Identifying the degree of luminescence signal bleaching in fluvial sediments from the Inner Mongolian reaches of the Yellow River

Abstract The partial bleaching of the luminescence signal prior to deposition results in age overestimation, and can be a problem in delineating fluvial evolution within an OSL chronological framework. The Inner Mongolian reaches of the Yellow River are characterised by a high sediment load and complex sources of sediments. To test the incomplete bleaching occurring in this type of environment, the residual doses and the luminescence signal characteristics of different particle size fractions from 14 modern fluvial sediment samples were investigated. Furthermore, 26 OSL ages derived from drilling cores were compared with 11 radiocarbon ages. Our results show that the residual equivalent doses principally range between 0.16 and 0.49 Gy for silt grains, and between 0.35 and 3.72 Gy for sand grains of modern samples. This suggests that medium-grained quartz has been well bleached prior to deposition, and is preferable to coarse-grained quartz when dating fluvial sediments in this region. The results also show that the De values of coarse-grained fractions display a stronger correlation with distance downstream. In addition, a comparison of OSL and radiocarbon ages from drilling cores establishes further confidence that any initial bleaching of these sediments was sufficient. As a result, we believe that the studied fluvial samples were well bleached prior to deposition.</jats:p

Late Wolstonian and Ipswichian (MIS 6/5e) sediment fill in a limestone sinkhole, Askham Fell, northern England

In 2019 a sinkhole (doline) occurred in Late Devensian till above fissured limestone in northern England. Most sediment plugging the fissure was evacuated down into a karstic drainage system. The residual sedimentary fill comprises three main lithofacies, dated using optically stimulated luminescence to between 170.7 ± 40.0 and 56.1 ± 13.5 ka. The earliest date demonstrates fissures were present in the limestone pavement at the time of Marine Isotope Stage (MIS) 6, or shortly thereafter. The fissure filled with fine sand and silt due to surface runoff and aeolian processes probably at the MIS 6 to MIS 5e transition after Wolstonian glacial ice had retreated. The deposits then collapsed into the karst system. Further fine sand and silt deposition occurred during MIS 3; this deposit filled the central cavity surrounded by residual MIS 6/5e deposits. The sequence was capped by till as Late Devensian (MIS 2) ice transgressed the area. Solution fissures in the karst surfaces of northern England may pre-date the Late Devensian glaciation. Moreover, fissures are repositories of pre-Devensian sediment deposits which survived the Late Devensian glaciation and the Ipswichian interglacial. Such sites should provide information on the nature and timing of pre-Devensian glacial–interglacial events and shed light on basal ice conditions and glaciokarst drainage behaviour

Tibetan Dust Accumulation Linked to Ecological and Landscape Response to Global Climate Change

The Tibetan Plateau (TP) is a hotspot of earth system research, and understanding its landscape and ecosystem evolution has been hampered by the lack of time-constrained geological records. Geochronological data from 14 loess sites covering a large region in the Tibetan interior show that the TP loess, rather than accumulating during glacial periods, began aggrading at either 13.4 ± 0.4 or 9.9 ± 0.2 ka. An ecological threshold was crossed, when warmer and wetter conditions resulted in increased vegetation cover enabling dust trapping. This dust accumulation model is out of phase with that of the Chinese Loess Plateau (CLP) where high sedimentation rates occurred during the cold/dry glacial stages. The TP loess accumulation is in response to global climate change, at both orbital (glacial/interglacial) and millennial (e.g., Younger Dryas event) time scales, despite more complexity via ecological and landscape processes than the CLP loess. It is very important to understand the processes of landscape and ecosystem evolution in Tibet to adapt to and mitigate the consequences from potential abrupt future climate changes, but not enough well-dated geological records are available. In this study, we present stratigraphic and numerical age results from 14 loess sites covering a large region in the Tibetan interior. Results show that Tibetan loess began aggrading at either 13.4 ± 0.4 or 9.9 ± 0.2 thousand years ago. Tibetan loess accumulated during warm/interglacial conditions of the Holocene and not during the last glacial period when loess aggradation rates in the Chinese Loess Plateau were high. In Tibet, vegetation cover, which was lowered during the last glacial period, increased during Holocene warming allowing for loess accumulation

Human dispersals out of Africa via the Levant

Homo sapiens dispersed from Africa into Eurasia multiple times in the Middle and Late Pleistocene. The route, across northeastern Africa into the Levant, is a viable terrestrial corridor, as the present harsh southern Levant would probably have been savannahs and grasslands during the last interglaciation. Here, we document wetland sediments with luminescence ages falling in the last interglaciation in the southern Levant, showing protracted phases of moisture availability. Wetland sediments in Wadi Gharandal containing Levallois artifacts yielded an age of 84 ka. Our findings support the growing consensus for a well-watered Jordan Rift Valley that funneled migrants into western Asia and northern Arabia

(Invited) Synthesis and Structures of Free-Base [14]Tribenzotriphyrin(2.1.1) and Their Metal Complexes

Subporphyrins are analogues of porphyrinoids that contain only three pyrrole or isoindole rings linked by meso-sp2 carbon atoms. The first synthesis of tribenzosubporphyrins was reported by Osuka’s group in 2006 with very harsh conditions. From then on, lots of subporphyrin analogues have been reported. However, almost all of these reported subporphyrins existed only as bowl-shaped boron complexes and the yields are typically very low. In 2008, we reported a facile synthesis of meso-aryl-substituted [14]benzotriphyrin(2.1.1) compounds based on a modified Lindsey condensation method in moderate yields up to 35%. These compounds represent the first example of near planar core-free contracted porphyrinoids with 14-π-electron aromatic systems containing only the standard pyrrole and isoindoline moieties. X-ray diffraction analysis revealed that the triphyrin core is near planar. Till now, different kinds of [14]Tribenzoriphyrin(2.1.1)-metal complexes have been synthesized and characterized including Ag(I), Mn(I), Fe(II), Re(I), Ru(II), Pd(II), Rh(III), Pt(II) and Pt(IV).</jats:p

Timing of glacier fluctuations and trigger mechanisms in eastern Qinghai-Tibetan Plateau during the late Quaternary

AbstractIt is highly debated whether glacial advances on the Qinghai–Tibetan Plateau (QTP) occurred as a response to temperature cooling, or whether they were forced by an increase in moisture brought by the intensive Indian summer monsoon. We here report a case study investigating this issue. Multiple moraine series in the Yingpu Valley, Queer Shan ranges of the Hengduan Mountains, and eastern QTP, provide an excellent archive for examining the timing and trigger mechanism of glacier fluctuations. Twenty-seven optically stimulated luminescence (OSL) samples of glacial sediments were collected from this valley. The quartz OSL ages show that the moraine series of Y-1, I, M and O were formed during the Late Holocene, Late Glacial, the global Last Glacial Maximum (LGM) and Marine Oxygen Isotope Stage (MIS) 3 (likely mid-MIS-3). The youngest Y-2 moraines probably formed during the Little Ice Age (LIA). The oldest H moraines formed before MIS-3. We found that glacial advances during the late Quaternary at the Yingpu Valley responded to cold stages or cold events rather than episodes of enhanced summer monsoon and moisture. As a result, glaciers in the monsoonal Hengduan Mountains were mainly triggered by changes in temperature. Millennial time scale temperature oscillations might have caused the multiple glacial advances.</jats:p