12 research outputs found
Reconversion of Parahydrogen Gas in Surfactant-Coated Glass NMR Tubes
The application of parahydrogen gas to enhance the magnetic resonance signals of a diversity of chemical species has increased substantially in the last decade. Parahydrogen is prepared by lowering the temperature of hydrogen gas in the presence of a catalyst; this enriches the para spin isomer beyond its normal abundance of 25% at thermal equilibrium. Indeed, parahydrogen fractions that approach unity can be attained at sufficiently low temperatures. Once enriched, the gas will revert to its normal isomeric ratio over the course of hours or days, depending on the surface chemistry of the storage container. Although parahydrogen enjoys long lifetimes when stored in aluminum cylinders, the reconversion rate is significantly faster in glass containers due to the prevalence of paramagnetic impurities that are present within the glass. This accelerated reconversion is especially relevant for nuclear magnetic resonance (NMR) applications due to the use of glass sample tubes. The work presented here investigates how the parahydrogen reconversion rate is affected by surfactant coatings on the inside surface of valved borosilicate glass NMR sample tubes. Raman spectroscopy was used to monitor changes to the ratio of the (J: 0 → 2) vs. (J: 1 → 3) transitions that are indicative of the para and ortho spin isomers, respectively. Nine different silane and siloxane-based surfactants of varying size and branching structures were examined, and most increased the parahydrogen reconversion time by 1.5×–2× compared with equivalent sample tubes that were not treated with surfactant. This includes expanding the pH2 reconversion time from 280 min in a control sample to 625 min when the same tube is coated with (3-Glycidoxypropyl)trimethoxysilane
Reconversion of Parahydrogen Gas in Surfactant-Coated Glass NMR Tubes
The application of parahydrogen gas to enhance the magnetic resonance signals of a diversity of chemical species has increased substantially in the last decade. Parahydrogen is prepared by lowering the temperature of hydrogen gas in the presence of a catalyst; this enriches the para spin isomer beyond its normal abundance of 25% at thermal equilibrium. Indeed, parahydrogen fractions that approach unity can be attained at sufficiently low temperatures. Once enriched, the gas will revert to its normal isomeric ratio over the course of hours or days, depending on the surface chemistry of the storage container. Although parahydrogen enjoys long lifetimes when stored in aluminum cylinders, the reconversion rate is significantly faster in glass containers due to the prevalence of paramagnetic impurities that are present within the glass. This accelerated reconversion is especially relevant for nuclear magnetic resonance (NMR) applications due to the use of glass sample tubes. The work presented here investigates how the parahydrogen reconversion rate is affected by surfactant coatings on the inside surface of valved borosilicate glass NMR sample tubes. Raman spectroscopy was used to monitor changes to the ratio of the (J: 0 → 2) vs. (J: 1 → 3) transitions that are indicative of the para and ortho spin isomers, respectively. Nine different silane and siloxane-based surfactants of varying size and branching structures were examined, and most increased the parahydrogen reconversion time by 1.5×–2× compared with equivalent sample tubes that were not treated with surfactant. This includes expanding the pH2 reconversion time from 280 min in a control sample to 625 min when the same tube is coated with (3-Glycidoxypropyl)trimethoxysilane
Experimental Verification of Sparse Frequency Linearly Frequency Modulated Ladar Signals Modeling
We present the results of an experiment designed to verify the results of a previously published theoretical model that predicts the range resolution and peak-to-side lobe ratio of sparse frequency linearly frequency modulated (SF-LFM) ladar signals. We use two ultra stable diode lasers which are frequency locked and can be current tuned in order to adjust the difference frequency between the two lasers. The results of the experiment verify the previously developed model proving that SF-LFM ladar signals have the ability to increase the range resolution of a ladar system without the need for larger bandwidth modulators. Finally we simulate a target at a range of approximately 150 meters through the use of a fiber optic delay line, and demonstrate the ability of SF-LFM ladar signals to detect a target at range
Polypropylene-Derived Luminescent Carbon Dots
Polypropylene is one of the most challenging plastics
to recycle
or upcycle due to its excellent chemical and thermal stability. Here,
we report an effective two-step synthesis to prepare carbon dots (CDs)
from polypropylene (PP). In the first step, bulk PP is converted to
PP nanoparticles (PP-NPs) by using a reprecipitation process. In the
second step, the PP-NPs are carbonized by a hydrothermal treatment.
The size, structure, and photonic properties of the PP-CDs vary significantly
with hydrothermal treatment temperature. At higher temperature, the
PP-CDs product is ∼2.5 nm in diameter with a quantum yield
of 10.3% and is free from unconverted PP. At lower temperature (120
°C), the PP-CDs are large in size (∼70 nm) and exhibit
low quantum yield (0.2%). This work demonstrates an effective method
to fully convert polypropylene to carbon dots and shows a high degree
of tunability in the size, structure, and photonic properties of the
product