living Rainforest. Because the inner greenhouse climate demands are comparable to that of ornamentals, the results will be applicable to commercial ornamental production. In future low k-value coverings will also be available with high light transmission, allowing wider application of the results. This paper focuses on the correlation between k-value, light transmission and energy demand in order to investigate the trade-off between light transmittance (a major energy gain) and heat loss. The effects of these design parameters on storage and harvesting capacity are also considered but appear to have a low sensitivity. The renovated greenhouse site at The Living Rainforest will show that new greenhouses and ecology can be linked to sustainability and this will be communicated and demonstrated to the public

An operational semantics for a fragment of PRS

The Procedural Reasoning System (PRS) is arguably the first implementation of the Belief–Desire–Intention (BDI) approach to agent programming. PRS remains extremely influential, directly or indirectly inspiring the development of subsequent BDI agent programming languages. However, perhaps surprisingly given its centrality in the BDI paradigm, PRS lacks a formal operational semantics, making it difficult to determine its expressive power relative to other agent programming languages. This paper takes a first step towards closing this gap, by giving a formal semantics for a significant fragment of PRS. We prove key properties of the semantics relating to PRS-specific programming constructs, and show that even the fragment of PRS we consider is strictly more expressive than the plan constructs found in typical BDI languages

Unavoidable Higgs coupling deviations in the Z2Z_2-symmetric Georgi-Machacek model

The $Z_{2}$-symmetric version of the Georgi-Machacek model does not possess a decoupling limit in which all the new particles can be made arbitrarily heavy, opening the possibility that the model can be entirely excluded if experiments reveal no deviations from the Standard Model. We explore this model, focusing on the part of parameter space in which the vacuum expectation value of the triplets, $\nu_\chi$, is small. In the small-$\nu_\chi$ limit, the second custodial-singlet scalar field $S$ necessarily becomes very light and can contribute to the total width of the 125 GeV Higgs boson $h$ via $h \to SS$. We show that this process, together with LHC measurements of the $h \to \gamma\gamma$ rate, entirely excludes masses $m_S < m_h/2$ and thereby severely constrains the parameter space, setting an experimental lower bound $\nu_\chi \gtrsim 12.5$ GeV on the vacuum expectation value of the triplets. This lower bound makes it impossible to avoid deviations from the Standard Model in the couplings of $h$ to fermion and vector boson pairs. We study the remaining parameter space after imposing constraints from direct searches for the additional Higgs bosons, and show that it is on the edge of being fully excluded at $95\%$ confidence level by LHC measurements of the 125 GeV Higgs boson's couplings. Measurements of these couplings at the future high-luminosity run of the LHC will have sufficient precision to entirely exclude the model at $5\sigma$ if no deviations from the Standard Model are observed.Comment: 30 pages, 11 figure

BDI agent architectures: A survey

The BDI model forms the basis of much of the research on symbolic models of agency and agent-oriented software engineering. While many variants of the basic BDI model have been proposed in the literature, there has been no systematic review of research on BDI agent architectures in over 10 years. In this paper, we survey the main approaches to each component of the BDI architecture, how these have been realised in agent programming languages, and discuss the trade-offs inherent in each approach

Can CP be conserved in the two-Higgs-doublet model?

We study the conditions under which the CP violation in the quark mixing matrix can leak into the scalar potential of the real two-Higgs-doublet model (2HDM) via divergent radiative corrections, thereby spoiling the renormalizability of the model. We show that any contributing diagram must involve 12 Yukawa-coupling insertions and a factor of the $U(1)_{PQ}$-breaking scalar potential parameter $\lambda_5$, thereby requiring at least six loops; this also implies that the 2HDM with only softly-broken $U(1)_{PQ}$ is safe from divergent leaks of CP violation to all orders. We demonstrate that additional symmetries of the six-loop diagrams in the type I and II 2HDMs guarantee that all of the divergent CP-violating contributions cancel at this order. We also show that these symmetries are violated at seven loops and enumerate the classes of diagrams that can contribute to CP-violating divergences, providing evidence that the real 2HDM is theoretically inconsistent starting at the seven-loop level.Comment: 27 pages, 14 figure

Food Access in Petersburg, Virginia: Final Report and Recommendations

The City of Petersburg has long suffered with issues of limited access to food and food insecurity. Food deserts, or areas underserved by retail food options, are prevalent throughout the City. As a result, the Robert Wood Johnson Foundation has ranked the city last of Virginia\u27s 133 counties in their annual health rankings. For the Fall 2019 semester, students from Virginia Commonwealth University\u27s L. Douglas Wilder School of Government and Public Affairs, through Dr. John Accordino\u27s Urban Commercial Revitalization course, focused on planning solutions to address food deserts in commercial areas, with the City of Petersburg being one of their clients. The class assessed the potential for commercial revitalization and made five recommendations

When stuff gets old: material surface characteristics and the visual perception of material change over time

YesMaterials’ surfaces change over time due to chemical and physical processes. These processes can significantly alter a material’s visual appearance, yet we can recognise the material as the same. The present study examined the extent of changes the human visual system can detect in specific materials over time. Participants (N = 5) were shown images of different materials (Banana, Copper, Leaf) from an existing calibrated set of photographs. Participants indicated which image pair (of the 2 pairs shown) displayed the largest difference. Estimated perceptual scales showed that observers were able to rank the images of aged materials systematically. Next, we examined the role that global and local changes in material surface colour play in the perception of material change. We altered the information about colour and geometrical distribution in the images used in the first experiment, and participants repeated the task with the altered images. Our results showed significant differences between individual observers. Most importantly, participants’ ability to rank the images varied with material type. The leaf images were particularly affected by our alteration of the geometrical distribution. Together, our findings show the factors contributing to the perception of material change over time.This work was supported by the European Union’s Horizon 2020 research and innovation programme [Grant Agreement No 765121]