Life Cycle Inventories of Metals and Methodological Aspects of Inventorying Material Resources in ecoinvent (7 pp)

Goal, Scope and Background: The ecoinvent database provides harmonised generic life cycle inventories for metal production and processing. They can be used as background data for different LCA applications. The goal of this paper is to provide an overview of the metals inventoried in ecoinvent. Beside, some methodological background information is given. The focus lies on a new methodology developed to inventorying joint resources. The implementation is shown in a case study of the production of primary copper on a global average. The respective process is assessed with Eco-indicator 99 (H,A) to identify dominant impacts within the production chain. Methods: In ecoinvent, a coupled production is inventoried in multi output unit processes. For database calculation, an allocation by economic revenue is applied. Elementary flows for resources, especially joint resources, include information on type and quality of the resources. Results and Conclusion: With the presented method, the extraction of resources can be valuated based on the cost of restoration or the change in the future impact due to the extraction of a specific resource. The case study indicates, for copper / molybdenum production, that the mineral extraction is of minor importance compared to the metallurgical step according to the LCIA results. Air emissions of heavy metals are identified as main impacts. Also, the resource depletion shows a notable impact. The environmental impacts of metals from sulphidic ores, however, are underestimated by neglecting emissions from tailings for lack of reliable data. Recommendation and Perspective: Impact assessment methods will have to be updated to account for different grades of ore. The ecoinvent database should be enlarged by more inventories of technically important metals and alloys, e.g. by gold, silver, solders, etc. for the electronics industry and by specific steel and aluminium alloys. Reliable composition data of sulphidic tailings and transfer coefficients for their disposal considering Acidic Rock Drainage (ARD) are to be developed as wel

Developments in Wood and Packaging Materials Life Cycle Inventories in ecoinvent (9 pp)

Goal, Scope and Background: This paper gives an overview on how the wood and packaging material production is inventoried in ecoinvent. Packaging materials have been a very important topic in the area of Life Cycle Assessment for more than twenty years. Wood is the most important renewable material and regenerative fuel used worldwide, and an important raw material for paper / board. Several methodological problems arising when inventorying wood for material and energetic uses in a generic database are discussed in more detail. Within the ecoinvent project, the Swiss data base for life cycle inventory data, two reports are dedicated to these two important topics report No. 9 for wood and report No. 11 for packaging materials. Methods: The whole wood chain has been modeled in a consistent way. This allows one to use this data for LCAs of building materials, bioenergy or paper production. The data represent average technologies used in Central Europe in the year 2000. A revenue-based co-product allocation approach is used for the different outputs. Correction factors are introduced for the consistent modeling of mass-based, material inherent wood properties such as solar energy, carbon uptake and land use. For packaging materials, the datasets represent European average data for the most often used materials as well as specific datasets for the production of actual packaging boxes and containers. Results and Discussion: For wood, revenue-based allocation and the use of the correction factors for mass-related wood properties are shown and explained. For packaging materials, the importance of the raw material wood to the total load is shown. Furthermore trends in the data inventories for board packaging materials over the last two decades are discussed: mainly due to the increased comprehensiveness of the data, higher cumulative emissions can be observed. Conclusion: For wood, the database ecoinvent provides consistent datasets for the entire chain from forestry to intermediate products such as timber, different types of wood-based boards, chips, pellets, etc. For packaging materials, the number of datasets of basic materials has been extended. A modular concept for actual packaging container datasets allows the user an easy modeling of various types of packaging containers/boxes. In the area of paper and board, a comprehensive database for the production of various types of pulp, paper and board is provided, which is representative for the average European production situation. Outlook: Since wood is only limited and representative data for Europe is therefore not included, an update in the near future would be reasonable. Possible further extensions in the future could include various, final wooden products. For the data on paper/board, different levels of quality are observed, requiring a selective up-date of these data. Future extensions could include datasets for the import of pulp from overseas especially from South America and Canad

Traffic noise in LCA: Part 1: state-of-science and requirement profile for consistent context-sensitive integration of traffic noise in LCA

Background, aim, and scope: According to some recent studies, noise from road transport is estimated to cause human health effects of the same order of magnitude as the sum of all other emissions from the transport life cycle. Thus, ISO 14′040 implies that traffic noise effects should be considered in life cycle assessment (LCA) studies where transports might play an important role. So far, five methods for the inclusion of noise in LCA have been proposed. However, at present, none of them is implemented in any of the major life cycle inventory (LCI) databases and commonly used in LCA studies. The goal of the present paper is to define a requirement profile for a method to include traffic noise in LCA and to assess the compliance of the five existing methods with this profile. It concludes by identifying necessary cornerstones for a model for noise effects of generic road transports that meets all requirements. Materials and methods: Requirements for a methodological framework for inclusion of traffic noise effects in LCA are derived from an analysis of how transports are included in 66 case studies published in International Journal of Life Cycle Assessment in 2006 and 2007, in the sustainability reports of ten Swiss companies, as well as on the basis of theoretical considerations. Then, the general compliance of the five existing methods for inclusion of noise in LCA with the postulated requirement profile is assessed. Results: Six general requirements for a methodological framework for inclusion of traffic noise effects in LCA were identified. A method needs to be applicable for (1) both generic and specific transports, (2) different modes of transport, (3) different vehicles within one mode of transport, (4) transports in different geographic contexts, (5) different temporal contexts, and (6) last but not least, the method needs to be compatible with the ISO standards on LCA. One of the reviewed methods is not specific for transports at all and two are only applicable for specific transports. The other two allow generic and specific road transports to be assessed. The methods either deal with road traffic noise only or they compare noise from different sources, ignoring the fact that not only physical sound levels but also the source of sound determines the effect. Three methods only differentiate between vehicle classes (lorries and passenger cars) while one method differentiates between specific vehicles of the same class. Four of the methods consider the geographic context and three of them differentiate between day- and nighttime traffic. Discussion: None of the existing methods for traffic noise integration in LCA complies with the proposed requirement profile. They either lack the genericness for a wide application or they lack the specificity needed for differentiations in LCA studies. There is no method available that allows for appropriate inter- or intramodal comparison of traffic noise effects. Thus, the benefit of the existing methods is limited. They can, in the better cases, only demonstrate the relative importance of road or rail traffic noise effects compared to the nonnoise-related effects of transportation. Conclusions: Currently, none of the major LCI databases includes traffic noise indicators. Thus, noise effects are usually not considered in LCA studies. We introduce a requirement profile for methods that allow the inclusion of noise in LCI. Due to the estimated significance of noise in transport LCA, this inclusion will change the overall results of many LCA studies. None of the existing methods fully complies with the requirement profile. Two of the methods can be modified and extended for inclusion in generic LCI databases. A third model allows for intermodal comparison. From an LCA perspective, all methods include weaknesses and need to be amended in order to make them widely usable. Recommendations and perspectives: In part 2 of this paper, an in-depth analysis of the promising methods is provided, improvement potential is evaluated, and a new context-sensitive framework for the consistent LCI modeling of noise emissions from road transportation is presented. Appropriate methods for modeling rail and air traffic noise will have to be developed in the future in order to arrive at a methodological framework fully compliant with the requirement profile. Furthermore, future research is needed to identify appropriate methods for impact assessmen

Traffic noise in LCA: Part 2: Analysis of existing methods and proposition of a new framework for consistent, context-sensitive LCI modeling of road transport noise emission

Background, aim, and scope: An inclusion of traffic noise effects could change considerably the overall results of many life cycle assessment (LCA) studies. However, at present, noise effects are usually not considered in LCA studies, mainly because the existing methods for their inclusion do not fulfill the requirement profile. Two methods proposed so far seem suitable for inclusion in generic life cycle inventory (LCI) databases, and a third allows for inter-modal comparison. The aim of this investigation is an in-depth analysis of the existing methods and the proposition of a framework for modeling road transport noise emissions in LCI in accordance to the requirement profile postulated in part 1. Materials and methods: This paper analyzes three methods for inclusion of traffic noise in LCA (Danish LCA guide method, Swiss EPA method, and Swiss FEDRO method) in detail. The additional basis for the analysis are the Swiss road traffic emission model "SonRoad,” traffic volume measurements at 444 sites in the Swiss road network, vehicle-type-specific noise measurements in free floating traffic situations in Germany, and noise emission measurements from different tires. Results: The Danish LCA guide method includes a major flaw that cannot be corrected within the methodological concept. It applies a dose-response function valid for average noise levels of a traffic situation to maximum noise levels of single vehicles. The Swiss FEDRO method is based on an inappropriate assumption since it bases distinctions of specific vehicles on data that do not allow for such a distinction. Noise emissions cannot be distinguished by the make and type of a vehicle since other factors, especially the tires, are dominant for noise emissions. Several problems are also identified in the Swiss EPA method, but they are not of a fundamental nature. Thus, we are able to base a new framework for vehicle and context-sensitive inclusion of road traffic noise emissions in LCI on the Swiss EPA method. We show how specific vehicle classes can be distinguished, how the influence of different tires can be dealt with, and what temporal and spatial aspects of traffic need to be distinguished. Discussion: While the Danish LCA guide method and the Swiss FEDRO method are not suitable for our purpose, the Swiss EPA method can be used as a basis to better meet the requirement profile identified in Part 1 of this paper. The proposed method for consistent, context-sensitive modeling of noise emissions from road transports in LCI meets all the requirements except that it is restricted to road transport. Conclusions: We show limitations of the existing methods and approaches for improving them. Our proposed model allows for a more specific consideration of the various vehicles and contexts in terms of space and time and thus in terms of speed and traffic volume. This can be used on one hand for a consistent, context sensitive assessment of different vehicles in different traffic situations. On the other hand, it also allows for an inclusion of noise in LCA of transports on which only very little is known. This new LCI model meets five of the six requirements postulated in Part 1. Recommendations and perspectives: In a next step, additional noise emissions due to additional traffic needs to be calculated based on the proposed framework and national or regional traffic models. Furthermore, the consideration of noise from different traffic modes should be addressed. The approach presented needs to be extended in order to make it also applicable for rail and air traffic noise, and the methods need to be implemented in LCI databases to make them easily available to practitioners. Furthermore, suitable impact assessment methods need to be identified or developed. They could base on the proposals made in the Swiss EPA and in the Swiss FEDRO method

Literature review of epidemiology studies on the association between exposure to particulate matter and human health outcomes

Airborne particles can come from a variety of sources and contain variable chemical constituents. Some particles are formed by natural processes, such as volcanoes, erosion, sea spray, and forest fires, while other are formed by anthropogenic processes, such as industrial- and motor vehicle-related combustion, road-related wear, and mining. In general, larger particles (those greater than 2.5 μm) are formed by mechanical processes, while those less than 2.5 μm are formed by combustion processes. The chemical composition of particles is highly influenced by the source: for combustion-related particles, factors such as temperature of combustion, fuel type, and presence of oxygen or other gases can also have a large impact on PM composition. These differences can often be observed at a regional level, such as the greater sulphate-composition of PM in regions that burn coal for electricity production (which contains sulphur) versus regions that do not. Most countries maintain air monitoring networks, and studies based on the resulting data are the most common basis for epidemiology studies on the health effects of PM. Data from these monitoring stations can be used to evaluate the relationship between community-level exposure to ambient particles and health outcomes (i.e., morbidity or mortality from various causes). Respiratory and cardiovascular outcomes are the most commonly assessed, although studies have also considered other related specific outcomes such as diabetes and congenital heart disease. The data on particle characteristics is usually not very detailed and most often includes some combination of PM2.5, PM10, sulphate, and NO2. Other descriptors that are less commonly found include particle number (ultrafine particles), metal components of PM, local traffic intensity, and EC/OC. Measures of association are usually reported per 10 μg/m3 or interquartile range increase in pollutant concentration. As the exposure data are taken from regional monitoring stations, the measurements are not representative of an individual's exposure. Particle size is an important descriptor for understanding where in the human respiratory system the particles will deposit: as a general rule, smaller particles penetrate to deeper regions of the lungs. Initial studies on the health effects of particulate matter focused on mass of the particles, including either all particles (often termed total suspended particulate or TSP) or PM10 (all particles with an aerodynamic diameter less than 10 μm). More recently, studies have considered both PM10 and PM2.5, with the latter corresponding more directly to combustion-related processes. UFPs are a dominant source of particles in terms of PNC, yet are negligible in terms of mass. Very few epidemiology studies have measured the effect of UFPs on health; however, the numbers of studies on this topic are increasing. In addition to size, chemical composition is of importance when understanding the toxicity of particles. Some studies consider the composition of particles in addition to mass; however this is not common, in part due the cost and labour involved in such analyses

Manufacturing and Disposal of Building Materials and Inventorying Infrastructure in ecoinvent (8 pp)

Goal, Scope and Background: The present paper describes the goal and scope of building material inventories in the ecoinvent database and gives an overview of its content. The ecoinvent database provides generic life cycle inventories for building material production and related processing. They can be used as background data for different LCA applications. Their geographical and temporal scope is Switzerland or Europe and the year 2000. Methods: Data is inventoried as unit processes. Consistency throughout different sources is heeded by systematically estimating missing data. Infrastructure is consequently considered. Different disposal options are modelled. Results and Conclusion: The ecoinvent data provide a harmonised basis for different kinds of building materials. Even though not all datasets could be established on the same quality level, the results generally are believed to be comparable. Since data are generic, they are, however, not suitable to directly compare specific products. Disposal is relevant for the environmental burdens of uses of building materials. Complete life cycles have to be assessed. For this purpose, cumulative energy demand (CED) is not a suitable indicator. Recommendation and Perspective: In future versions of ecoinvent, data quality could be further improved. The database should be extended to include further building materials from secondary materials. To do so, the methodological treatment of secondary materials needs special attentio

Environmental Assessment of End-of-Life Treatment Options for a GSM 900 Antenna Rack (12 pp paper version/18 pp online version)

Goal, Scope and Background: Telephony as well as remote data transfer is increasingly performed via mobile phone networks. However, the environmental consequences, in particular of the End-of-Life (EOL) treatment, of such network infrastructures have been investigated insufficiently to date. In the present report the environmental implications of the EOL treatment of a single GSM 900 antenna rack have been analysed. Methods: Based on comprehensive inventories of a GSM 900 antenna station rack and currently applied EOL treatment, the environmental impacts related to the EOL treatment of the rack are investigated. Six different EOL treatment scenarios are developed to find an environmentally safe treatment alternative. System expansion, i.e. inclusion of the production phase, is applied to all scenarios in order to consider different amounts of regained materials. Results and Discussion: The production of primary rack materials, especially that of palladium (accounts for almost 40% of the ecotoxicity impact category), to substitute lost materials dominates the overall environmental impact. Releases of heavy metals from landfilled rack components / materials and of by-products to the environment greatly influence the overall impacts on human health and ecosystem quality. The final disposal of rack components contributes to about 70% of the non-carcinogenic effects. Landfilled dust from steel production contributes to nearly 11% of this impact category. Conclusion: The results suggest that all precious metals containing electronic scrap should be treated in specially equipped metal recovery plants. A complete rack disassembly before processing in high-standard metal recovery plants is not necessary. An elaborated pre-treatment and fractionation of the scrap prior to precious material recovery does not lower the environmental impacts and is not mandatory and would only become environmentally interesting if high recovery of heavy metals is achieved. To avoid the formation and release of volatile and toxic heavy metal, incineration of electronic scrap as of by-products prior to landfilling should be avoided. To reduce the overall environmental load, a standardisation of the sizes of rack components, facilitating their re-use, is recommende

High Refractive Index Materials of Iron Sulfides and Poly(ethylene oxide)

High refractive index composites of iron sulfides and poly(ethylene oxide) (PEO) have been prepared by co-precipitation from aqueous solution. Several reaction parameters were varied: inorganic reactants, reactant ratios, reaction temperatures, and reaction times. Selected samples were characterized with organic microelemental analysis, x-ray fluorescence spectroscopy, x-ray diffraction, DSC, and TEM. The nanocomposites with the highest refractive indices have been prepared using PEO, Mohr's salt, and H2S or NaHS. The analyses indicate that the iron sulfides in these materials consist of finely dispersed mackinawite and greigite ("amorphous” FeS) and, partially, also pyrite. The refractive indexes of the resulting composites are clearly above 2 at 632.8 and 1295 nm and can assume values between 2.5 and 2.

Kritische Metalle: Wie die Schweizer Industrie vorsorgen kann

Im April 2016 organisierten der Entwicklungsfonds Seltene Metalle ESM, MatSearch Consulting Hofmann, die Empa sowie Life Cycle Consulting Althaus mit Unterstützung der SATW einen Workshop zum Thema «Daten-Netzwerk für kritische Rohstoffe». Der Terminus «kritische Rohstoffe» bezieht sich auf die von der Europäischen Union definierten Rohstoffe, hauptsächlich Metalle, die in Zukunft für den Wirtschaftsstandort dringend gebraucht werden, die aber aufgrund ihres Versorgungsrisikos ein Risiko für Europas Wirtschaft darstellen – zum Beispiel die Seltenen Erdelemente, aber auch Elemente wie Indium, Kobalt, Wolfram und viele andere. Workshop «Daten-Netzwerk kritische Rohstoffe» Teilnehmende aus Forschung, Industrie, mittelständischen Unternehmen, Verbänden und Politik diskutierten Möglichkeiten, wie die Schweiz auf drohende Versorgungsengpässe mit kritischen Rohstoffen reagieren kann. Moderierte Diskussionsgruppen befassten sich mit dem Einfluss kritischer Rohstoffe auf den Schweizer und den europäischen Markt. Sie identifizierten Hindernisse für eine adäquate Priorisierung des Themas in Unternehmen sowie relevante Akteure und besprachen Möglichkeiten, mehr Transparenz im Bereich kritischer Rohstoffe zu schaffen. Als grösste Herausforderung wurde nicht ein Mangel an Daten identifiziert, sondern ein unübersichtlicher Informationsfluss und fehlende Möglichkeiten für Firmen, sich individuell zu informieren sowie mangelndes Wissen über Strategien, wie mit Rohstoffknappheit umgegangen werden kann. Die grösste Herausforderung für die Schweiz und Europa besteht darin, das Bewusstsein für die Problematik der sicheren Verfügbarkeit kritischer Rohstoffe zu erhöhen. Die Kurzbroschüre bietet einen Überblick über das Thema mit speziellem Fokus auf die Schweiz