63 research outputs found
Glancing angle deposition of sculptured thin metal films at room temperature
Metallic thin films consisting of separated nanostructures are fabricated by evaporative glancing
angle deposition at room temperature. The columnar microstructure of the Ti and Cr columns is
investigated by high resolution transmission electron microscopy and selective area electron
diffraction. The morphology of the sculptured metallic films is studied by scanning electron
microscopy. It is found that tilted Ti and Cr columns grow with a single crystalline morphology,
while upright Cr columns are polycrystalline. Further, the influence of continuous substrate
rotation on the shaping of Al, Ti, Cr and Mo nanostructures is studied with view to surface
diffusion and the shadowing effect. It is observed that sculptured metallic thin films deposited
without substrate rotation grow faster compared to those grown with continuous substrate
rotation. A theoretical model is provided to describe this effec
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Glancing angle deposition of sculptured thin metal films at room temperature
Metallic thin films consisting of separated nanostructures are fabricated by evaporative glancing angle deposition at room temperature. The columnar microstructure of the Ti and Cr columns is investigated by high resolution transmission electron microscopy and selective area electron diffraction. The morphology of the sculptured metallic films is studied by scanning electron microscopy. It is found that tilted Ti and Cr columns grow with a single crystalline morphology, while upright Cr columns are polycrystalline. Further, the influence of continuous substrate rotation on the shaping of Al, Ti, Cr and Mo nanostructures is studied with view to surface diffusion and the shadowing effect. It is observed that sculptured metallic thin films deposited without substrate rotation grow faster compared to those grown with continuous substrate rotation. A theoretical model is provided to describe this effect
Pattern transfer of sub-micrometre-scaled structures into solid copper by laser embossing
Laser embossing allows the micron and submicron patterning of metal substrates that is of great interest in a wide range of applications. This replication process enables low-cost patterning of metallic materials by non-thermal, high-speed forming which is driven by laser-induced shock waves. In this study the surface topography characteristics as well as the material structure at laser embossing of sub-micrometre gratings into solid copper is presented. The topography of the laser-embossed copper pattern is analysed with atomic force microscopy (AFM) in comparison to the master surface. The height of the embossed structures and the replicated pattern fidelity increases up to a laser fluence of F ∼ 10 J/cm2. For higher laser fluences the height of the embossed structures saturates at 75% of the master pattern height and the shape is adequate to the master. Structural modifications in the copper mono crystals after the laser embossing process were investigated with transmission electron microscopy (TEM) and electron backscatter diffraction (EBSD). Almost no modifications were detected. The residual stress after laser embossing of 32 MPa (F = 30 J/cm2) has only a limited influence on the surface pattern formation
Ion-irradiation-assisted tuning of phase transformations and physical properties in single crystalline Fe₇Pd₃ ferromagnetic shape memory alloy thin films
Control of multi-martensite phase transformations and physical properties constitute greatly unresolved challenges in Fe7Pd3-based ferromagnetic shape memory alloys. Single crystalline Fe7Pd3 thin films reveal an austenite to martensite phase transformation, continuously ranging from the facecentered cubic (fcc) to the face-centered tetragonal (fct) and body-centered cubic (bcc) phases upon irradiation with 1.8 MeV Kr+ ions. Within the present contribution, we explore this scenario within a comprehensive experimental study: employing atomic force microscopy (AFM) and high resolution transmission electron microscopy (HR-TEM), we first clarify the crystallography of the ionirradiation-induced austenite⇒martensite and inter-martensite transitions, explore the multivariant martensite structures with c-a twinning and unravel a very gradual transition between variants at twin boundaries. Accompanying magnetic properties, addressed locally and globally, are characterized by an increasing saturation magnetization from fcc to bcc, while coercivity and remanence are demonstrated to be governed by magnetocrystalline anisotropy and ion-irradiationinduced defect density, respectively. Based on reversibility of ion-irradiation-induced materials changes due to annealing treatment and a conversion electron Mößbauer spectroscopy (CEMS) study to address changes in order, a quantitative defect-based physical picture of ion-irradiation-induced austenite⇔martensite transformation in Fe7Pd3 is developed. The presented concepts thus pave the way for ion-irradiation-assisted optimization strategies for tailored functional alloys
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Ion-irradiation-assisted tuning of phase transformations and physical properties in single crystalline Fe7Pd3ferromagnetic shape memory alloy thin films
Control of multi-martensite phase transformations and physical properties constitute greatly unresolved challenges in Fe7Pd3-based ferromagnetic shape memory alloys. Single crystalline Fe7Pd3 thin films reveal an austenite to martensite phase transformation, continuously ranging from the face-centered cubic (fcc) to the face-centered tetragonal (fct) and body-centered cubic (bcc) phases upon irradiation with 1.8 MeV Kr+ ions. Within the present contribution, we explore this scenario within a comprehensive experimental study: employing atomic force microscopy (AFM) and high resolution transmission electron microscopy (HR-TEM), we first clarify the crystallography of the ion-irradiation-induced austenite martensite and inter-martensite transitions, explore the multi-variant martensite structures with c-a twinning and unravel a very gradual transition between variants at twin boundaries. Accompanying magnetic properties, addressed locally and globally, are characterized by an increasing saturation magnetization from fcc to bcc, while coercivity and remanence are demonstrated to be governed by magnetocrystalline anisotropy and ion-irradiation-induced defect density, respectively. Based on reversibility of ion-irradiation-induced materials changes due to annealing treatment and a conversion electron Mößbauer spectroscopy (CEMS) study to address changes in order, a quantitative defect-based physical picture of ion-irradiation-induced austenite ⇔ martensite transformation in Fe7Pd3 is developed. The presented concepts thus pave the way for ion-irradiation-assisted optimization strategies for tailored functional alloys
Evolution of the fishtail-effect in pure and Ag-doped MG-YBCO
We report on magnetic measurements carried out in a textured
YBaCuO and YBa(CuAg)O (at
0.02) crystals. The so-called fishtail-effect (FE) or second
magnetization peak has been observed in a wide temperature range
0.4~~0.8 for . The origin of the FE arises for
the competition between surface barrier and bulk pinning. This is confirmed in
a non-monotonically behavior of the relaxation rate . The value
for Ag-doped crystals is larger than for the pure one due to the presence of
additional pinning centers, above all on silver atoms.Comment: 6 pages, 6 figure
Thermal transport of helium-3 in a strongly confining channel
In a neutral system such as liquid helium-3, transport of mass, heat, and
spin provide information analogous to electrical counterparts in metals,
superconductors and topological materials. Of particular interest is transport
in strongly confining channels of height approaching the superfluid coherence
length, where new quantum states are found and excitations bound to surfaces
and edges should be present. Here we report on the thermal conduction of
helium-3 in a 1.1~m high microfabricated channel. In the normal state we
observe a diffusive thermal conductivity that is approximately temperature
independent, consistent with recent work on the interference of bulk and
boundary scattering. In the superfluid state we measure diffusive thermal
transport in the absence of thermal counterflow. An anomalous thermal response
is also detected in the superfluid which we suggest may arise from a flux of
surface excitations.Comment: A supplement is available. Please contact Jeevak Parpia
([email protected]) if you would like the supplement as wel
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