The abundances of nitrogen-containing molecules during pre-protostellar collapse

We have studied the chemistry of nitrogen--bearing species during the initial stages of protostellar collapse, with a view to explaining the observed longevity of N2H+ and NH3 and the high levels of deuteration of these species. We followed the chemical evolution of a medium comprising gas and dust as it underwent free--fall gravitational collapse. Chemical processes which determine the relative populations of the nuclear spin states of molecules and molecular ions were included explicitly, as were reactions which lead ultimately to the deuteration of the nitrogen--containing species N2H+ and NH3. The freeze-out of `heavy' molecules onto grains was taken into account. We found that the timescale required for the nitrogen--containing species to attain their steady--state values was much larger than the free--fall time and even comparable with the probable lifetime of the precursor molecular cloud. However, it transpires that the chemical evolution of the gas during gravitational collapse is insensitive to its initial composition. If we suppose that the grain--sticking probabilities of atomic nitrogen and oxygen are both less than unity (S less than 0.3), we find that the observed differential freeze--out of nitrogen- and carbon--bearing species can be reproduced by the model of free--fall collapse when a sufficiently large grain radius (a_{g}= 0.5 micron) is adopted. Furthermore, the results of our collapse model are consistent with the high levels of deuteration of N2H+ and NH3 which have been observed in L1544 providing that 0.5<a_{g}<1 micron. We note that the o/p H2D+ ratio and fractional abundance of ortho-H2D+ should be largest when ND3 is most abundant.Comment: 22 Pages, 7 Figures, Accepted by Astronomy and Astrophysic

The depletion of NO in pre-protostellar cores

International audienceAims.Understanding the depletion of heavy elements is a fundamental step towards determining the structure of pre-protostellar cores just prior to collapse. We study the dependence of the NO abundance on position in the pre-protostellar cores L1544 and L183. Methods: We observed the 150 GHz and 250 GHz transitions of NO and the 93 GHz transitions of N{2}H+ towards L1544 and L183 using the IRAM 30 m telescope. We compare the variation of the NO column density with position in these objects with the H column density derived from dust emission measurements. Results: We find that NO behaves differently from N{2}H+ and appears to be partially depleted in the high density core of L1544. Other oxygen-containing compounds are also likely to be partially depleted in dense-core nuclei. The principal conclusions are that: the prestellar core L1544 is likely to be "carbon-rich"; the nitrogen chemistry did not reach equilibrium prior to gravitational collapse, and nitrogen is initially (at densities of the order of 104 cm-3) mainly in atomic form; the grain sticking probabilities of atomic C, N and, probably, O are significantly smaller than unity. Appendix A is only available in electronic form at http://www.aanda.or

The molecular hydrogen explorer H2EX

The Molecular Hydrogen Explorer, H2EX, was proposed in response to the ESA 2015 - 2025 Cosmic Vision Call as a medium class space mission with NASA and CSA participations. The mission, conceived to understand the formation of galaxies, stars and planets from molecular hydrogen, is designed to observe the first rotational lines of the H(2) molecule (28.2, 17.0, 12.3 and 9.7 mu m) over a wide field, and at high spectral resolution. H2EX can provide an inventory of warm (a parts per thousand yen 100 K) molecular gas in a broad variety of objects, including nearby young star clusters, galactic molecular clouds, active galactic nuclei, local and distant galaxies. The rich array of molecular, atomic and ionic lines, as well as solid state features available in the 8 to 29 mu m spectral range brings additional science dimensions to H2EX. We present the optical and mechanical design of the H2EX payload based on an innovative Imaging Fourier Transform Spectrometer fed by a 1.2 m telescope. The 20'x20' field of view is imaged on two 1024x1024 Si:As detectors. The maximum resolution of 0.032 cm (-aEuro parts per thousand 1) (full width at half maximum) means a velocity resolution of 10 km s (-aEuro parts per thousand 1) for the 0 - 0 S(3) line at 9.7 mu m. This instrument offers the large field of view necessary to survey extended emission in the Galaxy and local Universe galaxies as well as to perform unbiased extragalactic and circumstellar disks surveys. The high spectral resolution makes H2EX uniquely suited to study the dynamics of H(2) in all these environments. The mission plan is made of seven wide-field spectro-imaging legacy programs, from the cosmic web to galactic young star clusters, within a nominal two years mission. The payload has been designed to re-use the Planck platform and passive cooling design