Unforeseen high temperature and humidity stability of FeCl3_3 intercalated few layer graphene

We present the first systematic study of the stability of the structure and electrical properties of FeCl$_3$ intercalated few-layer graphene to high levels of humidity and high temperature. Complementary experimental techniques such as electrical transport, high resolution transmission electron microscopy and Raman spectroscopy conclusively demonstrate the unforeseen stability of this transparent conductor to a relative humidity up to $100 \%$ at room temperature for 25 days, to a temperature up to 150\,^\circC in atmosphere and up to a temperature as high as 620\,^\circC in vacuum, that is more than twice higher than the temperature at which the intercalation is conducted. The stability of FeCl$_3$ intercalated few-layer graphene together with its unique values of low square resistance and high optical transparency, makes this material an attractive transparent conductor in future flexible electronic applications.Comment: Scientific Reports, volume 5, article no. 760

Graphene and functionalised graphene for flexible and optoelectric applications

The landscape of consumer electronics has drastically changed over the last decade. Technological advances have led to the development of portable media devices, such as the iPod, smart phones and laptops. This has been achieved primarily through miniaturisation and using materials such as Lithium and Indium Tin Oxide (ITO) to increase energy density in batteries and as transparent electrodes for light emitting displays respectively. However, ten years on there are now new consumer demands, which are dictating the direction of research and new products are under constant development. Graphene is a promising next-generation material that was discovered in 2004. It is composed of a two-dimensional lattice made only from carbon. The atoms are arranged in a two atom basis hexagonal crystal structure which forms a fundamental building block of all sp2 hybrid forms of carbon. The production of large area graphene has a high cost, due to the long growth times and the high temperatures required. This is relevant as graphene is not viable compared to other transparent conductors which are produced on industrial scales for a fraction of the cost of graphene growth. Furthermore, graphene has a high intrinsic resistivity (2KW/_) which is three orders of magnitude greater than the current industry standard ITO. This limits the size of the electrodes as there is dissipation of energy across the electrode leading to inefficiency. Furthermore a potential drop occurs across the electrode leading to a non-uniform light emission when the electrode is used in a light emitting display. I investigate alternative methods of large area graphene growth with the aim of reducing the manufacturing costs, while maintaining the quality required for graphene human interface devices. Building on this I develop new fabrication methods for the production of large-area graphene devices which are flexible and transparent and show the first all graphene touch sensor. Focusing on the reducing the high resistivity of graphene using FeCl3 intercalation, while maintaining high optical transmission, I show low resistivity achieved using this process for microscopic graphene flakes, large-area graphene grown on silicon carbide and large-area graphene grown by CVD. Furthermore, I explore the stability of FeCl3 intercalated graphene and a process to transfer a material to arbitrary flexible substrates.EPSR

Is graphene a good transparent electrode for photovoltaics and display applications?

PublishedReviewThe current standard material used for transparent electrodes in displays, touch screens and solar cells is indium tin oxide (ITO) which has low sheet resistance (10 Ω/□), high optical transmission in the visible wavelength (85%) and does not suffer of optical haze. However, ITO is mechanically rigid and incompatible with future demands for flexible applications. Graphene materials share many of the properties desirable for flexible transparent conductors, including high optical transparency, high mechanical flexibility and strength. Whilst pristine graphene is not a good transparent conductor, functionalised graphene is at least 1000 times a better conductor than its pristine counterpart and it outperforms ITO. Here the authors review recent work on a novel graphene-based conductor with sheet resistance as low as 8.8 Ω/□ and 84% optical transmission. This material is obtained by ferric chloride (FeCl 3) intercalation into few-layer-graphene (FLG), giving rise to a new system which is the best known flexible and transparent electricity conductor. FeCl 3-FLG shows no significant changes in the electrical and structural properties for a long exposure to air, to high levels of humidity and at temperatures of up to 150°C in atmosphere. These properties position FeCl 3-FLG as a viable and attractive replacement to ITO.Engineering and Physical Sciences Research Council (EPSRC)Royal Society International Exchanges Schem

The effects of vibration on fringe projection systems

Mechanical vibration noise is a significant source of error in precision measuring instruments. Errors due to vibration can be detected in measurement signals, and so methods to control mechanical vibration must be considered throughout the design process. Fringe projection (FP) is a fast, non-contact and non-destructive measurement technology, that allows for the rapid form measurement of engineering components. There is an increasing demand in industry for low-intervention, factory-friendly FP systems. Vibration is reported to be a significant source of mechanical error in FP measurements, and so in order to design an effective metrology solution, it is vital to first understand the FP systems’ sensitivity to vibrational noise. In this research, a methodology for assessing the effects of vibration on the measurement accuracy and repeatability of a low-cost FP system is presented. The research includes a theoretical investigation of the effects of vibration on FP measurements using a computational simulation technique, as well as an experimental study, which is compared with the simulated results. The methodology presented here allows for the rapid benchmarking of a given FP system operating in any configuration, and can be used to define the required vibrational performance parameters of the system

All-graphene photodetectors

notes: PMCID: PMC3694352Copyright © 2013 American Chemical Society.Published versionWe investigate the optoelectronic properties of novel graphene/FeCl3-intercalated few-layer graphene (FeCl3-FLG, dubbed graphexeter) heterostructures using photovoltage spectroscopy. We observe a prominent photovoltage signal generated at the graphene/FeCl3-FLG and graphene/Au interfaces, whereas the photovoltage at the FeCl3-FLG/Au interface is negligible. The sign of the photovoltage changes upon sweeping the chemical potential of the pristine graphene through the charge neutrality point, and we show that this is due to the photothermoelectric effect. Our results are a first step toward all-graphene-based photodetectors and photovoltaics.Engineering and Physical Sciences Research Council (EPSRC

Performance Verification of a Flexible Vibration Monitoring System

The performance of measurement or manufacturing systems in high-precision applications is dependent upon the dynamics of the system, as vibration can be a significant contributor to the measurement uncertainty and process variability. Technologies making use of accelerometers and laser vibrometers are available to rapidly measure and process structural dynamic data but the software infrastructure is yet to be available in an open source or standardised format to allow rapid inter-platform use. In this paper, we present a novel condition monitoring system, which uses commercially available accelerometers in combination with a control-monitoring infrastructure to allow for the appraisal of the performance of a measurement or manufacturing system. A field-programmable gate array (FPGA)-based control system is implemented for high-speed data acquisition and signal processing of six triaxial accelerometers, with a frequency range of 1 Hz to 6000 Hz, a sensitivity of 102.5 mV/ms−2 and a maximum sample rate of 12,800 samples per second per channel. The system includes two methods of operation: real-time performance monitoring and detailed measurement/manufacturing verification. A lathe condition monitoring investigation is undertaken to demonstrate the utility of this system and acquire typical machining performance parameters in order to monitor the “health” of the system

Novel highly conductive and transparent graphene based conductors

Future wearable electronics, displays and photovoltaic devices rely on highly conductive, transparent and yet mechanically flexible materials. Nowadays indium tin oxide (ITO) is the most wide spread transparent conductor in optoelectronic applications, however the mechanical rigidity of this material limits its use for future flexible devices. Here we report novel transparent conductors based on few layer graphene (FLG) intercalated with ferric chloride (FeCl3) with an outstandingly high electrical conductivity and optical transparency. We show that upon intercalation a record low sheet resistance of 8.8 Ohm/square is attained together with an optical transmittance higher than 84% in the visible range. These parameters outperform the best values of ITO and of other carbon-based materials, making these novel transparent conductors the best candidates for future flexible optoelectronics

Unforeseen high temperature and humidity stability of FeCl3 intercalated few layer graphene

This is the final version of the article. Available from the publisher via the DOI in this record.We present the first systematic study of the stability of the structure and electrical properties of FeCl3 intercalated few-layer graphene to high levels of humidity and high temperature. Complementary experimental techniques such as electrical transport, high resolution transmission electron microscopy and Raman spectroscopy conclusively demonstrate the unforseen stability of this transparent conductor to a relative humidity up to 100% at room temperature for 25 days, to a temperature up to 150°C in atmosphere and to a temperature as high as 620°C in vacuum, that is more than twice higher than the temperature at which the intercalation is conducted. The stability of FeCl3 intercalated few-layer graphene together with its unique values of low square resistance and high optical transparency, makes this material an attractive transparent conductor in future flexible electronic applications