19 research outputs found

    λΆˆλ³€ 츑도와 이토 ν™•λ₯ λ―ΈλΆ„방정식에 λŒ€ν•œ 해석적 μ ‘κ·Ό

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    ν•™μœ„λ…Όλ¬Έ(박사)--μ„œμšΈλŒ€ν•™κ΅ λŒ€ν•™μ› :μžμ—°κ³Όν•™λŒ€ν•™ μˆ˜λ¦¬κ³Όν•™λΆ€,2019. 8. Gerald Trutnau.In this thesis, we study an analytic approach to global well-posedness and long-time behavior for weak solutions to ItΓ΄-SDEs with rough coefficients. Using elliptic and parabolic regularity theory and generalized Dirichlet form theory, we show existence of a pre-invariant measure for a large class of elliptic second order partial differential operators and show that these are in fact infinitesimal generators of a Hunt process. Subsequently, this Hunt process is identified for every starting point as a weak solution to an ItΓ΄-SDE in R^d up to its explosion time. The Hunt process has continuous sample paths on the one-point compactification of R^d and by a known local well-posedness result, it is a pathwise unique and strong solution up to its explosion time to the SDE that it weakly solves. Using analytic and probabilistic methods, we derive general strong Feller properties, including the classical strong Feller property, Krylov type estimates, moment inequalities and various non-explosion criteria. Using a parabolic Harnack inequality, we show irreducibility and strict irreducibility of the process and derive explicit conditions for recurrence and ergodic behavior. Moreover, we investigate well-posedness of weak solutions to ItΓ΄-SDEs with degenerate and rough diffusion coefficients whose points of degeneracy form a set of Lebesegue measure zero. In the final part we consider the case where the pre-invariant density is explicitly given. In contrast to the previous case, where we only knew its existence with a certain regularity, we investigate how far our previous methods can be extended and applied in case of a non-degenerate, possibly non-symmetric and discontinuous diffusion matrix. For this, we develop some variational approach to regularity theory for linear parabolic PDEs involving divergence form operators with weight in the term where time derivative appear.이 λ…Όλ¬Έμ—μ„œ μš°λ¦¬λŠ” 거친 κ³„μˆ˜λ₯Ό κ°–λŠ” 이토 ν™•λ₯ λ―ΈλΆ„λ°©μ •μ‹μ˜ μ•½ν•œ ν•΄λ“€μ˜ λŒ€μ—­μ μΈ 쑴재 및 μœ μΌμ„±, μž₯μ‹œκ°„μ˜ 행동에 λŒ€ν•œ 해석학적 접근을 μ—°κ΅¬ν•œλ‹€. νƒ€μ›ν˜• 및 ν¬λ¬Όν˜• μ •μΉ™μ„± 이둠과 μΌλ°˜ν™”λœ λ””λ¦¬ν΄λ ˆ ν˜•μ‹ 이둠을 μ‚¬μš©ν•¨μœΌλ‘œμ¨, μš°λ¦¬λŠ” 넓은 μœ ν˜•μ˜ νƒ€μ›ν˜• 2계 νŽΈλ―ΈλΆ„ μž‘μš©μ†Œμ˜ μ˜ˆλΉ„ λΆˆλ³€μΈ‘λ„μ˜ μ‘΄μž¬μ„±μ„ 보이고, κ·Έ μž‘μš©μ†ŒλŠ” 사싀은 μ–΄λŠ ν—ŒνŠΈ κ³Όμ •μ˜ κ·Ήμ†Œ μƒμ„±μžκ°€ 됨을 보인닀. κ·Έ ν›„, 이 ν—ŒνŠΈ 과정은 R^d μœ„μ˜ λͺ¨λ“  점듀을 μ‹œμž‘μ μœΌλ‘œ κ°–λŠ” 이토 ν™•λ₯ λ―ΈλΆ„λ°©μ •μ‹μ˜ 폭발 μ‹œκ°„ μ•ˆμ—μ„œ μ•½ν•œ ν•΄λ‘œ λ™μΌμ‹œλœλ‹€. κ·Έ ν—ŒνŠΈ ν”„λ‘œμ„ΈμŠ€λŠ” R^d의 ν•œμ  μ»΄νŒ©νŠΈν™”λœ κ³΅κ°„μ—μ„œ 연속인 μƒ˜ν”Œ 경둜λ₯Ό κ°–κ³  μ•Œλ €μ§„ 쑴재 및 μœ μΌμ„± 정리에 μ˜ν•΄ 그것은 폭발 μ‹œκ°„ μ•ˆμ—μ„œ κ²½λ‘œλ§ˆλ‹€ μœ μΌν•œ κ°•ν•œ ν•΄κ°€ λœλ‹€. 해석학적, ν™•λ₯ λ‘ μ  방법을 μ‚¬μš©ν•˜μ—¬ μš°λ¦¬λŠ” 고전적인 κ°•ν•œ 펠러 μ„±μ§ˆμ„ ν¬ν•¨ν•˜λŠ” μΌλ°˜ν™”λœ κ°•ν•œ 펠러 μ„±μ§ˆλ“€, ν¬λ¦΄λ‘œν”„ μœ ν˜•μ˜ κ°€λŠ , λͺ¨λ¨ΌνŠΈ 뢀등식, λ‹€μ–‘ν•œ λΉ„ν­λ°œ νŒμ •λ²•μ„ μœ λ„ν•œλ‹€. ν¬λ¬Όν˜• ν•˜λ₯΄λ‚™ 뢀등식을 μ΄μš©ν•˜μ—¬ μš°λ¦¬λŠ” ν”„λ‘œμ„ΈμŠ€μ˜ κΈ°μ•½μ„±κ³Ό κ°•ν•œ 기약성을 보이고 μž¬κ·€μ„±κ³Ό 에λ₯΄κ³ λ”• 행동듀에 λŒ€ν•œ λͺ…ν™•ν•œ 쑰건듀을 μ΄λŒμ–΄ λ‚Έλ‹€. 더 λ‚˜μ•„κ°€μ„œ μš°λ¦¬λŠ” ν‡΄ν™”λœ μ •λ„μ˜ 점듀이 λ₯΄λ²‘ 츑도 0을 λ§Œμ‘±ν•˜λŠ” ν‡΄ν™”λœ 거친 ν™•μ‚° κ³„μˆ˜μ— κ΄€ν•œ 이토 ν™•λ₯ λ―ΈλΆ„λ°©μ •μ‹μ˜ μ•½ν•œ ν•΄μ˜ μ‘΄μž¬μ„±κ³Ό μœ μΌμ„±μ„ μ‘°μ‚¬ν•œλ‹€. λ§ˆμ§€λ§‰μœΌλ‘œ μš°λ¦¬λŠ” μ˜ˆλΉ„ λΆˆλ³€μΈ‘λ„μ˜ λ°€λ„ν•¨μˆ˜κ°€ λͺ…ν™•νžˆ μ£Όμ–΄μ‘Œμ„ λ•Œλ₯Ό κ³ λ €ν•œλ‹€. λ‹¨μˆœνžˆ κ·Έ μ˜ˆλΉ„μΈ‘λ„μ˜ μ‘΄μž¬μ„±κ³Ό μ–΄λ–€ μ •μΉ™μ„±λ§Œ μ•Œμ•˜λ˜ μ΄μ „μ˜ κ²½μš°μ™€λŠ” 달리, μš°λ¦¬λŠ” ν‡΄ν™”λ˜μ§€ μ•Šμ€ λΉ„λŒ€μΉ­, λΆˆμ—°μ† ν™•μ‚° 행렬인 κ²½μš°μ— μ–Όλ§ˆλ‚˜ 우리의 방법듀이 ν™•μž₯되고 적용될 수 μžˆλŠ”μ§€ μ‘°μ‚¬ν•œλ‹€. 이λ₯Ό μœ„ν•΄ μš°λ¦¬λŠ” μ‹œκ°„ 텀에 무게λ₯Ό κ°–λŠ” λ°œμ‚° ν˜•μ‹ μ„ ν˜• ν¬λ¬Όν˜• νŽΈλ―ΈλΆ„λ°©μ •μ‹μ˜ 정칙이둠에 λŒ€ν•œ 변뢄적 접근을 λ°œμ „μ‹œν‚¨λ‹€.Abstract 1 Introduction . . . . . . 1 2 Notations . . . . . . 15 I Existence, uniqueness and ergodic properties for time-homogeneous ItΓ΄-SDEs with locally integrable drifts and Sobolev diffusion coefficients . . . . . . 19 3 Weak solutions via analytic theory . . . . . . 20 3.1 Analytic theory of generalized Dirichlet forms . . . . . . 20 3.2 Construction of a weak solution . . . . . . 37 4 Conservativeness and ergodic properties . . . . . . 47 4.1 Non-explosion criteria and moment inequalities . . . . . . 47 4.1.1 Non-explosion criteria and moment inequalities without involving the density . . . . . . 47 4.1.2 Non-explosion criteria involving the density . . . . . . 54 4.2 Recurrence criteria and other ergodic properties involving and not involving the density . . . . . . 55 4.2.1 Explicit recurrence criteria for possibly infinite m . . . . . . 60 4.2.2 Uniqueness of invariant measures and ergodic properties in case m is a probability measure . . . . . . 63 4.3 An application to pathwise uniqueness and strong solutions . . . . . . 68 II Existence and regularity of pre-invariant measures, transition functions and time homogeneous ItΓ΄-SDEs . . . . . . 69 5 Analytic results . . . . . . 70 5.1 Elliptic H^{1,p}-regularity and estimates . . . . . . 70 5.2 Existence of a pre-invariant measure and construction of a generalized Dirichlet form . . . . . . 77 5.3 Regularity results for resolvent and semigroup . . . . . . 83 6 Probabilistic results . . . . . . 88 6.1 The underlying SDE . . . . . . 88 6.2 Uniqueness in law under low regularity . . . . . . 93 III Well-posedness for ItΓ΄-SDEs with degenerate and rough diffusion coefficients . . . . . . 96 7 Regularity of solutions . . . . . . 97 7.1 Regularity results for linear parabolic equation with singular weight in the time derivative term . . . . . . 97 7.2 Elliptic HΓΆlder regularity and estimates . . . . . . 105 8 Analytic theory for degenerate second order partial differential operators . . . . . . 108 8.1 Framework . . . . . . 108 8.2 L^1-existence results . . . . . . 111 8.3 Existence of a pre-invariant measure and general strong Feller properties . . . . . . 131 8.4 Some auxiliary results . . . . . . 140 9 Well-posedness and irreducibility for degenerate ItΓ΄-SDEs . . . . . . 148 9.1 Weak existence of degenerate ItΓ΄-SDEs with rough coefficients . . . . . . 148 9.2 Strict irreducibility for special weight functions . . . . . . 151 9.3 Uniqueness in law for degenerate ItΓ΄-SDEs with discontinuous dispersion coefficients . . . . . . 156 IV Existence and regularity of transition functions with general pre-invariant measures and corresponding ItΓ΄-SDEs . . . . . . 171 10 Regularity results for weighted parabolic PDEs . . . . . . 172 10.1 L^1-estimate in terms of the L^2-norm . . . . . . 175 10.2 Parabolic Harnack inequality . . . . . . 179 11 Analytic and probabilistic results . . . . . . 193 11.1 Strong Feller property and irreducibility with general pre-invariant measures . . . . . . 193 11.2 Application to weak existence of ItΓ΄-SDEs . . . . . . 202 11.3 Explicit conditions for global well-posedness and ergodic properties . . . . . . 204 Abstract (in Korean) . . . . . . 215 Acknowledgement . . . . . . 216Docto

    A Study on the Development Strategy of Ulsan Port Authority using SWOT/AHP Analysis

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    λ³Έ μ—°κ΅¬λŠ” κ΅­λ‚΄μ™Έ ν™˜κ²½λ³€ν™”μ— 맞좰 μšΈμ‚°ν•­λ§Œκ³΅μ‚¬κ°€ μ–΄λ–»κ²Œ 경쟁λ ₯을 ν™•λ³΄ν•˜λ©°, μ–΄λ–€ λ°©λ²•μœΌλ‘œ 지속적인 μ„±μž₯을 좔ꡬ할 것이며, 이λ₯Ό μœ„ν•΄ μ–΄λ–€ 쀑μž₯κΈ° λ°œμ „λ°©μ•ˆμ„ μˆ˜λ¦½ν•΄μ•Ό ν•˜λŠ”μ§€λ₯Ό ꡬ체적으둜 μ œμ‹œν•˜μ˜€λ‹€. μšΈμ‚°ν•­λ§Œκ³΅μ‚¬μ˜ λ°œμ „λ°©μ•ˆμ„ μ‹€ν˜„ν•˜κΈ° μœ„ν•˜μ—¬, SWOT/AHP 뢄석을 μ΄μš©ν•˜μ˜€μœΌλ©°, 싀증뢄석을 λ°”νƒ•μœΌλ‘œ μšΈμ‚°ν•­λ§Œκ³΅μ‚¬μ˜ μ „λž΅μ  λ°œμ „λ°©μ•ˆμ„ μš°μ„ μˆœμœ„λ³„λ‘œ S/Oμ „λž΅, W/Oμ „λž΅, S/Tμ „λž΅, W/Tμ „λž΅ 순으둜 μˆ˜λ¦½ν•˜μ—¬ μ œμ‹œν•˜κ³ , 4λŒ€μ „λž΅κ³Ό 10λŒ€ μΆ”μ§„κ³Όμ œλ₯Ό μ„€μ •ν•˜κ³  2μ°¨ AHP 뢄석을 ν†΅ν•˜μ—¬ μΆ”μ§„κ³Όμ œλ₯Ό μ œμ‹œν•˜μ˜€λ‹€. This paper aims to propose practical and effective research result which can contribute to fulfill the strategy od Ulsan Port Authority, ultimately proposing tasks and strategies of development plan to the policy maker to make the right decision. In order to find out the optimal strategies of Ulsan Port Authory, The paper offers a systematic approach and analytical means with a combination of SWOT/AHP that can enhance stakeholders' and decision makers' understanding of the problem and help in the definition of solution objectives and constraints.1. μ„œλ‘  2. 이둠적 λ°°κ²½ 및 선행연ꡬ κ³ μ°° 3. SWOT/AHP λͺ¨ν˜•κ΅¬μΆ• 4. μšΈμ‚°ν•­λ§Œκ³΅μ‚¬ ν˜„ν™© 및 SWOT/AHP 뢄석 5. μšΈμ‚°ν•­λ§Œκ³΅μ‚¬ λ°œμ „λ°©μ•ˆ 6. κ²°λ‘  μ°Έκ³ λ¬Έν—Œ λΆ€

    ν‰μ—”λ“œλ°€μ˜ κ³΅κ΅¬λ³€ν˜•μ— μ˜ν•œ 평면도 μ˜€μ°¨μ— κ΄€ν•œ 연ꡬ

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    ν•™μœ„λ…Όλ¬Έ(석사)--μ„œμšΈλŒ€ν•™κ΅ λŒ€ν•™μ› :기계섀계학과,1999.Maste

    (An) economic evaluation on domestic importation of a newborn hearing screening

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    보건정책및관리학과/석사[ν•œκΈ€] λ ₯μž₯μ• λŠ” ν˜„μž¬ λ°œκ²¬λ˜λŠ” μ„ μ²œμ„± μ§ˆν™˜ 쀑 λ°œν˜„ λΉˆλ„κ°€ 높은 μž₯μ• μ˜ ν•˜λ‚˜λ‘œ, κ°€λŠ₯ν•œ ν•œ 쑰기에 λ°œκ²¬ν•˜μ—¬ μ μ ˆν•œ 치료λ₯Ό μ œκ³΅ν•˜κ³ , κ·Έ 결과에 따라 μ μ ˆν•œ μœ μ•„νŠΉμˆ˜κ΅μœ‘ μ„œλΉ„μŠ€λ₯Ό μ œκ³΅ν•¨μœΌλ‘œμ¨ μ΄λ“€μ˜ μž₯μ• λ₯Ό μ˜ˆλ°©ν•˜κ±°λ‚˜ μ΅œμ†Œν™”ν•  수 μžˆλ‹€. λ³Έ μ—°κ΅¬λŠ” 2000λ…„ ν•œ ν•΄ λ™μ•ˆ μΆœμƒν•˜λŠ” λͺ¨λ“  신생아 μ€‘μ—μ„œ μΆœμƒ λ‹Ήμ‹œ μΈκ³΅μ™€μš°μ΄μ‹μˆ˜μˆ μ˜ 적응증이 λ˜λŠ” μ–‘μΈ‘ κ³ λ„λ‚œμ²­ ν™˜μžλ₯Ό λŒ€μƒμœΌλ‘œ λΉ„μš©μ„ μ •λΆ€μ˜ κ΄€μ μ—μ„œ μΆ”κ³„ν•˜μ˜€κ³ , μ§μ ‘μ˜λ£ŒλΉ„μš©(신생아 λ‚œμ²­μ„ λ³„κ²€μ‚¬ λΉ„μš©, μΈκ³΅μ™€μš°μ΄μ‹μˆ˜μˆ  μ „ λΉ„μš©, 수술 λΉ„μš©, 수술 ν›„ λΉ„μš©)κ³Ό κ΅μœ‘λΉ„μš©μ„ λΉ„μš©μΆ”κ³„μ— ν¬ν•¨ν•˜μ˜€λ‹€. 연ꡬ κ²°κ³Ό 2000년을 κΈ°μ€€μœΌλ‘œ ν•˜μ˜€μ„ λ•Œ, μ—°κ°„ 총 신생아 μˆ˜λŠ” 494,625λͺ…, μ—°κ°„ μ„ μ²œμ„± λ‚œμ²­μ•„ μˆ˜λŠ” 494.625λͺ…, μ—°κ°„ μ„ λ³„κ²€μ‚¬μ—μ„œ λ†“μΉœ μ„ μ²œμ„± λ‚œμ²­μ•„ μˆ˜λŠ” 24.73125λͺ…, μ—°κ°„ μ„ λ³„κ²€μ‚¬μ—μ„œ λ‚œμ²­μœΌλ‘œ μ§„λ‹¨λœ 정상아 μˆ˜λŠ” 49,413.03750λͺ…μœΌλ‘œ μΆ”κ³„λ˜μ—ˆλ‹€. μ—°κ°„ μ†Œμš”λ˜λŠ” μ„ μ²œμ„± λ‚œμ²­ μ„ λ³„κ²€μ‚¬λΉ„μš©μ€ 3,960,957,000원, μΈκ³΅μ™€μš°μ΄μ‹μˆ˜μˆ κ³Ό κ΄€λ ¨λ˜μ–΄ μ†Œμš”λ˜λŠ” λΉ„μš©μ€ 11,862,097,000μ›μœΌλ‘œ μΆ”κ³„λ˜μ—ˆλ‹€. λ˜ν•œ νŠΉμˆ˜ν•™κ΅μ—μ„œ λ‚œμ²­ν•™μƒ 1인당 κ΅μœ‘μ— μ†Œμš”λ˜λŠ” λΉ„μš©μ€ 61,836,257.67원, μΌλ°˜ν•™κ΅μ—μ„œ λ‚œμ²­ν•™μƒ 1인당 κ΅μœ‘μ— μ†Œμš”λ˜λŠ” λΉ„μš©μ€ 13,325,769.18μ›μœΌλ‘œ μΆ”κ³„λ˜μ—ˆλ‹€. 결둠적으둜 ν˜„μž¬μ™€ 같이 μΆœμƒ λ‹Ήμ‹œ 신생아 λ‚œμ²­μ„ λ³„κ²€μ‚¬λ₯Ό μ‹œν–‰ν•˜μ§€ μ•ŠλŠ” 경우 μ˜λ£ŒλΉ„μš©μ€ 13,076,512,000원, κ΅μœ‘λΉ„μš©μ€ 26,986,584,000원(총 40,063,096,000원)이 μ†Œμš”λœλ‹€κ³  μΆ”κ³„λ˜μ—ˆμœΌλ©°, μΆœμƒ λ‹Ήμ‹œ 신생아 λ‚œμ²­μ„ λ³„κ²€μ‚¬λ₯Ό μ‹œν–‰ν•˜λŠ” 경우 μ˜λ£ŒλΉ„μš©μ€ 18,463,760,000원, κ΅μœ‘λΉ„μš©μ€ 14,449,457,000원(총 32,913,217,000원)이 μ†Œμš”λœλ‹€κ³  μΆ”κ³„λ˜μ—ˆλ‹€. κ²°κ΅­ μš°λ¦¬λ‚˜λΌμ—μ„œλ„ μ™Έκ΅­κ³Ό λ§ˆμ°¬κ°€μ§€λ‘œ 신생아 λ‚œμ²­μ„ λ³„κ²€μ‚¬λ₯Ό μ‹œν–‰ν•¨μœΌλ‘œμ¨ 의료 λΉ„μš©μ€ μ¦κ°€ν•˜μ§€λ§Œ, ꡐ윑 λΉ„μš©μ΄ μƒλŒ€μ μœΌλ‘œ 더 많이 κ°μ†Œν•¨μœΌλ‘œμ¨ 총 λΉ„μš©μ΄ κ°μ†Œν•˜λŠ” κ²°κ³Όλ₯Ό 얻을 수 μžˆμ—ˆλ‹€. λ”°λΌμ„œ μš°λ¦¬λ‚˜λΌμ—μ„œλ„ 선진ꡭ과 λ§ˆμ°¬κ°€μ§€λ‘œ 청각μž₯애아에 λŒ€ν•œ 선별검사λ₯Ό 쑰기에 λ„μž…ν•΄μ•Ό ν•  ν•„μš”μ„±μ΄ μžˆλ‹€. [영문]Hearing disability is one of the highly manipulated diseases in present times that can be minimized or treated by producing an appropriate therapy in the possibly earliest period of time and, further providing them with an appropriate childhood special education. This research has been conducted on all the babies born in 2000 with bilateral hearing loss. The cost of the fees was estimated by the government who has estimated educational fees and direct medical fees such as newborn hearing screening, cochlear implantation, operation during and after. Based on the experiment on 2000, the researchers estimated that there were 494,625 newborn babies in total; however, 494.625 newborn babies had hearing loss, 24.73125 newborn babies had innate hearing loss and missed their annual hearing screen, and 49,413.03750 newborns had hearing loss and were diagnosed by a hearing screen. The estimated annual cost of being diagnosed with the hearing screen was 3,960,957,000 won, and with the cochlear implantation was 11,862,097,000 won. Furthermore, the tuition for education was estimated 61,836,257.67 won for each student with hearing disability in special education schools and 13,325,769.18 won for each student with hearing loss in general schools. From these results, it is concluded that the estimated medical fee without hearing screen during the childbirth is 13,076,512,000 won, and the estimated education fee is 26,986,584,000 won (total 40,063,096,000 won). When the hearing screen is carried out for all newborn babies, the e! stimated amount of the medical fee is 18,493,760,000 won and the tuition is 14,449,457,00 won (total 32, 913,217,000 won). Similar to other foreign countries, the medical fees will likely rise as we provide newborn hearing screens at birth, but the cost of educational fee will decrease and a reduced cost can be obtained from the result in return. Thus, just like other advanced countries, it is also necessary for Korea to give hearing screens to all the newborn babies.ope

    μ‚¬μΆœκΈˆν˜• ν‘œλ©΄μ˜ 체계적 사상가곡

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    Thesis (doctoral)--μ„œμšΈλŒ€ν•™κ΅ λŒ€ν•™μ› :기계항곡곡학뢀,2004.Docto

    Cellulose ester complex material with improved strength under wet condition by modification of terminal group of aqueous plasticizer

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    λ³Έ 발λͺ…은 μˆ˜μš©μ„± κ°€μ†Œμ œμ˜ 말단기 μž¬μ§ˆμ„ 톡해 μŠ΅κ°•λ„κ°€ κ°•ν™”λœ μ…€λ£°λ‘œμ˜€μŠ€ μ—μŠ€ν…Œλ₯΄ λ³΅ν•©μ†Œμž¬μ— κ΄€ν•œ κ²ƒμœΌλ‘œμ„œ, λ”μš± μƒμ„Έν•˜κ²ŒλŠ” μΉœν™˜κ²½ κ°€μ†Œμ œμ˜ μΉœμˆ˜μ„± 말단기λ₯Ό μ†Œμˆ˜μ„±κΈ°μ— μ˜ν•΄ κ°œμ§ˆν•¨μœΌλ‘œμ¨ μ…€λ£°λ‘œμ˜€μŠ€ μ—μŠ€ν…Œλ₯΄ μ†Œμž¬ ν‘œλ©΄μœΌλ‘œμ˜ λ§ˆμ΄κ·Έλ ˆμ΄μ…˜(migration)을 λ°©μ§€ν•˜μ—¬ κ°€μ†Œ μ„±λŠ₯을 μœ μ§€ν•˜κ³  κ³ μŠ΅λ„ μ‘°κ±΄μ—μ„œμ˜ 강도λ₯Ό μœ μ§€ν•  수 μžˆλŠ” μ…€λ£°λ‘œμ˜€μŠ€ μ—μŠ€ν…Œλ₯΄ 볡합 μ†Œμž¬λ₯Ό μ œκ³΅ν•œλ‹€. λ³Έ 발λͺ…에 λ”°λ₯Έ μ…€λ£°λ‘œμ˜€μŠ€ μ—μŠ€ν…Œλ₯΄ 및 개질 κ°€μ†Œμ œλ‘œ 이루어진 λ³΅ν•©μ†Œμž¬λŠ” ν”„νƒˆλ ˆμ΄νŠΈκ³„ κ°€μ†Œμ œμ˜ μ‚¬μš©μ—†μ΄ μΉœν™˜κ²½ κ°€μ†Œμ œλ‘œ μ•Œλ €μ§„ ν΄λ¦¬μ•Œν‚¬λ ŒκΈ€λ¦¬μ½œμ„ λ„μž…ν•¨μœΌλ‘œμ¨ λ°œμ—°ν˜„μƒμ„ κ°μ†Œμ‹œμΌœ 기쑴의 용육 μ••μΆœλΏλ§Œ μ•„λ‹ˆλΌ μ‚¬μΆœ μ„±ν˜•λ„ κ°€λŠ₯ν•˜κ³  기쑴의 ν”„νƒˆλ ˆμ΄νŠΈκ³„ κ°€μ†Œμ œλ₯Ό μ‚¬μš©ν•œ κ²½μš°μ™€ λ™λ“±μˆ˜μ€€ μ΄μƒμ˜ 물성을 μœ μ§€ν•  수 μžˆλŠ” λ™μ‹œμ—, μΉœν™˜κ²½ κ°€μ†Œμ œμΈ ν΄λ¦¬μ•Œν‚¬λ ŒκΈ€λ¦¬μ½œμ˜ 말단기λ₯Ό μ†Œμˆ˜μ„±κΈ°λ‘œ κ°œμ§ˆν•¨μœΌλ‘œμ¨, ν΄λ¦¬μ•Œν‚¬λ ŒκΈ€λ¦¬μ½œμ˜ κ°€μ†Œν™” μ„±λŠ₯을 μœ μ§€ν•˜λ©΄μ„œ μ΅œμ’… μ„±ν˜•μ²΄μ—μ„œμ˜ κ°€μ†Œμ œ λ§ˆμ΄κ·Έλ ˆμ΄μ…˜μ„ μ΅œμ†Œν™”μ‹œμΌœ μŠ΅λ„κ°€ 높은 ν™˜κ²½μ—μ„œλ„ μ €μŠ΅λ„ μ‘°κ±΄μ—μ„œμ™€ 동등 μˆ˜μ€€μ˜ 강도λ₯Ό μœ μ§€ν•  수 μžˆλŠ” νš¨κ³Όκ°€ μžˆλ‹€.μ…€λ£°λ‘œμ˜€μŠ€ μ—μŠ€ν…Œλ₯΄ 및 μ†Œμˆ˜μ„± ν΄λ¦¬μ•Œν‚¬λ ŒκΈ€λ¦¬μ½œμ„ ν¬ν•¨ν•˜λŠ” λ³΅ν•©μ†Œμž¬λ‘œμ„œ,상기 볡합 μ†Œμž¬μ˜ 전체 μ€‘λŸ‰μ— λŒ€ν•΄ 상기 μ…€λ£°λ‘œμ˜€μŠ€ μ—μŠ€ν…Œλ₯΄λŠ” 50 내지 90 μ€‘λŸ‰%, 상기 μ†Œμˆ˜μ„± ν΄λ¦¬μ•Œν‚¬λ ŒκΈ€λ¦¬μ½œμ€ 10 내지 50 μ€‘λŸ‰%λ₯Ό ν•¨μœ ν•˜λ˜,상기 μ…€λ£°λ‘œμ˜€μŠ€ μ—μŠ€ν…Œλ₯΄μ˜ 평균 μΉ˜ν™˜λ„κ°€ 1.6 내지 2.9이고,상기 μ†Œμˆ˜μ„± ν΄λ¦¬μ•Œν‚¬λ ŒκΈ€λ¦¬μ½œμ€ 말단기 쀑 μ•„μ„Έν‹ΈκΈ°μ˜ μΉ˜ν™˜λ„κ°€ 50~99%이며, 상기 μ†Œμˆ˜μ„± ν΄λ¦¬μ•Œν‚¬λ ŒκΈ€λ¦¬μ½œμ˜ μ€‘λŸ‰ν‰κ· λΆ„μžλŸ‰μ΄ 200~1,000인 것을 νŠΉμ§•μœΌλ‘œ ν•˜λŠ” μ…€λ£°λ‘œμ˜€μŠ€ μ—μŠ€ν…Œλ₯΄ 및 μ†Œμˆ˜μ„± ν΄λ¦¬μ•Œν‚¬λ ŒκΈ€λ¦¬μ½œμ„ ν¬ν•¨ν•˜λŠ” λ³΅ν•©μ†Œμž¬λ‘œμ„œ, 상기 μ†Œμˆ˜μ„± ν΄λ¦¬μ•Œν‚¬λ ŒκΈ€λ¦¬μ½œμ€ ν΄λ¦¬μ•Œν‚¬λ ŒκΈ€λ¦¬μ½œκ³Ό λ¬΄μˆ˜μ΄ˆμ‚°μ„ 10 : 1~5의 λͺ°λΉ„λ‘œ νˆ¬μž…ν•˜λ©° 60~90β„ƒμ˜ μ˜¨λ„μ—μ„œ 1~12μ‹œκ°„ λ™μ•ˆ κ΅λ°˜ν•˜μ— λ°˜μ‘μ‹œμΌœ 제쑰되며, 상기 μ…€λ£°λ‘œμ˜€μŠ€ μ—μŠ€ν…Œλ₯΄ 및 μ†Œμˆ˜μ„± ν΄λ¦¬μ•Œν‚¬λ ŒκΈ€λ¦¬μ½œμ„ μš©λ§€μ— μš©ν•΄μ‹œμΌœ μΊμŠ€νŒ…λ²•μœΌλ‘œ ν•„λ¦„ν™”ν•˜μ—¬ 얻어진 필름 μ‹œνŽΈμ˜ 접촉각 ν…ŒμŠ€νŠΈμ— μžˆμ–΄ 앑적을 필름 ν‘œλ©΄μ— νˆ¬μž…ν•œ 경우의 필름 μ‹œνŽΈκ³Ό 앑적 μ‚¬μ΄μ˜ 초기 접촉각이 50도 이상이고, 5λΆ„ κ²½κ³Όμ‹œμ˜ 접촉각이 45도 μ΄μƒμœΌλ‘œ μœ μ§€λ˜λŠ” 것을 νŠΉμ§•μœΌλ‘œ ν•˜λ©°,상기 μ…€λ£°λ‘œμ˜€μŠ€ μ—μŠ€ν…Œλ₯΄ 및 μ†Œμˆ˜μ„± ν΄λ¦¬μ•Œν‚¬λ ŒκΈ€λ¦¬μ½œμ„ μš©λ§€μ— μš©ν•΄μ‹œμΌœ μΊμŠ€νŒ…λ²•μœΌλ‘œ ν•„λ¦„ν™”ν•˜μ—¬ 얻어진 필름 μ‹œνŽΈμ˜ μƒλŒ€ μŠ΅λ„ 80% μ‘°κ±΄ν•˜μ—μ„œ 24 μ‹œκ°„ 체λ₯˜ν•˜μ˜ ASTM D 638에 따라 μΈ‘μ •ν•œ 인μž₯ 강도가 250~350 kg/cm2인 것을 νŠΉμ§•μœΌλ‘œ ν•˜λŠ” μ…€λ£°λ‘œμ˜€μŠ€ μ—μŠ€ν…Œλ₯΄ 및 μ†Œμˆ˜μ„± ν΄λ¦¬μ•Œν‚¬λ ŒκΈ€λ¦¬μ½œμ„ ν¬ν•¨ν•˜λŠ” λ³΅ν•©μ†Œμž¬

    Talc-free polypropylene composition with long lasting scratch resistance, and method of manufacturing the same

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    λ³Έ 발λͺ…은 νƒˆν¬-프리 지속 λ‚΄μŠ€ν¬λž˜μΉ˜μ„± ν΄λ¦¬ν”„λ‘œν•„λ Œ μ‘°μ„±λ¬Ό, 그리고 이의 μ œμ‘°λ°©λ²•μ— κ΄€ν•œ 것이닀. λ³Έ 발λͺ…μ˜ 제 1 μ‹€μ‹œμ˜ˆμ— 따라 νƒˆν¬-프리 지속 λ‚΄μŠ€ν¬λž˜μΉ˜μ„± ν΄λ¦¬ν”„λ‘œν•„λ Œ 쑰성물은 ν΄λ¦¬ν”„λ‘œν•„λ Œ μˆ˜μ§€, μΆ©μ§„μž¬ 및 슬립제λ₯Ό ν¬ν•¨ν•˜λŠ” νƒˆν¬-프리 지속 λ‚΄μŠ€ν¬λž˜μΉ˜μ„± ν΄λ¦¬ν”„λ‘œν•„λ Œ 쑰성물을 μ œκ³΅ν•œλ‹€. λ˜ν•œ, λ³Έ 발λͺ…μ˜ 제 2 μ‹€μ‹œμ˜ˆμ— 따라 (1) ν΄λ¦¬ν”„λ‘œν•„λ Œ μˆ˜μ§€, μΆ©μ§„μž¬, 그리고 슬립제λ₯Ό 미리 μ„€μ •λœ μ€‘λŸ‰μœΌλ‘œ κ³„λŸ‰ν•˜λŠ” 단계; (2) μΆ©μ§„μž¬ 담지λ₯Ό μœ„ν•΄ 상기 (1)μ—μ„œ κ°œλŸ‰λœ 슬립제 쀑 제1ν•¨λŸ‰μ˜ 슬립제λ₯Ό μš©λ§€μ— λ…Ήμ—¬ μš©μ•‘μ„ μ œμ‘°ν•œ ν›„ 상기 μš©μ•‘μ— 상기 (1)μ—μ„œ κ°œλŸ‰λœ μΆ©μ§„μž¬λ₯Ό 첨가 ν›„ ꡐ반 및 κ°μ••ν•˜λ©° μ„Έμ²™ 및 원심 뢄리 ν›„ κ±΄μ‘°ν•˜λŠ” 단계; (3) 주재 성뢄인 ν΄λ¦¬ν”„λ‘œν•„λ Œκ³Ό 상기 (1)μ—μ„œ κ°œλŸ‰λœ 슬립제 쀑 상기 (2)의 제1ν•¨λŸ‰μ„ μ œμ™Έν•œ λ‚˜λ¨Έμ§€ 양인 제2ν•¨λŸ‰μ˜ 슬립제, 및 상기 (2) λ‹¨κ³„μ—μ„œ 슬립제 μš©μ•‘μ— λ‹΄μ§€λœ μΆ©μ§„μž¬λ₯Ό 미리 μ„€μ •λœ 가곡 μ˜¨λ„μ—μ„œ μ••μΆœν•˜μ—¬ 펠릿(pellet)을 μ œμ‘°ν•˜λŠ” 단계; 및 (4) νŽ λ¦Ώμ„ μ‚¬μΆœ μ„±ν˜•ν•˜μ—¬ λ‚΄μŠ€ν¬λž˜μΉ˜μ„± ν΄λ¦¬ν”„λ‘œν•„λ Œ 쑰성물을 μ–»λŠ” 단계;λ₯Ό ν¬ν•¨ν•˜λŠ” νƒˆν¬-프리 지속 λ‚΄μŠ€ν¬λž˜μΉ˜μ„± ν΄λ¦¬ν”„λ‘œν•„λ Œ μ‘°μ„±λ¬Όμ˜ 제쑰 방법을 μ œκ³΅ν•œλ‹€. 이에 μ˜ν•΄, 기쑴에 μ‚¬μš©λ˜λŠ” λ‚΄μŠ€ν¬λž˜μΉ˜μ„± λ³΅ν•©μ†Œμž¬λ³΄λ‹€ 슬립제의 용좜 κΈ°ν•œμ΄ 길어지도둝 ν•¨μœΌλ‘œμ¨, λ‚΄μŠ€ν¬λž˜μΉ˜ νŠΉμ„±μ˜ λ°œν˜„κΈ°ν•œ λ˜ν•œ μ—°μž₯λ˜λ„λ‘ ν•˜λŠ” νš¨κ³Όκ°€ μžˆλ‹€. λ˜ν•œ, λ³Έ 발λͺ…은, λ‚΄μŠ€ν¬λž˜μΉ˜ νŠΉμ„±λΏλ§Œ μ•„λ‹ˆλΌ, 기계적 강도가 μš°μˆ˜ν•œ ν΄λ¦¬ν”„λ‘œν•„λ Œ 쑰성물을 μ œκ³΅ν•  수 μžˆλŠ” νš¨κ³Όκ°€ μžˆλ‹€. 뿐만 μ•„λ‹ˆλΌ, λ³Έ 발λͺ…은, 인체에 λ¬΄ν•΄ν•œ λ‚˜λ…Έμ‹€λ¦¬μΉ΄λ‘œ μ’…λž˜μ— μ‚¬μš©λ˜λ˜ 인체 μœ ν•΄μ„± μΆ©μ§„μž¬μΈ νƒˆν¬ λ˜λŠ” μœ λ¦¬μ„¬μœ λ₯Ό λŒ€μ²΄ν•˜μ—¬, 인체 μΉœν™”μ„± λ³΅ν•©μ†Œμž¬λ₯Ό μ΄μš©ν•΄ 기쑴에 μ‚¬μš©ν•˜λŠ” λ‚΄μŠ€ν¬λž˜μΉ˜μ„± 쑰성물을 λŒ€μ²΄ν•˜λŠ” νš¨κ³Όκ°€ μžˆλ‹€.(1) ν΄λ¦¬ν”„λ‘œν•„λ Œ μˆ˜μ§€, μΆ©μ§„μž¬, 그리고 슬립제λ₯Ό 미리 μ„€μ •λœ μ€‘λŸ‰μœΌλ‘œ κ³„λŸ‰ν•˜λŠ” 단계; (2) μΆ©μ§„μž¬ 담지λ₯Ό μœ„ν•΄ 상기 (1)μ—μ„œ κ³„λŸ‰λœ 슬립제 쀑 제1ν•¨λŸ‰μ˜ 슬립제λ₯Ό μš©λ§€μ— λ…Ήμ—¬ μš©μ•‘μ„ μ œμ‘°ν•œ ν›„ 상기 μš©μ•‘μ— 상기 (1)μ—μ„œ κ³„λŸ‰λœ μΆ©μ§„μž¬λ₯Ό 첨가 ν›„ ꡐ반 및 κ°μ••ν•˜λ©° μ„Έμ²™ 및 원심 뢄리 ν›„ κ±΄μ‘°ν•˜λŠ” 단계;(3) 주재 성뢄인 ν΄λ¦¬ν”„λ‘œν•„λ Œκ³Ό 상기 (1)μ—μ„œ κ³„λŸ‰λœ 슬립제 쀑 상기 (2)의 제1ν•¨λŸ‰μ„ μ œμ™Έν•œ λ‚˜λ¨Έμ§€ 양인 제2ν•¨λŸ‰μ˜ 슬립제, 및 상기 (2) λ‹¨κ³„μ—μ„œ 슬립제 μš©μ•‘μ— λ‹΄μ§€λœ μΆ©μ§„μž¬λ₯Ό 미리 μ„€μ •λœ 가곡 μ˜¨λ„μ—μ„œ μ••μΆœν•˜μ—¬ 펠릿(pellet)을 μ œμ‘°ν•˜λŠ” 단계; 및 (4) νŽ λ¦Ώμ„ μ‚¬μΆœ μ„±ν˜•ν•˜μ—¬ λ‚΄μŠ€ν¬λž˜μΉ˜μ„± ν΄λ¦¬ν”„λ‘œν•„λ Œ 쑰성물을 μ–»λŠ” 단계;λ₯Ό ν¬ν•¨ν•˜λŠ” νƒˆν¬-프리 지속 λ‚΄μŠ€ν¬λž˜μΉ˜μ„± ν΄λ¦¬ν”„λ‘œν•„λ Œ μ‘°μ„±λ¬Όμ˜ 제쑰 방법

    Studies on the Cellulose Acetate Glasses Frame Sheet

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    λͺ©μ : λ³Έ μ—°κ΅¬λŠ” κ΅­μ™Έμ—μ„œ νŒλ§€μ€‘μΈ μ…€λ£°λ‘œμ˜€μŠ€ μ•„μ„Έν…Œμ΄νŠΈ μ•ˆκ²½ν…Œμš© 판재(μˆ˜μž… CA판재, overseas company's cellulose acetate glasses frame sheet)의 νŠΉμ„±μ„ ν‰κ°€ν•˜κ³  μ•ˆκ²½ν…Œμš© CA νŒμž¬λ‘œμ„œ μ ν•©ν•œ κ³΅μ—…μš© μ…€λ£°λ‘œμ˜€μŠ€ μ•„μ„Έν…Œ 이트 λ ˆμ§„(κ³΅μ—…μš© CAλ ˆμ§„, industrial cellulose acetate resin)을 μ„ μ •ν•˜μ—¬ κ·Έ μ†Œμž¬μ˜ 졜적 용육 μ••μΆœ 쑰건을 λ„μΆœν•˜λŠ” 데 λͺ©μ μ΄ μžˆλ‹€. 방법: μˆ˜μž… CA판재의 νŠΉμ„±μ„ κ³ μ°°ν•˜κΈ° μœ„ν•΄ 1H-NMR, GPC, TGA 뢄석을 μ‹€μ‹œν•˜κ³ , κ³΅μ—…μš© CA레 μ§„μ˜ 졜적 λ°°ν•© 쑰건 및 용육 μ••μΆœ 쑰건을 λ„μΆœν•œλ‹€. λ˜ν•œ hot press에 μ˜ν•΄ 제쑰 된 3개ꡭ의 μˆ˜μž… CAνŒμž¬μ™€ 곡업 용 CAλ ˆμ§„ μ„±ν˜•μ²΄μ˜ 물성을 비ꡐ 평가λ₯Ό μ‹€μ‹œν•˜μ˜€λ‹€. κ²°κ³Ό: μˆ˜μž… CA판재의 νŠΉμ„± 뢄석 κ²°κ³Ό, virgin CAλ₯Ό κ°€μ†Œν™”μ‹œ ν‚€κΈ° μœ„ν•΄ μ‚¬μš©λœ κ°€μ†Œμ œλŠ” diethyl phthalate이며 κ°€μ†Œμ œμ˜ ν•¨λŸ‰μ€ 30 wt% λ‚΄μ™Έμž„μ„ ν™•μΈν•˜μ˜€λ‹€. 용육 μ••μΆœ μ‹œν—˜ κ²°κ³Ό, μ•• μΆœμ˜¨λ„λŠ” 190~200oCμ—μ„œ κ³΅μ—…μš© CAλ ˆμ§„μ˜ μΆ©λΆ„ν•œ μš©μœ΅κ±°λ™ 및 μ••μΆœμ„±μ„ λ³΄μ˜€μœΌλ©° μ„±ν˜•μ²΄ λ˜ν•œ μ•ˆκ²½ν…Œμš© 물성을 λ§Œμ‘±ν•˜λŠ” μˆ˜μ€€μΈ 2.3 kgf/mm2μž„μ„ ν™•μΈν•˜μ˜€λ‹€. κ²°λ‘ : 30 wt%의 κ°€μ†Œμ œ ν•¨λŸ‰μ„ 가진 κ³΅μ—…μš© CAλ ˆμ§„μ˜ 경우, 쀑ꡭ 의 CA판재λ₯Ό λŒ€μ²΄ν•˜μ—¬ μ•ˆκ²½ν…Œμš© μ…€λ£°λ‘œμ˜€μŠ€ μ•„μ„Έν…Œμ΄νŠΈ 판재 μ œμ‘°μ— μ ν•©ν•œ μ†Œμž¬λ‘œ νŒλ‹¨λœλ‹€.2
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