259 research outputs found
Methanol in the sky with diamonds
The present of gas phase methanol in dense interstellar molecular clouds was established by radio detection of its rotational emission lines. However, the position, width, and profile of a absorption band near 1470 cm(exp -1) in the IR spectra of many dense molecular clouds strongly suggests that solid methanol is an important component of interstellar ices. In an attempt to better constrain the identification of 1470 cm(exp -1) feature, we began a program to search for other characteristic absorption bands of solid state methanol in the spectra of objects known to produce this band. One such feature is now identified in the spectra of several dense molecular clouds and its position, width, and profile fit well with those of laboratory H2O:CH3OH ices. Thus, the presence of methanol-bearing ices in space is confirmed
Laboratory and observational study of the interrelation of the carbonaceous component of interstellar dust and solar system materials
By studying the chemical and isotopic composition of interstellar ice and dust, one gains insight into the composition and chemical evolution of the solid bodies in the solar nebula and the nature of the material subsequently brought into the inner part of the solar system by comets and meteorites. It is now possible to spectroscopically probe the composition of interstellar ice and dust in the mid-infrared, the spectral range which is most diagnostic of fundamental molecular vibrations. We can compare these spectra of various astronomical objects (including the diffuse and dense interstellar medium, comets, and the icy outer planets and their satellites) with the spectra of analogs we produce in the laboratory under conditions which mimic those in these different objects. In this way one can determine the composition and abundances of the major constituents of the various ices and place general constraints on the types of organics coating the grains in the diffuse interstellar medium. In particular we have shown the ices in the dense clouds contain H2O, CH3OH, CO, perhaps some NH3 and H2CO, we well as nitriles and ketones or esters. Furthermore, by studying the photochemistry of these ice analogs in the laboratory, one gains insight into the chemistry which takes place in interstellar/precometary ices. Chemical and spectroscopic studies of photolyzed analogs (including deuterated species) are now underway. The results of some of these studies will be presented and implications for the evolution of the biogenic elements in interstellar dust and comets will be discussed
Laboratory Determination of the Infrared Band Strengths of Pyrene Frozen in Water Ice: Implications for the Composition of Interstellar Ices
Broad infrared emission features (e.g., at 3.3, 6.2, 7.7, 8.6, and 11.3
microns) from the gas phase interstellar medium have long been attributed to
polycyclic aromatic hydrocarbons (PAHs). A significant portion (10%-20%) of the
Milky Way's carbon reservoir is locked in PAH molecules, which makes their
characterization integral to our understanding of astrochemistry. In molecular
clouds and the dense envelopes and disks of young stellar objects (YSOs), PAHs
are expected to be frozen in the icy mantles of dust grains where they should
reveal themselves through infrared absorption. To facilitate the search for
frozen interstellar PAHs, laboratory experiments were conducted to determine
the positions and strengths of the bands of pyrene mixed with H2O and D2O ices.
The D2O mixtures are used to measure pyrene bands that are masked by the strong
bands of H2O, leading to the first laboratory determination of the band
strength for the CH stretching mode of pyrene in water ice near 3.25 microns.
Our infrared band strengths were normalized to experimentally determined
ultraviolet band strengths, and we find that they are generally ~50% larger
than those reported by Bouwman et al. based on theoretical strengths. These
improved band strengths were used to reexamine YSO spectra published by Boogert
et al. to estimate the contribution of frozen PAHs to absorption in the 5-8
micron spectral region, taking into account the strength of the 3.25 micron CH
stretching mode. It is found that frozen neutral PAHs contain 5%-9% of the
cosmic carbon budget, and account for 2%-9% of the unidentified absorption in
the 5-8 micron region.Comment: Accepted for publication in ApJ on 14 Feb 201
Spectral structure near the 11.3 micron emission feature
If the 11.3 micron emission feature seen in the spectra of many planetary nebulae, H II regions, and reflection nebulae is attributable to polycyclic aromatic hydrocarbons (PAHs), then additional features should be present between 11.3 and 13.0 microns. Moderate resolution spectra of NGC 7027, HD 44179, BD+30 deg 3639, and IRAS 21282+5050 are presented which show evidence for new emission features centered near 12.0 and 12.7 microns. These are consistent with an origin from PAHs and can be used to constrain the molecular structure of the family of PAHs responsible for the infrared features. There is an indication that coronene-like PAHs contribute far more to the emission from NGC 7027 than to the emission from HD 44179. The observed asymmetric profile of the 11.3 micron band in all the spectra is consistent with the slight anharmonicity expected in the C-H out-of-plane bending mode in PAHs. A series of repeating features between 10 and 11 microns in the spectrum of HD 44179 suggests a simple hydride larger than 2 atoms is present in the gas phase in this object
The 5.25 & 5.7 m Astronomical Polycyclic Aromatic Hydrocarbon Emission Features
Astronomical mid-IR spectra show two minor PAH features at 5.25 and 5.7
m (1905 and 1754 cm) that hitherto have been little studied,
but contain information about the astronomical PAH population that complements
that of the major emission bands. Here we report a study involving both
laboratory and theoretical analysis of the fundamentals of PAH spectroscopy
that produce features in this region and use these to analyze the astronomical
spectra. The ISO SWS spectra of fifteen objects showing these PAH features were
considered for this study, of which four have sufficient S/N between 5 and 6
m to allow for an in-depth analysis. All four astronomical spectra show
similar peak positions and profiles. The 5.25 m feature is peaked and
asymmetric, while the 5.7 m feature is broader and flatter. Detailed
analysis of the laboratory spectra and quantum chemical calculations show that
the astronomical 5.25 and 5.7 m bands are a blend of combination,
difference and overtone bands primarily involving CH stretching and CH in-plane
and CH out-of-plane bending fundamental vibrations. The experimental and
computational spectra show that, of all the hydrogen adjacency classes possible
on PAHs, solo and duo hydrogens consistently produce prominent bands at the
observed positions whereas quartet hydrogens do not. In all, this a study
supports the picture that astronomical PAHs are large with compact, regular
structures. From the coupling with primarily strong CH out-of-plane bending
modes one might surmise that the 5.25 and 5.7 m bands track the neutral
PAH population. However, theory suggests the role of charge in these
astronomical bands might also be important.Comment: Accepted ApJ, 40 pages in pre-print, 14 figures, two onlin
The CH out-of-plane bending modes of PAH molecules in astrophysical environments
We present 10-15 micron spectra of a sample of H II regions, YSOs and evolved
stars that show strong unidentified infrared emission features, obtained with
the ISO/SWS spectrograph on-board ISO. These spectra reveal a plethora of
emission features with bands at 11.0, 11.2, 12.0, 12.7, 13.5 and 14.2 micron.
These features are observed to vary considerably in relative strength to
each-other from source to source. In particular, the 10-15 micron spectra of
the evolved stars are dominated by the 11.2 micron band while for H II regions
the 12.7 is typically as strong as the 11.2 micron band. Analysing the ISO data
we find a good correlation between the 11.2 micron band and the 3.3 micron
band, and between the 12.7 micron and the 6.2 micron band. There is also a
correlation between the ratio of the UIR bands to the total dust emission and
the 12.7 over 11.2 micron ratio. Bands in the 10-15 micron spectral region are
due to CH out-of-plane (OOP) bending modes of polycyclic aromatic hydrocarbons
(PAHs). We summarise existing laboratory data and theoretical quantum chemical
calculations of these modes for neutral and cationic PAHs. Due to mode
coupling, the exact peak position of these bands depends on the number of
adjacent CH groups and hence the observed interstellar 10-15 micron spectra can
be used to determine the molecular structure of the interstellar PAHs emitting
in the different regions. We conclude that evolved stars predominantly inject
compact ~100-200 C-atom PAHs into the ISM where they are subsequently
processed, resulting in more open and uneven PAH structures.Comment: 14 pages, 9 figures, accepted for A&
Identifying Organic Molecules in Space: The AstroBiology Explorer (ABE) Mission Concept
The AstroBiology Explorer (ABE) mission concept consists of a dedicated space observatory having a 60 cm class primary mirror cooled to T 2000 of about 1500 objects including galaxies, stars, planetary nebulae, young stellar objects, and solar system objects. Keywords: Astrobiology, infrared, Explorers, interstellar organics, telescope, spectrometer, space, infrared detector
Large Abundances of Polycyclic Aromatic Hydrocarbons in Titan's Upper Atmosphere
In this paper, we analyze the strong unidentified emission near 3.28 micron in Titan's upper daytime atmosphere recently discovered by Dinelli et al.We have studied it by using the NASA Ames PAH IR Spectroscopic Database. The polycyclic aromatic hydrocarbons (PAHs), after absorbing UV solar radiation, are able to emit strongly near 3.3 micron. By using current models for the redistribution of the absorbed UV energy, we have explained the observed spectral feature and have derived the vertical distribution of PAH abundances in Titan's upper atmosphere. PAHs have been found to be present in large concentrations, about (2-3) 10(exp 4) particles / cubic cm. The identified PAHs have 9-96 carbons, with a concentration-weighted average of 34 carbons. The mean mass is approx 430 u; the mean area is about 0.53 sq. nm; they are formed by 10-11 rings on average, and about one-third of them contain nitrogen atoms. Recently, benzene together with light aromatic species as well as small concentrations of heavy positive and negative ions have been detected in Titan's upper atmosphere. We suggest that the large concentrations of PAHs found here are the neutral counterpart of those positive and negative ions, which hence supports the theory that the origin of Titan main haze layer is located in the upper atmosphere
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