Bond Strength Degradation for Prestressed Steel and Carbon FRP Bars in High-Performance Self-Consolidating Concrete at Elevated Temperatures and in Fire

Novel structures are emerging utilizing high performance, self-consolidating, fibre-reinforced concrete (HPSCC) reinforced with high-strength, lightweight, and non-corroding prestressed reinforcement. One example of this is a new type of precast carbon fibre reinforced polymer (CFRP) pretensioned HPSCC panel intended as load-bearing panels for building envelopes. As for all load-bearing structural members in building applications, the performance of these members in fire must be understood before they can be used with confidence. In particular, the bond performance of CFRP prestressing reinforcement at elevated temperatures is not well known. This paper examines the fire performance of these new types of structural elements, placing particular emphasis on the bond performance of CFRP and steel wire prestressing reinforcement at elevated temperatures. The results of large-scale fire tests and transient high temperature tensile and bond-pullout tests on CFRP and steel prestressing bars embedded in HPSCC cylinders are presented and discussed to shed light on the fire performance of these structural elements

Thermo-mechanical compatibility of CFRP versus steel reinforcement for concrete at high temperature

Optimization of the design of concrete structures has become a driver for the use of nonconventional reinforcing materials. One example of this is the emerging use of non-corrosive, highstrength, and lightweight carbon fibre reinforced polymer (CFRP) prestressing tendons. It is widely known that the bond between FRP reinforcing tendons and concrete deteriorates at elevated temperature due to a combination of factors. Lateral thermal expansion of FRP reinforcing tendons at elevated temperature has been shown to have consequences for the bond performance of these systems. This paper presents the results of an experimental study carried out to assess the occurrence of heat-induced longitudinal splitting cracks in concrete specimens reinforced with CFRP or steel prestressing tendons. A novel testing methodology, namely a Heat-Transfer Rate Inducing System (H-TRIS), is used to subject specimens to thermal loading which replicates that experienced by equivalent specimens in a standard fire resistance test. A comparison between CFRP and steel tendons is made, and the occurrence of longitudinal splitting cracks is evaluated in terms of the time to occurrence and thermal gradient within the concrete. Results are compared against an available analytical model

Generation of superoxide and singlet oxygen from α-tocopherolquinone and analogues.

Three potential routes to generation of reactive oxygen species from a tocopherolquinone have been identified. The quinone of the water-soluble vitamin E analogue Trolox C (Trol-Q) is reduced by hydrated electron and isopropanol a hydroxyalkyl radical, and the resulting semiquinone reacts with molecular oxygen to form superoxide with a second order rate constant of 1.3 x 108 dm3 mol-1 s-1, illustrating the potential for redox cycling. Illumination (UV-A, 355 nm) of the quinone of 2,2,5,7,8-pentamethyl-6-hydroxychromanol (PMHC-Q) leads to a reactive short-lived (ca 10-6 s) triplet state, able to oxidise tryptophan with a second order rate constant greater than 109 dm3 mol-1 s-1. The triplet states of these quinones sensitize singlet oxygen formation with quantum yields of about 0.8. Such potentially damaging reactions of a tocopherolquinone may in part account for the recent findings that high levels of dietary vitamin E supplementation lack any beneficial effect and may lead to slightly enhanced levels of overall mortality

Differential effects of negative emotion on memory for items and associations, and their relationship to intrusive imagery

A crucial aspect of episodic memory formation is the way in which our experiences are stored within a coherent spatio-temporal context. We review research that highlights how the experience of a negative event can alter memory encoding in a complex manner, strengthening negative items but weakening associations with other items and the surrounding context. Recent evidence suggests that these opposing effects can occur through amygdala up-modulation to facilitate item encoding, while the hippocampal provision of contextual binding is down-modulated. We consider how these characteristics of memory for negative events might contribute to the development and maintenance of distressing intrusive imagery in posttraumatic stress disorder, and how they should influence therapeutic interventions

The Structural Capacity of Laminated Timber Compression Elements in Fire: A Meta-Analysis

Modern building construction is increasingly applying laminated timber products as structural members for larger and more ambitious projects, both commercial and residential. As a consequence, designers require reliable knowledge and design tools to assess the structural capacity of laminated mass timber elements in fire. This paper reviews and assesses available data and methods to design for fire resistance of laminated mass timber compression elements. Historical data from fire resistance tests is presented and compared against the available design calculation methods. The underlying assumptions of the thermal and structural analyses applied within the presented calculation methodologies are discussed. The resulting meta-analysis suggests that the available methods are all able to make reasonable predictions (with an average mean absolute error (MAPE) of 22% across methods) of the fire resistance of glued-laminated columns exposed to standard fires; however, the available methods for CLT walls give inconsistent (MAPE of 46% across all methods and 30% excluding extreme outliers) and potentially non-conservative results (up to 88% of investigated cases are statistically non-conservative). Additional research on loaded compression elements is therefore needed