Augmenting Distillation by Membranes: Developments and Prospects

The growing consciousness for sustainable industrial processes has resulted in industrially developed countries in supporting research efforts toward thorough evaluation of possibilities for improving efficiency of energy intensive separations implying also significant reduction of related carbon dioxide emissions. Being inherently thermodynamically inefficient, distillation, which is by far the most widely utilised and energy intensive separation technology in chemical process industries, has become primary target of energy conservation projects in refining, petrochemical and chemical industries. Improvement is an ongoing activity, replacing still beyond comprehension and a great deal of academic effort is oriented towards augmenting distillation by combining it, where appropriate, with membranes, i.e. pervaporation or vapour permeation, which in conjunction with polymeric membranes proved to be an industrially viable alternative to conventional processes for dehydration of alcohols. Present paper addresses recent developments along this line striving for larger fluxes in alcohol dehydrations by utilising ceramic membranes, with focus on vapour permeation, as well as the potential for the recovery of organic solvents and reactants forming azeotropes with other organics

Augmenting Distillation by Membranes: Developments and Prospects

The growing consciousness for sustainable industrial processes has resulted in industrially developed countries in supporting research efforts toward thorough evaluation of possibilities for improving efficiency of energy intensive separations implying also significant reduction of related carbon dioxide emissions. Being inherently thermodynamically inefficient, distillation, which is by far the most widely utilised and energy intensive separation technology in chemical process industries, has become primary target of energy conservation projects in refining, petrochemical and chemical industries. Improvement is an ongoing activity, replacing still beyond comprehension and a great deal of academic effort is oriented towards augmenting distillation by combining it, where appropriate, with membranes, i.e. pervaporation or vapour permeation, which in conjunction with polymeric membranes proved to be an industrially viable alternative to conventional processes for dehydration of alcohols. Present paper addresses recent developments along this line striving for larger fluxes in alcohol dehydrations by utilising ceramic membranes, with focus on vapour permeation, as well as the potential for the recovery of organic solvents and reactants forming azeotropes with other organics

OH rotational lines as a diagnostic of the warm neutral gas in galaxies

We present Infrared Space Observatory (ISO) observations of several OH, CH and H2O rotational lines toward the bright infrared galaxies NGC253 and NGC1068. As found in the Galactic clouds in SgrB2 and Orion, the extragalactic far-IR OH lines change from absorption to emission depending on the physical conditions and distribution of gas and dust along the line of sight. As a result, most of the OH rotational lines that appear in absorption toward NGC253 are observed in emission toward NGC1068. We show that the far-IR spectrum of OH can be used as a powerful diagnostic to derive the physical conditions of extragalactic neutral gas. In particular, we find that a warm (Tk~150 K, n(H2)< 5 10^4 cm^-3) component of molecular gas with an OH abundance of 10^{-7} from the inner <15'' can qualitatively reproduce the OH lines toward NGC253. Similar temperatures but higher densities (5 10^5 cm^-3) are required to explain the OH emission in NGC1068.Comment: 5 pages, 4 figures, accepted in ApJ Part I (2004, October 6

The 35Cl/37Cl isotopic ratio in dense molecular clouds: HIFI observations of hydrogen chloride towards W3A

We report on the detection with the HIFI instrument on board the Herschel satellite of the two hydrogen chloride isotopologues, H35Cl and H37Cl, towards the massive star-forming region W3A. The J=1-0 line of both species was observed with receiver 1b of the HIFI instrument at 625.9 and 624.9 GHz. The different hyperfine components were resolved. The observations were modeled with a non-local, non-LTE radiative transfer model that includes hyperfine line overlap and radiative pumping by dust. Both effects are found to play an important role in the emerging intensity from the different hyperfine components. The inferred H35Cl column density (a few times 1e14 cm^-2), and fractional abundance relative to H nuclei (~7.5e^-10), supports an upper limit to the gas phase chlorine depletion of ~200. Our best-fit model estimate of the H35Cl/H37Cl abundance ratio is ~2.1+/-0.5, slightly lower, but still compatible with the solar isotopic abundance ratio (~3.1). Since both species were observed simultaneously, this is the first accurate estimation of the [35Cl]/[37Cl] isotopic ratio in molecular clouds. Our models indicate that even for large line opacities and possible hyperfine intensity anomalies, the H35Cl and H37Cl J=1-0 integrated line-intensity ratio provides a good estimate of the 35Cl/37Cl isotopic abundance ratio.Comment: Accepted for publication in Astronomy and Astrophysics (Herschel special issue

Water in Emission in the ISO Spectrum of the Early M Supergiant Star mu Cephei

We report a detection of water in emission in the spectrum of the M2 supergiant atar mu Cep (M2Ia) observed by the Short Wavelength Spectrometer (SWS) aboard Infrared Space Observatory (ISO) and now released as the ISO Archives. The emission first appears in the 6 micron region (nu2 fundamental) and then in the 40 micron region (pure rotation lines) despite the rather strong dust emission. The intensity ratios of the emission features are far from those of the optically thin gaseous emission. Instead, we could reproduce the major observed emission features by an optically thick water sphere of the inner radius about two stellar radii (1300Rsun), Tex = 1500K, and Ncol (H2O) = 3.0E+20/cm2. This model also accounts for the H2O absorption bands in the near infrared (1.4, 1.9, and 2.7 micron) as well. The detection of water in emission provides strong constraints on the nature of water in the early M supergiant stars, and especially its origin in the outer atmosphere is confirmed against other models such as the large convective cell model. We finally confirm that the early M supergiant star is surrounded by a huge optically thick sphere of the warm water vapor, which may be referred to as MOLsphere for simplicity. Thus, the outer atmosphere of M supergiant stars should have a complicated hierarchical and/or hybrid structure with at least three major constituents including the warm MOLsphere (T about 1.0E+3K) together with the previously known hot chromosphere (T about 1.0E+4K) and cool expanding gas-dust envelope (T about 1.0E+2K).Comment: 14 pages, 5 postscript figures, to appear in ApJ

Feasibility and performances of compressed-sensing and sparse map-making with Herschel/PACS data

The Herschel Space Observatory of ESA was launched in May 2009 and is in operation since. From its distant orbit around L2 it needs to transmit a huge quantity of information through a very limited bandwidth. This is especially true for the PACS imaging camera which needs to compress its data far more than what can be achieved with lossless compression. This is currently solved by including lossy averaging and rounding steps on board. Recently, a new theory called compressed-sensing emerged from the statistics community. This theory makes use of the sparsity of natural (or astrophysical) images to optimize the acquisition scheme of the data needed to estimate those images. Thus, it can lead to high compression factors. A previous article by Bobin et al. (2008) showed how the new theory could be applied to simulated Herschel/PACS data to solve the compression requirement of the instrument. In this article, we show that compressed-sensing theory can indeed be successfully applied to actual Herschel/PACS data and give significant improvements over the standard pipeline. In order to fully use the redundancy present in the data, we perform full sky map estimation and decompression at the same time, which cannot be done in most other compression methods. We also demonstrate that the various artifacts affecting the data (pink noise, glitches, whose behavior is a priori not well compatible with compressed-sensing) can be handled as well in this new framework. Finally, we make a comparison between the methods from the compressed-sensing scheme and data acquired with the standard compression scheme. We discuss improvements that can be made on ground for the creation of sky maps from the data.Comment: 11 pages, 6 figures, 5 tables, peer-reviewed articl

GREAT: the SOFIA high-frequency heterodyne instrument

We describe the design and construction of GREAT, the German REceiver for Astronomy at Terahertz frequencies operated on the Stratospheric Observatory for Infrared Astronomy (SOFIA). GREAT is a modular dual-color heterodyne instrument for highresolution far-infrared (FIR) spectroscopy. Selected for SOFIA's Early Science demonstration, the instrument has successfully performed three Short and more than a dozen Basic Science flights since first light was recorded on its April 1, 2011 commissioning flight. We report on the in-flight performance and operation of the receiver that - in various flight configurations, with three different detector channels - observed in several science-defined frequency windows between 1.25 and 2.5 THz. The receiver optics was verified to be diffraction-limited as designed, with nominal efficiencies; receiver sensitivities are state-of-the-art, with excellent system stability. The modular design allows for the continuous integration of latest technologies; we briefly discuss additional channels under development and ongoing improvements for Cycle 1 observations. GREAT is a principal investigator instrument, developed by a consortium of four German research institutes, available to the SOFIA users on a collaborative basis

Detection of H2 pure rotational line emission from the GG~Tau binary system

We present the first detection of the low-lying pure rotational emission lines of H2 from circumstellar disks around T~Tauri stars, using the Short Wavelength Spectrometer on the Infrared Space Observatory. These lines provide a direct measure of the total amount of warm molecular gas in disks. The J=2->0 S(0) line at 28.218 mum and the J=3->1 S(1) line at 17.035 mum have been observed toward the double binary system GG Tau. Together with limits on the J=5->3 S(3) and J=7->5 S(5) lines, the data suggest the presence of gas at T_kin=110+-10 K with a mass of (3.6+-2.0)x10^-3 M_sol (3sigma). This amounts to ~3% of the total gas + dust mass of the circumbinary disk as imaged by millimeter interferometry, but is larger than the estimated mass of the circumstellar disk(s). Possible origins for the warm gas seen in H2 are discussed in terms of photon and wind-shock heating mechanisms of the circumbinary material, and comparisons with model calculations are made.Comment: 14 pages including 1 figure. To appear in Astrophysical Journal Letter