Second Harmonic Generation, Electrooptical Pockels Effect, and Static First-Order Hyperpolarizabilities of 2,2′-Bithiophene Conformers: An HF, MP2, and DFT Theoretical Investigation

The static and dynamic electronic (hyper)polarizabilities of the equilibrium conformations of 2,2′-bithiophene (anti-gauche and syn-gauche) were computed in the gas phase. The calculations were carried out using Hartree-Fock (HF), Møller-Plesset second-order perturbation theory (MP2), and density functional theory methods. The properties were evaluated for the second harmonic generation (SHG), and electrooptical Pockels effect (EOPE) nonlinear optical processes at the typical λ=1064 nm of the Nd:YAG laser. The anti-gauche form characterized by the S–C2–C2′–S dihedral angle of 137° (MP2/6-311G**) is the global minimum on the potential energy surface, whereas the syn-gauche rotamer (S–C2–C2′–S = 48°, MP2/6-311G**) lies ca. 0.5 kcal/mol above the anti-gauche form. The structural properties of the gauche structures are rather similar to each other. The MP2 electron correlation effects are dramatic for the first-order hyperpolarizabilities of the 2,2′-bithiophenes, decreasing the HF values by ca. a factor of three. When passing from the anti-gauche to the syn-gauche conformer, the static and frequency-dependent first-order hyperpolarizabilities increase by ca. a factor of two. Differently, the electronic polarizabilities and second-order hyperpolarizabilities of these rotamers are rather close to each other. The syn-gauche structure could be discriminated from the anti-gauche one through its much more intense SHG and EOPE signals

Static and Dynamic Electronic (Hyper)polarizabilities of Dimethylnaphthalene Isomers: Characterization of Spatial Contributions by Density Analysis

Static and frequency-dependent electronic (hyper)polarizabilities of the dimethylnaphthalene (DMN) isomers were computed in vacuum using the Coulomb-attenuating Density Functional Theory method. The nonlinear optical Second Harmonic Generation (SHG) and Electro-Optical Pockels Effect (EOPE) were investigated at the characteristic Nd:YAG laser wavelength of 1064 nm. The response electric properties especially the longitudinal polarizability, polarizability anisotropy, and first-order hyperpolarizability are significantly affected by the position of the methyl groups. The SHG and EOPE techniques can be potentially useful to discriminate the ,-DMN isomers (2,6-DMN < 2,7-DMN < 2,3-DMN) as well as the ,-DMN isomers (1,5-DMN < 1,4-DMN < 1,8-DMN). The (hyper)polarizability differences among the investigated DMNs were elucidated through density analysis calculations. The predicted polarizabilities exhibit good linear relationships with the experimental first-order biomass-normalized rate coefficient, a physicochemical property connected to the rates of biodegradation processes of polycyclic aromatic hydrocarbons

Da Reforma do Ensino Médio às possibilidades da Educação Pupular: caminhos para uma contraproposta ao Novo Ensino Médio

Artigo submetido para Trabalho de Conclusão de Curso em História - LicenciaturaTrabalho de Conclusão de Curso apresentado ao Instituto Latino-Americano de Arte, Cultura e História da Universidade Federal da Integração Latino- Americana, como requisito parcial à obtenção do título de Licenciado em História. Orientadora: Profa. Dra. Lívia Fernanda MoralesRecentemente, no breve governo Temer, foram aprovadas a Reforma do Ensino Médio brasileiro e a Base Nacional Curricular Comum. Estas medidas fazem parte do avanço da agenda neoliberal e a educação é um campo importante para o estabelecimento deste domínio (Ducasse, 2015; Freitas, 2018). Este artigo tem como objetivo a análise dos possíveis efeitos desta reforma recortando através da tensão entre trabalho intelectual e trabalho manual partindo da abordagem marxista e, em seguida, apresentar caminhos para a construção de uma contraproposta a este Novo Ensino Médio. Através do resgate histórico de experiências da educação popular, apresentamos uma perspectiva de transformação educacional através da cultura junto a princípios pedagógicos para uma educação contra-hegemônica que importe América Latina.Recientemente, en el breve gobierno de Temer, se aprobaron la Reforma de la Escuela Secundaria de Brasil y la Base de Currículo Común Nacional. Estas medidas son parte del avance de la agenda neoliberal y la educación es un campo importante para el establecimiento de este dominio (Ducasse, 2015; Freitas, 2018). Este artículo tiene como objetivo analizar los posibles efectos de esta reforma y luego presentar formas de construir una contrapropuesta a esta nueva escuela secundaria. A través del rescate histórico de experiencias de educación popular, presentamos una perspectiva de transformación educativa a través de la cultura junto con principios pedagógicos para una educación contrahegemónica que es importante en América Latin

Exploring The Use Of SAR Remote Sensing To Detect Microplastics Pollution In The Oceans

The increase in plastic pollution is advancing micro level pollution and the total weight of microplastics (8 tons and in the North Atlantic as 10.4 x 108 tons. The plastic in marine environment will eventually degrade and it will be promptly colonized by bacteria releasing surfactants. Such surfactants will have the effect of damping the capillary and small gravitational waves on the ocean surface. Since SAR is sensitive to roughness induced by capillary waves, it may be exploited to detect bacterial activities related to plastic pollution. In this work we used Sentinel-1A and COSMO SkyMed radar images acquired in the Atlantic and Pacific gyres to detect surfactants that may be associated to plastic pollution. We are using SAR, because the damping properties of surfactants produce dark areas in images. Since area of low backscattering in SAR images could also be produced by other oceanographic/meteorological event, we exploited geophysical remote sensing products associated to time and locations synchronised to SAR acquisitions. Among other products we considered sea surface temperature, surface wind, chlorophyll, surface reflectance, turbidity and wave heights. Additionally we made sure that the areas were not within busy shipping routes. The result of the analysis is that, including effects due to colocation errors of SAR and meteorological data, we could identify a large amount of linear slicks in SAR images that were not directly related to apparent meteorological conditions. Such slicks in the gyres have the appearance of oil slicks, however in some areas they are in large amount and they are not connected to large ship traffic. At the moment these slicks seems to only be visible when the wind conditions are moderate (e.g. 6m/s) as it happen for ordinary oil slicks. Besides the work on radar data, we are making controlled experiments with micro-plastic pollution in sea water, to understand the amount and type of surfactants produced by microbes colonising plastics. The conclusion of our study is that radar remote sensing has the potential to detect plastic pollution areas under sorter meteorological conditions

Detecting microplastics pollution in world oceans using SAR remote sensing

Plastic pollution in the world’s oceans is estimated to have reached 270.000 tones, or 5.25 trillion pieces. This plastic is now ubiquitous, however due to ocean circulation patterns, it accumulates in the ocean gyres, creating “garbage patches”. This plastic debris is colonized by microorganisms which create unique bio-film ecosystems. Microbial colonization is the first step towards disintegration and degradation of plastic materials: a process that releases metabolic by-products from energy synthesis. These by-products include the release of short-chain and more complex carbon molecules in the form of surfactants, which we hypothesize will affect the fluid dynamic properties of waves (change in viscosity and surface tension) and make them detectable by SAR sensor. In this study we used Sentinel-1A and COSMO-SkyMed SAR images in selected sites of both the North Pacific and North Atlantic oceans, close to ocean gyres and away from coastal interference. Together with SAR processing we conducted contextual analysis, using ocean geophysical products of the sea surface temperature, surface wind, chlorophyll, wave heights and wave spectrum of the ocean surface. In addition, we started experiments under controlled conditions to test the behaviour of microbes colonizing the two most common pollutants, polyethylene (PE) and polyethylene terephthalate (PET) microplastics. The analysis of SAR images has shown that a combination of surface wind speed and Langmuir cells- ocean circulation pattern is the main controlling factor in creating the distinct appearance of the sea-slicks and microbial bio-films. The preliminary conclusion of our study is that SAR remote sensing may be able to detect plastic pollution in the open oceans and this method can be extended to other areas

Heidegger and Lacan

Lacanian psychoanalysis cannot disregard its debts to philosophy, especially continental philosophy. Lacan’s conception of language is derived from multiple philosophical sources (i.e., Plato, Aristotle, Kant, Hegel, Kierkegaard) including Heidegger’s philosophy of language and pride of place. Heidegger’s view of language prepares the ground for reversing the relationship between language and human beings, overcoming common sense about language and the communicative model of language. Language is much more than a set of labels; it shapes the human world and structures social relations themselves. In addition, language acts as a social link. The function of language as a social link allows us to think of it in relation to the Law and the very function of this human subjectivity. In reference to the Other of the Law and language, the subject finds her recognition, and this implies that the language is not reducible to communication. The process of technical-scientific domination of Western institutions leads to a reduction of their functions to the formal aspects, which may lead to a reification of the human as well as a state of alienation

Microwave satellite remote sensing for a sustainable sea

The oceans cover roughly 2/3 of the Earth’s surface and are a fundamental ecosystem regulating climate, weather and representing a huge reservoir of biodiversity and natural resources. The preservation of the oceans is therefore not only relevant on an environmental perspective but also on an economical one. A sustainable approach is requested that cannot be simply achieved by improving technologies but calls for a shared new vision of common goods.Within such a complex and holistic problem, the role of satellite microwave remote sensing to observe marine ecosystem and to assist a sustainable development of human activities must be considered. In such a view the paper is meant. Accordingly, the key microwave sensor technologies are reviewed paying particular emphasis on those applications that can provide effective support to pursue some of the UN Sustainable Development Goals. Three meaningful sectors are showcased:oil and gas, where microwave sensors can provide continuous fine-resolution monitoring of critical infrastructures; renewable energy, where microwave satellite remote sensing allows supporting the management of offshore wind farms during both feasibility and operational stages; plastic pollution, where microwave technologies that exploit signals of opportunity offer large-scale monitoring capability to provide marine litter maps of the oceans

Fusion of VNIR Optical and C-Band Polarimetric SAR Satellite Data for Accurate Detection of Temporal Changes in Vegetated Areas

In this paper, we propose a processing chain jointly employing Sentinel-1 and Sentinel-2 data, aiming to monitor changes in the status of the vegetation cover by integrating the four 10 m visible and near-infrared (VNIR) bands with the three red-edge (RE) bands of Sentinel-2. The latter approximately span the gap between red and NIR bands (700 nm–800 nm), with bandwidths of 15/20 nm and 20 m pixel spacing. The RE bands are sharpened to 10 m, following the hypersharpening protocol, which holds, unlike pansharpening, when the sharpening band is not unique. The resulting 10 m fusion product may be integrated with polarimetric features calculated from the Interferometric Wide (IW) Ground Range Detected (GRD) product of Sentinel-1, available at 10 m pixel spacing, before the fused data are analyzed for change detection. A key point of the proposed scheme is that the fusion of optical and synthetic aperture radar (SAR) data is accomplished at level of change, through modulation of the optical change feature, namely the difference in normalized area over (reflectance) curve (NAOC), calculated from the sharpened RE bands, by the polarimetric SAR change feature, achieved as the temporal ratio of polarimetric features, where the latter is the pixel ratio between the co-polar and the cross-polar channels. Hyper-sharpening of Sentinel-2 RE bands, calculation of NAOC and modulation-based integration of Sentinel-1 polarimetric change features are applied to multitemporal datasets acquired before and after a fire event, over Mount Serra, in Italy. The optical change feature captures variations in the content of chlorophyll. The polarimetric SAR temporal change feature describes depolarization effects and changes in volumetric scattering of canopies. Their fusion shows an increased ability to highlight changes in vegetation status. In a performance comparison achieved by means of receiver operating characteristic (ROC) curves, the proposed change feature-based fusion approach surpasses a traditional area-based approach and the normalized burned ratio (NBR) index, which is widespread in the detection of burnt vegetation

A Tutorial on Speckle Reduction in Synthetic Aperture Radar Images

Speckle is a granular disturbance, usually modeled as a multiplicative noise, that affects synthetic aperture radar (SAR) images, as well as all coherent images. Over the last three decades, several methods have been proposed for the reduction of speckle, or despeckling, in SAR images. Goal of this paper is making a comprehensive review of despeckling methods since their birth, over thirty years ago, highlighting trends and changing approaches over years. The concept of fully developed speckle is explained. Drawbacks of homomorphic filtering are pointed out. Assets of multiresolution despeckling, as opposite to spatial-domain despeckling, are highlighted. Also advantages of undecimated, or stationary, wavelet transforms over decimated ones are discussed. Bayesian estimators and probability density function (pdf) models in both spatial and multiresolution domains are reviewed. Scale-space varying pdf models, as opposite to scale varying models, are promoted. Promising methods following non-Bayesian approaches, like nonlocal (NL) filtering and total variation (TV) regularization, are reviewed and compared to spatial- and wavelet-domain Bayesian filters. Both established and new trends for assessment of despeckling are presented. A few experiments on simulated data and real COSMO-SkyMed SAR images highlight, on one side the costperformance tradeoff of the different methods, on the other side the effectiveness of solutions purposely designed for SAR heterogeneity and not fully developed speckle. Eventually, upcoming methods based on new concepts of signal processing, like compressive sensing, are foreseen as a new generation of despeckling, after spatial-domain and multiresolution-domain method