27 research outputs found

    Hot Nano-particles in Polar or Paramagnetic Liquids Interact as Monopoles.

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    When neutral nano-particles are heated or cooled in a polar liquid, they will interact with each other as if they carry an electrostatic charge that is proportional to the temperature difference between the particle and the surrounding fluid. The same should hold for suspensions liquids of asymmetric ferromagnetic particles, in which case the heated nano-particles should behave as magnetic monopoles. However, the analogy with electrostatics/magnetostatics is not complete: heated/cooled nano-particles do not move under the influence of an applied homogeneous field. They should, however, interact as monopoles with each other and should move in inhomogeneous fields.This is the author accepted manuscript. The final version is available from the American Chemical Society via https://doi.org/10.1021/acs.jpcb.6b0184

    Thermodynamic and Electron Diffraction Signatures of Charge and Spin Ordering in La1-xCaxMnO3

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    The large-magnetoresistance compounds La1-xCaxMnO3 have been studied using specific heat, sound velocity (v), and electron diffraction. For 0.63 ≤ x ≤ 0.67 charge ordering is observed at 260 K and accompanied by a dramatic (>10%) increase in v. This simultaneous occurrence of electron and lattice ordering features implies extremely strong electron-phonon coupling, known to exist for the octahederally coordinated d4 ion and originating in the Jahn-Teller effect. A dynamic manifestation of this Jahn-Teller coupling has been suggested by Millis et al. as the origin for colossal magnetoresistance.

    Thermal Stability of Azole‐Coated Copper Surfaces

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    Multicenter comprehensive methodological and technical analysis of 832 pressurized intraperitoneal aerosol chemotherapy (PIPAC) interventions performed in 349 patients for peritoneal carcinomatosis treatment: An international survey study.

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    Pressurized intraperitoneal aerosol chemotherapy (PIPAC) is a new drug delivery method offered in selected patients suffering from non-resectable peritoneal carcinomatosis (PC). As reported experience is still limited, we conducted a survey among active PIPAC centers aiming to report their technical approach and clinical findings. An online survey was sent to active PIPAC centers worldwide. The questionnaire consisted of 34 closed questions and was conducted over a period of 3 months beginning in March 2017. Nine out of 15 contacted centers completed the questionnaire totaling 832 PIPAC procedures in 349 patients. Most common indications for PIPAC were PC from gastric, ovarian and colorectal origin. The mean time between each PIPAC procedure was 6-8 weeks. Seven of nine (77.8%) centers evaluate the PCI at every PIPAC procedure. At least four tissue samples for histopathology analysis were retrieved in 5 (55.6%). All centers (100%) use the same chemotherapy protocol: oxaliplatin at a dosage of 92mg/m <sup>2</sup> for PC of colorectal origin and a combination of cisplatin and doxorubicin at a dosage of 7.5mg/m <sup>2</sup> and 1.5mg/m <sup>2</sup> , respectively, for other types of PC. Eight centers (88.9%) perform routine radiological evaluation before first PIPAC and after third PIPAC. These data confirm that PIPAC procedures are homogeneously performed in established centers. Standardization of the procedure will facilitate future international multicenter prospective clinical trials
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