8,232 research outputs found

    From workers education to societal competencies: approaches to a critical, emancipatory education for democracy

    Full text link
    This article presents two conceptions concerning critical political education for workers, developed in Germany in the 1960s and the 1990s respectively. First, the conception of “Sociological Imagination and Exemplary Learning” published in 1968 by the German philosopher and sociologist Oskar Negt (1975). Further the elaboration of this conception, which since the 1980s is known as “Societal Competencies“ (Negt, 1986). These competencies concern fundamental knowledge, which enables people to make political judgments, and act politically in democratic societies in an enlightened and reflected way. This conception deliberately distinguishes itself from the economic, instrumentalist notions of key qualifications and key competencies, which at least since the 1970s have been discussed with the aim of maintaining individual employability and competitiveness. ‘Societal competencies’ aim for individual and collective emancipation, the development of the capability to make judgments, and autonomy in the sense of the enlightened political agency and participation in democratization processes. (DIPF/Orig.

    Cubic di-μ-amido-bis[bis(η5-cyclopentadienyl)ytterbium(III)]

    Get PDF
    The title compound, [Yb2(C5H5)4(NH2)2], was synthesized in a Parr high-pressure vessel starting from monoclinic [Cp2YbNH2]2 (where Cp = cyclopentadienyl). The complex is located on a special position of site symmetry mmm with just an eighth of the complex in the asymmetric unit. The Yb atom is in a distorted tetrahedral coordination environment, coordinated by two cyclopentadienyl rings and two amino groups forming a dimeric complex bridged through the amino groups. This compound represents the high-pressure cubic modification of monoclinic [Cp2YbNH2]2 obtained at 250 bar (1 bar = 105 Pa) under an atmosphere of argon

    One-Pot Synthesis of Single-Source Precursors for Nanocrystalline LED Phosphors M2Si5N8:Eu2+ (M = Sr, Ba)

    Get PDF
    Highly efficient red-emitting nitridosilicate phosphors Sr2Si5N8:Eu2+ and Ba1.5Sr0.5Si5N8:Eu2+ (doping level 1%) applicable to phosphor converted pc-LEDs were synthesized in nanocrystalline form at low temperatures employing a novel single-source precursor approach. Synthesis starts from nanocrystalline silicon and uses mixed metal amides M(NH2)2 with M = Sr, Ba, Eu as reactive intermediates. In a second approach, a single-source precursor mixture obtained from a one-pot reaction of the corresponding elements (Sr/Ba, Eu, Si) was obtained in supercritical ammonia. Thermoanalytical in situ investigations gain a deeper insight into the degradation mechanism of the mixed metal amide precursors and revealed the onset for the formation of the 2-5-8 phosphor materials at temperatures slightly above 900°C. Formation of the products is complete below 1400°C. Under these conditions, the nitridosilicate phosphors form spherically shaped particles with crystallites of 200 nm in size. Spherical particles are desirable for phosphor application because light extraction may be improved by decreased light trapping and re-absorption losses. As a major advantage of the one-pot precursor approach, the exact Sr/Ba content in the solid solution series Sr2−xBaxSi2N8:Eu2+ and the doping concentration of Eu2+ can easily be controlled in a wide range by the relative amount of the elemental starting materials (Sr, Ba, Eu, Si). Simultaneously, thorough mixing of these elements down to an atomic level (Sr, Ba, Eu) or at least at nanoscopic dimensions (silicon) is achieved by the solution approach. As a consequence, no milling and pre-reaction steps are necessary which might give rise to contamination. Advantageously, this approach can easily be extended to large-scale processes by simultaneously preserving complete mixing. Furthermore, the influence of the starting materials (single-source precursor, nanocrystalline silicon) and the reaction conditions on the crystal shape and finally on the luminescence properties of the products was investigated. The obtained nanophosphors exhibit luminescence properties comparable to coarsely crystalline nitridosilicate phosphor powders prepared by conventional high-temperature processing

    An optical readout for a fibre tracker

    Get PDF
    The performance of 16 and 64 channel photomultipliers coupled to scintillating fibres has been tested. The devices are sensitive to single photoelectrons, show little gain losses for magnetic fields up to 100 Gauss and have moderate optical cross-talk. The maximum channel to channel gain variations reach a factor two for the 16 channel version and a factor of four for the 64 channel PM. The measurements and simulations indicate that the photomultipliers are well suited for the light detection in fibre trackers.Comment: 11 pages, 9 picture

    Detection of spatially structured scattering polarization of Sr i 4607.3 Å with the Fast Solar Polarimeter

    Get PDF
    Context. Scattering polarization in the Sr I 4607.3 Å line observed with high resolution is an important diagnostic of the Sun's atmosphere and magnetism at small spatial scales. Investigating the scattering polarization altered by the Hanle effect is key to constraining the role of small-scale magnetic activity in solar atmospheric activity and energy balance. At present, spatially resolved observations of this diagnostic are rare and have not been reported as close to the disk center as for μ = 0.6. Aims. Our aim is to measure the scattering polarization in the Sr I line at μ = 0.6 and to identify the spatial fluctuations with a statistical approach. Methods. Using the Fast Solar Polarimeter (FSP) mounted on the TESOS filtergraph at the German Vacuum Tower Telescope (VTT) in Tenerife, Spain, we measured both the spatially resolved full Stokes parameters of the Sr I line at μ = 0.6 and the center-to-limb variation of the spatially averaged Stokes parameters. Results. We find that the center-to-limb variation of the scattering polarization in the Sr I line measured with FSP is consistent with previous measurements. A statistical analysis of Stokes Q/I (i.e., the linear polarization component parallel to the solar limb), sampled with 0.16″ pixel-1 in the line core of Sr I reveals that the signal strength is inversely correlated with the intensity in the continuum. We find stronger linear polarimetric signals corresponding to dark areas in the Stokes I continuum image (intergranular lanes). In contrast, independent measurements at μ = 0.3 show a positive correlation of Q/I with respect to the continuum intensity. We estimate that the subregion diameter responsible for the excess Q/I signal is on the order of 0.5″-1″. Conclusions. The presented observations and the statistical analysis of Q/I signals at μ = 0.6 complement reported scattering polarization observations as well as simulations. The FSP has proven to be a suitable instrument to measure spatially resolved scattering polarization signals. In the future, a systematic center-to-limb series of observations with subgranular spatial resolution and increased polarimetric sensitivity (<10-3) compared to that in the present study is needed in order to investigate the change in trend with μ that the comparison of our results with the literature suggests.Fil: Zeuner, F.. Universität Göttingen; Alemania. Institut für Sonnensystemforschung; AlemaniaFil: Feller, A.. Institut für Sonnensystemforschung; AlemaniaFil: Iglesias, Francisco Andres. Institut für Sonnensystemforschung; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza; ArgentinaFil: Solanki, S.K.. Institut für Sonnensystemforschung; Alemania. Kyung Hee University; Corea del Su

    Anti-phospholipid-antibodies in patients with relapsing polychondritis

    Get PDF
    Relapsing polychondritis (RP) is an extremly rare multisystemic disease thought to be of autoimmune origin. In order to assess if RP is associated with anti-phospholipid antibodies (aPL), clinical data and sera of 21 patients with RP were collected in a multicentre study. Concentration of anti-cardiolipin antibodies (aCL) (IgG-, IgM-and IgA-isotypes), anti-phosphatidylserine-antibodies (aPS) (IgG-and IgM-isotypes) and anti-β-2-glycoprotein I-antibodies (aβ2 GPI) were measured by ELISA. In eight patients aCL were found to be elevated. One patient had elevated aPS. No patient had elevated aβ2 GPI. No patient had clinical signs and symptoms of a aPL syndrome. Interestingly, the two RP patients with the highest aPL had concomitant systemic lupus erythematosus (SLE). Therefore the presence of elevated aPL in RP is probably more closely related to an associated SLE than to RP itself. There is no convincing evidence that aPL are associated with RP

    Solvent engineering and other reaction design methods for favouring enzyme-catalysed synthesis

    Get PDF
    corecore