3,995 research outputs found
Edge-functionalized and substitutional doped graphene nanoribbons: electronic and spin properties
Graphene nanoribbons are the counterpart of carbon nanotubes in
graphene-based nanoelectronics. We investigate the electronic properties of
chemically modified ribbons by means of density functional theory. We observe
that chemical modifications of zigzag ribbons can break the spin degeneracy.
This promotes the onset of a semiconducting-metal transition, or of an
half-semiconducting state, with the two spin channels having a different
bandgap, or of a spin-polarized half-semiconducting state -where the spins in
the valence and conduction bands are oppositely polarized. Edge
functionalization of armchair ribbons gives electronic states a few eV away
from the Fermi level, and does not significantly affect their bandgap. N and B
produce different effects, depending on the position of the substitutional
site. In particular, edge substitutions at low density do not significantly
alter the bandgap, while bulk substitution promotes the onset of
semiconducting-metal transitions. Pyridine-like defects induce a
semiconducting-metal transition.Comment: 12 pages, 5 figure
Isotropization of Bianchi type models and a new FRW solution in Brans-Dicke theory
Using scaled variables we are able to integrate an equation valid for
isotropic and anisotropic Bianchi type I, V, IX models in Brans-Dicke (BD)
theory. We analyze known and new solutions for these models in relation with
the possibility that anisotropic models asymptotically isotropize, and/or
possess inflationary properties. In particular, a new solution of curve
() Friedmann-Robertson-Walker (FRW) cosmologies in Brans-Dicke theory
is analyzed.Comment: 15 pages, 4 postscript figures, to appear in Gen. Rel. Grav., special
issue dedicated in honour of Prof. H. Dehne
Tracking primary thermalization events in graphene with photoemission at extreme timescales
Direct and inverse Auger scattering are amongst the primary processes that
mediate the thermalization of hot carriers in semiconductors. These two
processes involve the annihilation or generation of an electron-hole pair by
exchanging energy with a third carrier, which is either accelerated or
decelerated. Inverse Auger scattering is generally suppressed, as the
decelerated carriers must have excess energies higher than the band gap itself.
In graphene, which is gapless, inverse Auger scattering is instead predicted to
be dominant at the earliest time delays. Here, femtosecond
extreme-ultraviolet pulses are used to detect this imbalance, tracking both the
number of excited electrons and their kinetic energy with time- and
angle-resolved photoemission spectroscopy. Over a time window of approximately
25 fs after absorption of the pump pulse, we observe an increase in conduction
band carrier density and a simultaneous decrease of the average carrier kinetic
energy, revealing that relaxation is in fact dominated by inverse Auger
scattering. Measurements of carrier scattering at extreme timescales by
photoemission will serve as a guide to ultrafast control of electronic
properties in solids for PetaHertz electronics.Comment: 16 pages, 8 figure
Direct evidence for efficient ultrafast charge separation in epitaxial WS/graphene heterostructure
We use time- and angle-resolved photoemission spectroscopy (tr-ARPES) to
investigate ultrafast charge transfer in an epitaxial heterostructure made of
monolayer WS and graphene. This heterostructure combines the benefits of a
direct gap semiconductor with strong spin-orbit coupling and strong
light-matter interaction with those of a semimetal hosting massless carriers
with extremely high mobility and long spin lifetimes. We find that, after
photoexcitation at resonance to the A-exciton in WS, the photoexcited holes
rapidly transfer into the graphene layer while the photoexcited electrons
remain in the WS layer. The resulting charge transfer state is found to
have a lifetime of \,ps. We attribute our findings to differences in
scattering phase space caused by the relative alignment of WS and graphene
bands as revealed by high resolution ARPES. In combination with spin-selective
excitation using circularly polarized light the investigated WS/graphene
heterostructure might provide a new platform for efficient optical spin
injection into graphene.Comment: 28 pages, 14 figure
Direct evidence for efficient ultrafast charge separation in epitaxial WS<sub>2</sub>/graphene heterostructures
We use time- and angle-resolved photoemission spectroscopy (tr-ARPES) to investigate ultrafast charge transfer in an epitaxial heterostructure made of monolayer WS2 and graphene. This heterostructure combines the benefits of a direct-gap semiconductor with strong spin-orbit coupling and strong light-matter interaction with those of a semimetal hosting massless carriers with extremely high mobility and long spin lifetimes. We find that, after photoexcitation at resonance to the A-exciton in WS2, the photoexcited holes rapidly transfer into the graphene layer while the photoexcited electrons remain in the WS2 layer. The resulting charge-separated transient state is found to have a lifetime of ∼1 ps. We attribute our findings to differences in scattering phase space caused by the relative alignment of WS2 and graphene bands as revealed by high-resolution ARPES. In combination with spin-selective optical excitation, the investigated WS2/graphene heterostructure might provide a platform for efficient optical spin injection into graphene
Ultrafast Momentum Imaging of Pseudospin-Flip Excitations in Graphene
The pseudospin of Dirac electrons in graphene manifests itself in a peculiar
momentum anisotropy for photo-excited electron-hole pairs. These interband
excitations are in fact forbidden along the direction of the light
polarization, and are maximum perpendicular to it. Here, we use time- and
angle-resolved photoemission spectroscopy to investigate the resulting
unconventional hot carrier dynamics, sampling carrier distributions as a
function of energy and in-plane momentum. We first show that the
rapidly-established quasi-thermal electron distribution initially exhibits an
azimuth-dependent temperature, consistent with relaxation through collinear
electron-electron scattering. Azimuthal thermalization is found to occur only
at longer time delays, at a rate that depends on the substrate and the static
doping level. Further, we observe pronounced differences in the electron and
hole dynamics in n-doped samples. By simulating the Coulomb- and
phonon-mediated carrier dynamics we are able to disentangle the influence of
excitation fluence, screening, and doping, and develop a microscopic picture of
the carrier dynamics in photo-excited graphene. Our results clarify new aspects
of hot carrier dynamics that are unique to Dirac materials, with relevance for
photo-control experiments and optoelectronic device applications.Comment: 23 pages, 12 figure
Relativistic static thin dust disks with an inner edge: An infinite family of new exact solutions
An infinite family of new exact solutions of the Einstein vacuum equations
for static and axially symmetric spacetimes is presented. All the metric
functions of the solutions are explicitly computed and the obtained expressions
are simply written in terms of oblate spheroidal coordinates. Furthermore, the
solutions are asymptotically flat and regular everywhere, as it is shown by
computing all the curvature scalars. These solutions describe an infinite
family of thin dust disks with a central inner edge, whose energy densities are
everywhere positive and well behaved, in such a way that their energy-momentum
tensor are in fully agreement with all the energy conditions. Now, although the
disks are of infinite extension, all of them have finite mass. The
superposition of the first member of this family with a Schwarzschild black
hole was presented previously [G. A. Gonz\'alez and A. C.
Guti\'errez-Pi\~neres, arXiv: 0811.3002v1 (2008)], whereas that in a subsequent
paper a detailed analysis of the corresponding superposition for the full
family will be presented.Comment: 9 pages, 3 figure
From MinX to MinC: Semantics-Driven Decompilation of Recursive Datatypes
Reconstructing the meaning of a program from its binary executable is known as
reverse engineering; it has a wide range of applications in software security, exposing piracy, legacy systems, etc. Since reversing is ultimately a search for meaning, there is much interest in inferring a type (a meaning) for the elements of a binary in a consistent way. Unfortunately existing approaches do not guarantee any semantic relevance for their reconstructed types. This paper presents a new and semantically-founded approach that provides strong guarantees for the reconstructed types. Key to our approach is the derivation of a witness program in a high-level language alongside the reconstructed types. This witness has the same semantics as the binary, is type correct by construction, and it induces a (justifiable) type assignment on the binary. Moreover, the approach effectively yields a type-directed decompiler. We formalise and implement the approach for reversing Minx, an abstraction of x86, to MinC, a type-safe dialect of C with recursive datatypes. Our evaluation compiles a range of textbook C algorithms to MinX and then recovers the original structures
Probing Yukawian gravitational potential by numerical simulations. I. Changing N-body codes
In the weak field limit general relativity reduces, as is well known, to the
Newtonian gravitation. Alternative theories of gravity, however, do not
necessarily reduce to Newtonian gravitation; some of them, for example, reduce
to Yukawa-like potentials instead of the Newtonian potential. Since the
Newtonian gravitation is largely used to model with success the structures of
the universe, such as for example galaxies and clusters of galaxies, a way to
probe and constrain alternative theories, in the weak field limit, is to apply
them to model the structures of the universe. In the present study, we consider
how to probe Yukawa-like potentials using N-body numerical simulations.Comment: 17 pages, 11 figures. To appear in General Relativity and Gravitatio
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