Characterization of volatile organic compounds at a roadside environment in Hong Kong: An investigation of influences after air pollution control strategies

Vehicular emission is one of the important anthropogenic pollution sources for volatile organic compounds (VOCs). Four characterization campaigns were conducted at a representative urban roadside environment in Hong Kong between May 2011 and February 2012. Carbon monoxide (CO) and VOCs including methane (CH4), non-methane hydrocarbons (NMHCs), halocarbons, and alkyl nitrates were quantified. Both mixing ratios and compositions of the target VOCs show ignorable seasonal variations. Except CO, liquefied petroleum gas (LPG) tracers of propane, i-butane and n-butane are the three most abundant VOCs, which increased significantly as compared with the data measured at the same location in 2003. Meanwhile, the mixing ratios of diesel- and gasoline tracers such as ethyne, alkenes, aromatics, halogenated, and nitrated hydrocarbons decreased by at least of 37%. The application of advanced multivariate receptor modeling technique of positive matrix factorization (PMF) evidenced that the LPG fuel consumption is the largest pollution source, accounting for 60 ± 5% of the total quantified VOCs at the roadside location. The sum of ozone formation potential (OFP) for the target VOCs was 300.9 μg-O3 m-3, which was 47% lower than the value of 567.3 μg-O3 m-3 measured in 2003. The utilization of LPG as fuel in public transport (i.e., taxis and mini-buses) contributed 51% of the sum of OFP, significantly higher than the contributions from gasoline- (16%) and diesel-fueled (12%) engine emissions. Our results demonstrated the effectiveness of the switch from diesel to LPG-fueled engine for taxis and mini-buses implemented by the Hong Kong Special Administrative Region (HKSAR) Government between the recent ten years, in additional to the execution of substitution to LPG-fueled engine and restrictions of the vehicular emissions in compliance with the updated European emission standards

Latent Variable Dialogue Models and their Diversity

We present a dialogue generation model that directly captures the variability in possible responses to a given input, which reduces the ‘boring output’ issue of deterministic dialogue models. Experiments show that our model generates more diverse outputs than baseline models, and also generates more consistently acceptable output than sampling from a deterministic encoder-decoder model

Summer and winter variations of dicarboxylic acids, fatty acids and benzoic acid in PM₂.₅ in Pearl Delta River Region, China

Author name used in this publication: Lee, S. C.2010-2011 > Academic research: refereed > Publication in refereed journalVersion of RecordPublishe

Irregular polar coding for complexity-constrained lightwave systems

Next-generation fiber-optic communications call for ultra-reliable forward error correction codes that are capable of low-power and low-latency decoding. In this paper, we propose a new class of polar codes, whose polarization units are irregularly pruned to reduce computational complexity and decoding latency without sacrificing error correction performance. We then experimentally demonstrate that the proposed irregular polar codes can outperform state-of-the-art low-density parity-check (LDPC) codes, while decoding complexity and latency can be reduced by at least 30% and 70%, respectively, versus regular polar codes, while also obtaining a marginal performance improvement

A path planning approach of 3D manipulators using zenithal gnomic projection and polar piecewise interpolation.

In this paper, the mathematical modeling and trajectory planning of a 3D rotating manipulator composed of a rotating-prismatic joint and multiple rigid links is considered. Possible trajectories of the end effector of the manipulator—following a sequence of 3D target points under the action of 2 external driving torques and an axial force—are modeled using zenithal gnomic projections and polar piecewise interpolants expressed as polynomial Hermite-type functions. Because of the geometry of the manipulator, the time-dependent generalized coordinates are associated with the spherical coordinates named the radial distance related to the manipulator length, and the polar and azimuthal angles describing the left and right and, respectively, up and down motion of the manipulator. The polar trajectories (left and right motion) of the end effector are generated using a inverse geometric transformation applied to the polar piecewise interpolants that approximate the gnomic projective trajectory of the 3D via-points. The gnomic via-points—located on a projective plane situated on the northern hemisphere—are seen from the manipulator base location, which represents the center of rotation of the extensible manipulator. The related azimuthal trajectory (up and down motion) is generated by polar piecewise interpolants on the azimuthal angles. Smoothness of the polygonal trajectory is obtained through the use of piecewise interpolants with continuous derivatives, while the kinematics and dynamics implementation of the model is well suited to computer implementation (easy calculation of kinematics variables) and simulation. To verify the approach and validate the model, a numerical example—implemented in Matlab—is presented, and the results are discussed

Different characteristics of char and soot in the atmosphere and their ratio as an indicator for source identification in Xi'an, China

2009-2010 > Academic research: refereed > Publication in refereed journalVersion of RecordPublishe

Suv4-20h Histone Methyltransferases Promote Neuroectodermal Differentiation by Silencing the Pluripotency-Associated Oct-25 Gene

Post-translational modifications (PTMs) of histones exert fundamental roles in regulating gene expression. During development, groups of PTMs are constrained by unknown mechanisms into combinatorial patterns, which facilitate transitions from uncommitted embryonic cells into differentiated somatic cell lineages. Repressive histone modifications such as H3K9me3 or H3K27me3 have been investigated in detail, but the role of H4K20me3 in development is currently unknown. Here we show that Xenopus laevis Suv4-20h1 and h2 histone methyltransferases (HMTases) are essential for induction and differentiation of the neuroectoderm. Morpholino-mediated knockdown of the two HMTases leads to a selective and specific downregulation of genes controlling neural induction, thereby effectively blocking differentiation of the neuroectoderm. Global transcriptome analysis supports the notion that these effects arise from the transcriptional deregulation of specific genes rather than widespread, pleiotropic effects. Interestingly, morphant embryos fail to repress the Oct4-related Xenopus gene Oct-25. We validate Oct-25 as a direct target of xSu4-20h enzyme mediated gene repression, showing by chromatin immunoprecipitaton that it is decorated with the H4K20me3 mark downstream of the promoter in normal, but not in double-morphant, embryos. Since knockdown of Oct-25 protein significantly rescues the neural differentiation defect in xSuv4-20h double-morphant embryos, we conclude that the epistatic relationship between Suv4-20h enzymes and Oct-25 controls the transit from pluripotent to differentiation-competent neural cells. Consistent with these results in Xenopus, murine Suv4-20h1/h2 double-knockout embryonic stem (DKO ES) cells exhibit increased Oct4 protein levels before and during EB formation, and reveal a compromised and biased capacity for in vitro differentiation, when compared to normal ES cells. Together, these results suggest a regulatory mechanism, conserved between amphibians and mammals, in which H4K20me3-dependent restriction of specific POU-V genes directs cell fate decisions, when embryonic cells exit the pluripotent state

Requirement of RIZ1 for cancer prevention by methyl-balanced diet

The typical Western diet is not balanced in methyl nutrients that regulate the level of the methyl donor S-adenosylmethionine (SAM) and its derivative metabolite S-adenosylhomocysteine (SAH), which in turn may control the activity of certain methyltransferases. Feeding rodents with amino acid defined and methyl-imbalanced diet decreases hepatic SAM and causes liver cancers. RIZ1 (PRDM2 or KMT8) is a tumor suppressor and functions in transcriptional repression by methylating histone H3 lysine 9. Here we show that a methyl-balanced diet conferred additional survival benefits compared to a tumor-inducing methyl-imbalanced diet only in mice with wild type RIZ1 but not in mice deficient in RIZ1. While absence of RIZ1 was tumorigenic in mice fed the balanced diet, its presence did not prevent tumor formation in mice fed the imbalanced diet. Unlike most of its related enzymes, RIZ1 was upregulated by methyl-balanced diet. Methyl-balanced diet did not fully repress oncogenes such as c-Jun in the absence of RIZ1. The data identify RIZ1 as a critical target of methyl-balanced diet in cancer prevention. The molecular understanding of dietary carcinogenesis may help people make informed choices on diet, which may greatly reduce the incidence of cancer