775 research outputs found

    Covert Ephemeral Communication in Named Data Networking

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    In the last decade, there has been a growing realization that the current Internet Protocol is reaching the limits of its senescence. This has prompted several research efforts that aim to design potential next-generation Internet architectures. Named Data Networking (NDN), an instantiation of the content-centric approach to networking, is one such effort. In contrast with IP, NDN routers maintain a significant amount of user-driven state. In this paper we investigate how to use this state for covert ephemeral communication (CEC). CEC allows two or more parties to covertly exchange ephemeral messages, i.e., messages that become unavailable after a certain amount of time. Our techniques rely only on network-layer, rather than application-layer, services. This makes our protocols robust, and communication difficult to uncover. We show that users can build high-bandwidth CECs exploiting features unique to NDN: in-network caches, routers' forwarding state and name matching rules. We assess feasibility and performance of proposed cover channels using a local setup and the official NDN testbed

    Biotechnology to develop innovative syntheses using CO2

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    We present an overview of possible biotechnological applications for using carbon dioxide for the synthesis of chemicals. These approaches are very appealing as they contribute to the implementation of new synthetic methodologies that reduce waste and make a better use of carbon and energy. Several synthetic approaches will be considered including both the incorporation of the whole COO moiety or its reduction to other C1 molecules. Each option will be discussed making a comparison between the natural and artificial process in order to highlight the possibility to learn from Nature and develop useful mimetic or enzymatic systems

    Shedding Light On Dark Pools: Recent Regulatory Attempts Toward Transparency And Oversight Of Alternative Trading Systems

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    The article focuses on dark pools wherein a small group of investors engage in investments among themselves bypassing the ordinary mode of use of stock exchanges. In additional, a brief discussion of high speed trading is included. Pros and cons of dark pools, and their regulation are highlighted .together with future regulatory trends

    Synthesis and characterization of p-n junction ternary mixed oxides for photocatalytic coprocessing of CO2 and H2O

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    In the present paper, we report the synthesis and characterization of both binary (Cu2 O, Fe2 O3, and In2 O3 ) and ternary (Cu2 O-Fe2 O3 and Cu2 O-In2 O3 ) transition metal mixed-oxides that may find application as photocatalysts for solar driven CO2 conversion into energy rich species. Two different preparation techniques (High Energy Milling (HEM) and Co-Precipitation (CP)) are compared and materials properties are studied by means of a variety of characterization and analytical techniques UV-Visible Diffuse Reflectance Spectroscopy (UV-VIS DRS), X-ray Photoelectron Spectroscopy (XPS), X-Ray Diffraction (XRD), Transmission Electron Microscopy (TEM), and Energy Dispersive X-Ray spectrometry (EDX). Appropriate data elaboration methods are used to extract materials bandgap for Cu2 O@Fe2 O3 and Cu2 O@In2 O3 prepared by HEM and CP, and foresee whether the newly prepared semiconductor mixed oxides pairs are useful for application in CO2-H2 O coprocessing. The experimental results show that the synthetic technique influences the photoactivity of the materials that can correctly be foreseen on the basis of bandgap experimentally derived. Of the mixed oxides prepared and described in this work, only Cu2 O@In2 O3 shows positive results in CO2-H2 O photo-co-processing. Preliminary results show that the composition and synthetic methodologies of mixed-oxides, the reactor geometry, the way of dispersing the photocatalyst sample, play a key role in the light driven reaction of CO2 –H2 O. This work is a rare case of full characterization of photo-materials, using UV-Visible DRS, XPS, XRD, TEM, EDX for the surface and bulk analytical characterization. Surface composition may not be the same of the bulk composition and plays a key role in photocatalysts behavior. We show that a full material knowledge is necessary for the correct forecast of their photocatalytic behavior, inferred from experimentally determined bandgaps

    Well-posedness for a class of nonlinear degenerate parabolic equations

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    In this paper we obtain well-posedness for a class of semilinear weakly degenerate reaction-diffusion systems with Robin boundary conditions. This result is obtained through a Gagliardo-Nirenberg interpolation inequality and some embedding results for weighted Sobolev spaces

    Effects of Synaptic and Myelin Plasticity on Learning in a Network of Kuramoto Phase Oscillators

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    Models of learning typically focus on synaptic plasticity. However, learning is the result of both synaptic and myelin plasticity. Specifically, synaptic changes often co-occur and interact with myelin changes, leading to complex dynamic interactions between these processes. Here, we investigate the implications of these interactions for the coupling behavior of a system of Kuramoto oscillators. To that end, we construct a fully connected, one-dimensional ring network of phase oscillators whose coupling strength (reflecting synaptic strength) as well as conduction velocity (reflecting myelination) are each regulated by a Hebbian learning rule. We evaluate the behavior of the system in terms of structural (pairwise connection strength and conduction velocity) and functional connectivity (local and global synchronization behavior). We find that for conditions in which a system limited to synaptic plasticity develops two distinct clusters both structurally and functionally, additional adaptive myelination allows for functional communication across these structural clusters. Hence, dynamic conduction velocity permits the functional integration of structurally segregated clusters. Our results confirm that network states following learning may be different when myelin plasticity is considered in addition to synaptic plasticity, pointing towards the relevance of integrating both factors in computational models of learning.Comment: 39 pages, 15 figures This work is submitted in Chaos: An Interdisciplinary Journal of Nonlinear Scienc

    Comparative life cycle assessment study on environmental impact of oil production from micro-algae and terrestrial oilseed crops

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    In this study the LCA methodology is applied in order to satisfy two goals: i) to evaluate the hot spots in site-specific production chain of biodiesel from terrestrial and micro-algae feedstock; ii) to compare quantitatively, utilizing primary data, the impacts of the first generation in respect to the third generation bio-fuels. Results show that micro-algae are neither competitive yet with traditional oil crops nor with fossil fuel. The use of renewable technologies as photovoltaics and biogas self production might increase the competitiveness of micro-algae oil. Further investigations are however necessary to optimize their production chain and to increase the added value of co-products

    Selective Aerobic Oxidation of 5-Hydroxymethylfurfural to 2,5-Diformylfuran or 2-Formyl-5-furancarboxylic Acid in Water by using MgOâ‹…CeO2 Mixed Oxides as Catalysts

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    Mixed oxides based on MgO⋅CeO2 were used as efficient catalysts in the aerobic oxidation of 5-hydroxymethylfurfural (5-HMF) to afford, with very high selectivity, either 2,5-diformylfuran (DFF, 99 %) or 2-formyl-5-furancarboxylic acid (FFCA, 90 %), depending on the reaction conditions. 5-Hydroxymethyl-2-furancarboxylic acid (HMFCA, 57–90 %) was formed only at low concentration of 5-HMF (<0.03 m) or in presence of external bases. The conversion of 5-HMF ranged from a few percent to 99 %, according to the reaction conditions. The oxidation was performed in water, with O2 as oxidant, without any additives. The surface characterization of the catalysts gave important information about their acid–base properties, which drive the selectivity of the reaction towards DFF. FFCA was formed from DFF at longer reaction times. Catalysts were studied by XPS and XRD before and after catalytic runs to identify the reason why they undergo reversible deactivation. XRD showed that MgO is hydrated to Mg(OH)2, which, even if not leached out, changes the basic properties of the catalyst that becomes less active after some time. Calcination of the recovered catalyst allows recovery of its initial activity. The catalyst is thus recoverable (>99 %) and reusable. The use of mixed oxides allows tuning of the basicity of the catalysts, avoiding the need for external bases for efficient and selective conversion of 5-HMF and waste formation, resulting in an environmentally friendly, sustainable process
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