Attractive forces in microporous carbon electrodes for capacitive deionization

The recently developed modified Donnan (mD) model provides a simple and useful description of the electrical double layer in microporous carbon electrodes, suitable for incorporation in porous electrode theory. By postulating an attractive excess chemical potential for each ion in the micropores that is inversely proportional to the total ion concentration, we show that experimental data for capacitive deionization (CDI) can be accurately predicted over a wide range of applied voltages and salt concentrations. Since the ion spacing and Bjerrum length are each comparable to the micropore size (few nm), we postulate that the attraction results from fluctuating bare Coulomb interactions between individual ions and the metallic pore surfaces (image forces) that are not captured by meanfield theories, such as the Poisson-Boltzmann-Stern model or its mathematical limit for overlapping double layers, the Donnan model. Using reasonable estimates of the micropore permittivity and mean size (and no other fitting parameters), we propose a simple theory that predicts the attractive chemical potential inferred from experiments. As additional evidence for attractive forces, we present data for salt adsorption in uncharged microporous carbons, also predicted by the theory.Comment: 19 page

Contact transformations for difference schemes

We define a class of transformations of the dependent and independent variables in an ordinary difference scheme. The transformations leave the solution set of the system invariant and reduces to a group of contact transformations in the continuous limit. We use a simple example to show that the class is not empty and that such "contact transformations for discrete systems" genuinely exist

Aperiodic nano-photonic design

The photon scattering properties of aperiodic nano-scale dielectric structures can be tailored to closely match a desired response by using adaptive algorithms for device design. We show that broken symmetry of aperiodic designs provides access to device functions not available to conventional periodic photonic crystal structures.Comment: 23 pages, LaTex, 8 postscript figure

Saturated VSD model of a six-phase induction machine

In this paper, a saturated model of an asymmetrical six-phase induction machine is presented. The model is based on the vector space decomposition approach, and it includes main and leakage flux saturation, as well as the mutual coupling between orthogonal planes, while using the Gamma equivalent circuit approach. The accuracy of the proposed model in unbalanced operating modes that are characteristic for multiphase machines, such as post-fault and power sharing operation, makes it advantageous compared to existing models. The model is developed assuming that the machine operates in asymmetrical conditions and that, therefore, there is fundamental frequency excitation in both planes. The inter-plane coupling effect is examined using finite element analysis and an experimental procedure for its quantification is developed. The model is verified by comparison with the experimental results obtained from a prototype asymmetrical six-phase induction machine, and its advantages compared to existing models are emphasized

Non-Relativistic Gravitation: From Newton to Einstein and Back

We present an improvement to the Classical Effective Theory approach to the non-relativistic or Post-Newtonian approximation of General Relativity. The "potential metric field" is decomposed through a temporal Kaluza-Klein ansatz into three NRG-fields: a scalar identified with the Newtonian potential, a 3-vector corresponding to the gravito-magnetic vector potential and a 3-tensor. The derivation of the Einstein-Infeld-Hoffmann Lagrangian simplifies such that each term corresponds to a single Feynman diagram providing a clear physical interpretation. Spin interactions are dominated by the exchange of the gravito-magnetic field. Leading correction diagrams corresponding to the 3PN correction to the spin-spin interaction and the 2.5PN correction to the spin-orbit interaction are presented.Comment: 10 pages, 3 figures. v2: published version. v3: Added a computation of Einstein-Infeld-Hoffmann in higher dimensions within our improved ClEFT which partially confirms and partially corrects a previous computation. See notes added at end of introductio

Normal frames for general connections on differentiable fibre bundles

The theory of frames normal for general connections on differentiable bundles is developed. Links with the existing theory of frames normal for covariant derivative operators (linear connections) in vector bundles are revealed. The existence of bundle coordinates normal at a given point and/or along injective horizontal path is proved. A necessary and sufficient condition of existence of bundle coordinates normal along injective horizontal mappings is derived.Comment: 24 LaTeX pages. The packages AMS-LaTeX and amsfonts are required. In version 2 some results are generalized and proved under weaker conditions. For other papers on the same topic view the "publication" pages at http://theo.inrne.bas.bg/~bozho

Quasistationary binary inspiral. I. Einstein equations for the two Killing vector spacetime

The geometry of two infinitely long lines of mass moving in a fixed circular orbit is considered as a toy model for the inspiral of a binary system of compact objects due to gravitational radiation. The two Killing fields in the toy model are used, according to a formalism introduced by Geroch, to describe the geometry entirely in terms of a set of tensor fields on the two-manifold of Killing vector orbits. Geroch's derivation of the Einstein equations in this formalism is streamlined and generalized. The explicit Einstein equations for the toy model spacetime are derived in terms of the degrees of freedom which remain after a particular choice of gauge.Comment: 37 pages, REVTeX, one PostScript Figure included with epsfig; minor formatting changes and copyright notice added for journal publicatio