An improved atomistic simulation based mixed-mode cohesive zone law considering non-planar crack growth

AbstractA novel and improved atomistic simulation based cohesive zone law characterizing interfacial debonding is developed which explicitly accounts for the non-planarity of the crack propagation. Group of atoms in the simulation constituting cohesive zones which are used to obtain local stress and crack opening displacement data are determined dynamically during the non-planar crack growth as they cannot be determined apriori. The methodology is used to study the debonding of Σ5 (210)/[001] symmetric tilt grain boundary interface in a Cu bicrystal under several mixed mode loading conditions. Simulations show that such bicrystalline specimen exhibits three types of energy dissipative mechanisms – shear coupled GB migration (SCM) away from the crack-tips, change in spacial orientation of GB structural units rendering highly disordered grain boundary near the crack tips and brittle intergranular fracture. Which combination of these three deformation mechanism will be active influencing the degree of non-planarity of the crack propagation at various stages of loading depends on the loading mode-mixity. As the ratio of shear component of the loading parallel to the GB plane and normal to the tilt axis with respect to the normal loading increases (thereby increasing the mode-mixity), overall strain-to-failure also increases and SCM tends to become the dominant deformation mechanism. Through this framework, analytical functional forms and parameters describing cohesive laws for both normal and shear traction as a function of the mode-mixity of the loading and crack opening displacement are predicted

PHOTOCATALYTICDEGRADATION OF RHODAMIN-B USING METAL COMPLEXES AND HYDROGEN PEROXIDE

ABSTRACT The photocatalytic degradation has been considered to be an efficient process for degradation of organic pollutants, which are present in the effluents released by industries. Thephotocatalytic bleaching was carried out on rhodamin-B (cationic dye) in the presence of iron (III) complex, hydrogen peroxide and was observed spectrophotometrically. The effect of various operating variables like pH, concentration of complex and dye, amount of HzOzand light intensity etc. was also observed on the efficiency of the reaction. A tentative mechanism has also been proposed for this photocatalytic degradation of rhodamin-B. Keywords: Photocatalytic degradation, rhodamin-B, metal complexes, hydrogen peroxide

Elastic properties and zone centre frequencies of Cu2O by LCAO method

918-922The elastic properties and the phonon frequencies at the Brillouin zone centre have been investigated for the cubic cuprous oxide. The calculations under the framework of density functional theory have been carried out by deploying the periodic linear combination of atomic orbitals method. After settling the crystal structure the elastic constants have been determined. The absolute values of elastic constants are well in agreement with the experimental reports. The vibrational frequencies at the centre of the Brillouin zone are classified as the Raman and Infrared active modes and compared with the available experimental data. The contribution of vibrational modes to the Gibbs free energy, entropy and heat capacity has also been found

Effect of speech coders on speech recognition performance

Speech coders with bitrates as low as 2.4 kbits/s are now being de-veloped for speech transmission in the telecommunications industry. For speech coders to work at this reduced bitrate, some speech infor-mation has to be removed and it is only natural to expect that the per-formance of speechrecognition systems will deteriorate when coded speech is applied as input to a recognition system. In this paper, the results of a study to examine the effects speech coders have on speech recogntion are presented. Six different speech coders rang-ing from 4.8 kbits/s to 40 kbits/s are used with two different speech recognition systems 1) isolated word recogntion and 2) phoneme recogntion from continuous speech. The effects on speech recog-nition performance by tandeming each of the speech coders are also presented. 1

Pressure dependent electronic properties of MgO polymorphs: A first-principles study of Compton profiles and autocorrelation functions

The first-principles periodic linear combination of atomic orbitals method within the framework of density functional theory implemented in the CRYSTAL06 code has been applied to explore effect of pressure on the Compton profiles and autocorrelation functions of MgO. Calculations are performed for the B1, B2, B3, B4, B8_1 and h-MgO polymorphs of MgO to compute lattice constants and bulk moduli. The isothermal enthalpy calculations predict that B4 to B8_1, h-MgO to B8_1, B3 to B2, B4 to B2 and h-MgO to B2 transitions take place at 2, 9, 37, 42 and 64 GPa respectively. The high pressure transitions B8_1 to B2 and B1 to B2 are found to occur at 340 and 410 GPa respectively. The pressure dependent changes are observed largely in the valence electrons Compton profiles whereas core profiles are almost independent of the pressure in all MgO polymorphs. Increase in pressure results in broadening of the valence Compton profiles. The principal maxima in the second derivative of Compton profiles shifts towards high momentum side in all structures. Reorganization of momentum density in the B1 to B2 structural phase transition is seen in the first and second derivatives before and after the transition pressure. Features of the autocorrelation functions shift towards lower r side with increment in pressure.Comment: 19 pages, 8 figures, accepted for publication in Journal of Materials Scienc

Potential of genomics for the improvement of underutilized legumes in sub-Saharan Africa

Open Access Journal; Published online: 03 Jan 2021Underutilized, or orphan legumes, are widely distributed across farming landscapes in sub-Saharan Africa (SSA) but often have low yields and do not fulfill their potential due to very limited research, breeding, development, marketing, and awareness of their benefits. These advantages include nutritional quality and climate resilience. In this review, we focus on Bambara groundnut, African yam bean, and Kersting's groundnut. Knowledge of the challenges and rewards of exploiting them will provide opportunities for concerted approaches to their revival and contribution to future global food systems, especially in the context of climate change. This review identifies the institutional and noninstitutional challenges, the constraints, the prospects, and the rewards that can be derived from exploiting orphan legumes in SSA. The genetic resources center (GRC) of the International Institute of Tropical Agriculture (IITA) conserves a diverse collection of about 2500 accessions of these crops with the majority from Africa. In this review, we focus on the ex situ conservation of the genetic resources of these indigenous African legume crops, their characterization and evaluation, prospects for the development of improved cultivars, and the role they could play, particularly with respect to nutrition and adaptation to climate change. We emphasize progress made in recent years concerning the assembly of information required for application of genomics tools to these crops and how this will underpin the development of improved varieties

Ubv CCD Standards Near 5C1 Radio Sources at Intermediate Galactic Latitude-I

We have been doing a photometric and astrometric sample survey programme on Schmidt plates in a few selected directions in the Galaxy with an aim to study galactic stellar populations. In order to calibrate Schmidt plates photometrically, it is necessary to have a number of photometric standards which cover the entire range of magnitudes to be studied on the plates. As Schmidt plates cover a wide area of the sky, the standards should also be spread over the surface of the plate so as to minimise geometrical effects present on the plate. This paper is first in a series of papers aimed at to provide photometric standards in the selected galactic directions to be studied. In this paper we present photometric magnitudes obtained through CCD observation in the galactic direction (l=170deg, b=45deg) centered at alpha(2000) = 9h 41m 20s and delta(2000) = +49deg 54' 20'' and covering an area of 14 sq degs. B and V magnitudes have been obtained for a total of 214 stars out of which for 73 stars U magnitudes also have been obtained. The magnitude range covered is 11<V<21 and 0.18<B-V<1.85.Comment: Postscript file, 13 pages, 1 figure (figure available on request), paper accepted for publication in the Bulletin of Astronomical Society of Indi

Sunstein, Statutes, and the Common Law – Reconciling Markets, the Communal Impulse, and the Mammoth State

Professor Cass Sunstein\u27s new book, After the Rights Revolution: Reconceiving the Regulatory State, builds upon, and in important ways seeks to integrate, much of Professor Sunstein\u27s work over the past several years. He has been one of our most prolific and influential writers on issues of governmental structure, approaching the subject both from more or less conventional administrative law perspectives and from the constitutional perspectives of separation of powers. His work has dealt with a tension often addressed in the literature, that between the eighteenth-century Madisonian constitutional engine of limited, internally checked government and the realities of our sprawling contemporary structures. A particular contribution of Sunstein\u27s has been to insist on bringing forward the Madisonian visions, on their accommodation, not their abandonment. This contribution entails rather vigorous disagreement with the economics-driven theorists of public choice, on the right, and those of deconstructionism, on the left. Sunstein wants to build a conceptual framework for contemporary government that embraces the Madisonian ideal of government structured to serve genuinely public ends in face of the risk of faction; that vision entails both reaching agreement on appropriate distinctions between public and private ends, and finding effective contemporary expression of such ideas as checks and balances