Effects of adding aluminium in zinc bath on Co-Zn interfacial reaction

Effects of adding 0.3 wt.% Al in Zn bath on the microstructure and reaction kinetics of intermetallic compounds have been studied using Co/Zn and Co/Zn-Al solid/liquid diffusion couples by means of scanning electron microscopy (SEM) and wave dispersive spectrometry (WDS). The intermetallic compounds in the Co-Zn interface have been identified and the diffusion process of Al in zinc bath has been analyzed. The diffusion constants of intermetallic compounds have been evaluated. The chemical potential of Al and standard Gibbs free energy of intermetallic compounds have been calculated using the Co content as a variable based on the calculation of phase diagram (CALPHAD) method. The results show that the chemical potential of Al decreases with increasing Co. At the solid/liquid interface, the Co content is high, the chemical potential of Al atoms is lower than that in other areas, uphill diffusion of Al atoms occurs, and an Al-rich metastable phase forms. The Gibbs free energy of the CoAl phase is lower than that of Co-Zn compounds; therefore, the Co atoms diffuse through the γ2 layer into the Al-rich area and nucleate to form a shape-stable CoAl layer at the solid/liquid interface and significantly inhibit the Co-Zn interfacial reaction

Effects of adding aluminium in zinc bath on Co-Zn interfacial reaction

764-769Effects of adding 0.3 wt.% Al in Zn bath on the microstructure and reaction kinetics of intermetallic compounds have been studied using Co/Zn and Co/Zn-Al solid/liquid diffusion couples by means of scanning electron microscopy (SEM) and wave dispersive spectrometry (WDS). The intermetallic compounds in the Co-Zn interface have been identified and the diffusion process of Al in zinc bath has been analyzed. The diffusion constants of intermetallic compounds have been evaluated. The chemical potential of Al and standard Gibbs free energy of intermetallic compounds have been calculated using the Co content as a variable based on the calculation of phase diagram (CALPHAD) method. The results show that the chemical potential of Al decreases with increasing Co. At the solid/liquid interface, the Co content is high, the chemical potential of Al atoms is lower than that in other areas, uphill diffusion of Al atoms occurs, and an Al-rich metastable phase forms. The Gibbs free energy of the CoAl phase is lower than that of Co-Zn compounds; therefore, the Co atoms diffuse through the γ2 layer into the Al-rich area and nucleate to form a shape-stable CoAl layer at the solid/liquid interface and significantly inhibit the Co-Zn interfacial reaction

First-principles study on the preferential sites of Cr in Co7W6

The preferential sites of Cr in the μ -Co _7 W _6 phase and its influence on electronic properties were studied by first-principles calculations based on density functional theory. The calculation results of the formation energy and defect formation energy show that the stability of the system is enhanced when Cr occupies the Co site, which indicates that Cr tends to occupy the Co site of the system. By calculating the density of states, the Hamilton population of crystal orbital, the electron location function and the Bader charge distribution, the reason why Cr preferentially occupied the Co sites is further explained. This is primarily owing to the hybridization of the d-d orbitals of the Cr atom to its adjacent atoms