2,081 research outputs found
Microphase separation in polyelectrolytic diblock copolymer melt : weak segregation limit
We present a generalized theory of microphase separation for charged-neutral
diblock copolymer melt. Stability limit of the disordered phase for salt-free
melt has been calculated using Random Phase Approximation (RPA) and
self-consistent field theory (SCFT). Explicit analytical free energy
expressions for different classical ordered microstructures (lamellar, cylinder
and sphere) are presented. We demonstrate that chemical mismatch required for
the onset of microphase separation () in charged-neutral
diblock melt is higher and the period of ordered microstructures is lower than
those for the corresponding neutral-neutral diblock system. Theoretical
predictions on the period of ordered structures in terms of Coulomb
electrostatic interaction strength, chain length, block length, and the
chemical mismatch between blocks are presented. SCFT has been used to go beyond
the stability limit, where electrostatic potential and charge distribution are
calculated self-consistently. Stability limits calculated using RPA are in
perfect agreement with the corresponding SCFT calculations. Limiting laws for
stability limit and the period of ordered structures are presented and
comparisons are made with an earlier theory. Also, transition boundaries
between different morphologies have been investigated
Gender gap in the ERASMUS mobility program
Studying abroad has become very popular among students. The ERASMUS mobility
program is one of the largest international student exchange programs in the
world, which has supported already more than three million participants since
1987. We analyzed the mobility pattern within this program in 2011-12 and found
a gender gap across countries and subject areas. Namely, for almost all
participating countries, female students are over-represented in the ERASMUS
program when compared to the entire population of tertiary students. The same
tendency is observed across different subject areas. We also found a gender
asymmetry in the geographical distribution of hosting institutions, with a bias
of male students in Scandinavian countries. However, a detailed analysis
reveals that this latter asymmetry is rather driven by subject and consistent
with the distribution of gender ratios among subject areas
Best-Bet Astrophysical Neutrino Sources
Likely astrophysical sources of detectable high-energy (>> TeV) neutrinos are
considered. Based on gamma-ray emission properties, the most probable sources
of neutrinos are argued to be GRBs, blazars, microquasars, and supernova
remnants. Diffuse neutrino sources are also briefly considered.Comment: 6 pages, 2 figures, in Proc. of TeV-Particle Astrophysics II,
Madison, WI, 28-31 Aug, 200
Composition, structure and stability of RuO_2(110) as a function of oxygen pressure
Using density-functional theory (DFT) we calculate the Gibbs free energy to
determine the lowest-energy structure of a RuO_2(110) surface in thermodynamic
equilibrium with an oxygen-rich environment. The traditionally assumed
stoichiometric termination is only found to be favorable at low oxygen chemical
potentials, i.e. low pressures and/or high temperatures. At realistic O
pressure, the surface is predicted to contain additional terminal O atoms.
Although this O excess defines a so-called polar surface, we show that the
prevalent ionic model, that dismisses such terminations on electrostatic
grounds, is of little validity for RuO_2(110). Together with analogous results
obtained previously at the (0001) surface of corundum-structured oxides, these
findings on (110) rutile indicate that the stability of non-stoichiometric
terminations is a more general phenomenon on transition metal oxide surfaces.Comment: 12 pages including 5 figures. Submitted to Phys. Rev. B. Related
publications can be found at http://www.fhi-berlin.mpg.de/th/paper.htm
Electronic structure and magnetic properties of cobalt intercalated in graphene on Ir(111)
Using a combination of photoemission and x-ray magnetic circular dichroism (XMCD), we characterize the growth and the electronic as well as magnetic structure of cobalt layers intercalated in between graphene and Ir(111). We demonstrate that magnetic ordering exists beyond one monolayer intercalation, and determine the Co orbital and spin magnetic moments. XMCD from the carbon edge shows an induced magnetic moment in the graphene layer, oriented antiparallel to that of cobalt. The XMCD experimental data are discussed in comparison to our results of first-principles electronic structure calculations. It is shown that good agreement between theory and experiment for the Co magnetic moments can be achieved when the local-spin-density approximation plus the Hubbard U (LSDA+U) is used
Non-Gaussian statistics of electrostatic fluctuations of hydration shells
We report the statistics of electric field fluctuations produced by SPC/E
water inside a Kihara solute given as a hard-sphere core with a Lennard-Jones
layer at its surface. The statistics of electric field fluctuations, obtained
from numerical simulations, are studied as a function of the magnitude of a
point dipole placed close to the solute-water interface. The free energy
surface as a function of the electric field projected on the dipole direction
shows a cross-over with the increasing dipole magnitude. While it is a
single-well harmonic function at low dipole values, it becomes a double-well
surface at intermediate dipole moment magnitudes, transforming to a single-well
surface, with a non-zero minimum position, at still higher dipoles. A broad
intermediate region where the interfacial waters fluctuate between the two
minima is characterized by intense field fluctuations, with non-Gaussian
statistics and the variance far exceeding the linear-response expectations. The
excited state of the surface water is found to be lifted above the ground state
by the energy required to break approximately two hydrogen bonds. This state is
pulled down in energy by the external electric field of the solute dipole,
making it readily accessible to thermal excitations. The excited state is a
localized surface defect in the hydrogen-bond network creating a stress in the
nearby network, but otherwise relatively localized in the region closest to the
solute dipole
Modeling the Emission Processes in Blazars
Blazars are the most violent steady/recurrent sources of high-energy
gamma-ray emission in the known Universe. They are prominent emitters of
electromagnetic radiation throughout the entire electromagnetic spectrum. The
observable radiation most likely originates in a relativistic jet oriented at a
small angle with respect to the line of sight. This review starts out with a
general overview of the phenomenology of blazars, including results from a
recent multiwavelength observing campaign on 3C279. Subsequently, issues of
modeling broadband spectra will be discussed. Spectral information alone is not
sufficient to distinguish between competing models and to constrain essential
parameters, in particular related to the primary particle acceleration and
radiation mechanisms in the jet. Short-term spectral variability information
may help to break such model degeneracies, which will require snap-shot
spectral information on intraday time scales, which may soon be achievable for
many blazars even in the gamma-ray regime with the upcoming GLAST mission and
current advances in Atmospheric Cherenkov Telescope technology. In addition to
pure leptonic and hadronic models of gamma-ray emission from blazars,
leptonic/hadronic hybrid models are reviewed, and the recently developed
hadronic synchrotron mirror model for TeV gamma-ray flares which are not
accompanied by simultaneous X-ray flares (``orphan TeV flares'') is revisited.Comment: Invited Review at "The Multimessenger Approach to Gamma-Ray Sources",
Barcelona, Spain, July 2006; submitted to Astrophysics and Space Science. 10
pages, including 6 eps figures. Uses Springer's ApSS macro
Equilibrium solvation in quadrupolar solvents
We present a microscopic theory of equilibrium solvation in solvents with
zero dipole moment and non-zero quadrupole moment (quadrupolar solvents). The
theory is formulated in terms of autocorrelation functions of the quadrupolar
polarization (structure factors). It can be therefore applied to an arbitrary
dense quadrupolar solvent for which the structure factors are defined. We
formulate a simple analytical perturbation treatment for the structure factors.
The solute is described by coordinates, radii, and partial charges of
constituent atoms. The theory is tested on Monte Carlo simulations of solvation
in model quadrupolar solvents. It is also applied to the calculation of the
activation barrier of electron transfer reactions in a cleft-shaped
donor-acceptor complex dissolved in benzene with the structure factors of
quadrupolar polarization obtained from Molecular Dynamics simulations.Comment: Submitted to J. Chem. Phys., 20 pages and 13 figure
Terahertz response of dipolar impurities in polar liquids: On anomalous dielectric absorption of protein solutions
A theory of radiation absorption by dielectric mixtures is presented. The
coarse-grained formulation is based on the wavevector-dependent correlation
functions of molecular dipoles of the host polar liquid and a density-density
structure factor of the positions of the solutes. A nonlinear dependence of the
absorption coefficient on the solute concentration is predicted and originates
from the mutual polarization of the liquid surrounding the solutes by the
collective field of the solute dipoles aligned along the radiation field. The
theory is applied to terahertz absorption of hydrated saccharides and proteins.
While the theory gives an excellent account of the observations for saccharides
without additional assumptions and fitting parameters, experimental absorption
coefficient of protein solutions significantly exceeds theoretical calculations
within standard dielectric models and shows a peak against the protein
concentration. A substantial polarization of protein's hydration shell is
required to explain the differences between standard theories and experiment.
When the correlation function of the total dipole moment of the protein with
its hydration shell from numerical simulations is used in the present
analytical model an absorption peak similar to that seen is experiment is
obtained. The result is sensitive to the specifics of protein-protein
interactions in solution. Numerical testing of the theory requires the
combination of terahertz dielectric and small-angle scattering measurements.Comment: 11 p
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