Climate change mitigation potential of lignocellulosic succinic acid: assessing feedstock supply and integrated land use options in a UK Wheat-Miscanthus bio-succinic acid-based bioplastics production system

This research addresses emergent societal concerns driving national policies that seek to replace or reduce the use of petro-based plastics. Whilst environmental pollution by plastics is the dominant contemporary driver, alternatives will also need to demonstrate wider environmental and social benefits, not least the reduction of Greenhouse Gas (GHG) emissions. Biodegradable plastics produced from bio-based Succinic Acid (SA) are evaluated as an alternative to petro-based plastics in the context of the transition to a post-petroleum era. A case study-based methodology was adopted that uses a feedstock catchment area near Hull, England, to provide high spatial and temporal resolution bio-physical, agronomic and climatic data to parameterise quantitative models for crop growth, nitrogen and carbon turnover and life cycle assessment (LCA). The main research questions are: (1) how can the feedstock availability of lignocellulosic biomass (LCB) be optimized, and; (2) can the associated GHG emissions of the commercial scale production of LCB-derived SA be reduced by the using agricultural residues and/or perennial, LCB crops? The results of this case study suggest that significant environmental benefits would result from the adoption of a mixed LCB resourcing strategy. Introducing the perennial grass crop Miscanthus into the arable landscape to replace winter wheat on selected low quality, and environmentally vulnerable soils (8% of the total area) is the main driver for the benefits. A ‘mixed production’ (MP) scenario, using Miscanthus and winter wheat, and a ‘winter wheat only’ single production (SP) scenario, were developed to investigate the productivity and the potential climate change mitigation impacts arising from the proposed land use change strategy i.e. a shift from the SP to MP scenarios. LCAs were conducted to explore the climate mitigation potential of LCB-based SA production. Integrated feedstock provision strategies that include perennial-derived LCB are found to be crucial for the overall climate mitigation performance of bio-plastics. A significant bioeconomy and agricultural opportunity has been identified for the provision of LCB-derived bio-plastics from dedicated, perennial crops. Scenarios without the perennial crop resulted in GHG emission balances of bio-SA based plastics that were similar to grain and petro-based plastics. In the scenario of Miscanthus being cultivated on low-quality soils, the LCB-based SA life cycle results in a persistent net carbon sink being generated.Open Acces

Limiting shape of profile due to dual-mode fretting wear in contact with an elastomer

Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich.This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.We consider fretting wear due to superimposed normal and tangential oscillations of two contacting bodies, one of which is an elastomer with a linear rheology. Similarly to the contact of elastic bodies, at small oscillation amplitudes, the wear occurs only in a circular slip zone at the border of the contact area and the wear profile tends to a limiting form, in which no further wear occurs. It is shown that under assumption of a constant coefficient of friction at the contact interface, the limiting form of the wear profile does depend neither on the particular wear criterion nor on the rheology of the elastomer and can be calculated analytically in a general form. The general calculation procedure and explicit analytic solutions for two initial forms, parabolic and conical, are presented for various combinations of frequencies and phases of normal and tangential oscillations as well as for various linear rheologies of the elastomer

Construction of stable Ta3N5/g-C3N4 metal/non-metal nitride hybrids with enhanced visible-light photocatalysis

In this paper, a novel Ta3N5/g-C3N4 metal/non-metal nitride hybrid was successfully synthesized by a facile impregnation method. The photocatalytic activity of Ta3N5/g-C3N4 hybrid nitrides was evaluated by the degradation of organic dye rhodamine B (RhB) under visible light irradiation, and the result indicated that all Ta3N5/g-C3N4 samples exhibited distinctly enhanced photocatalytic activities for the degradation of RhB than pure g-C3N4. The optimal Ta3N5/g-C3N4 composite sample, with Ta3N5 mass ratio of 2%, demonstrated the highest photocatalytic activity, and its degradation rate constant was 2.71 times as high as that of pure g-C3N4. The enhanced photocatalytic activity of this Ta3N5/g-C3N4 metal/metal-free nitride was predominantly attributed to the synergistic effect which increased visible-light absorption and facilitated the efficient separation of photoinduced electrons and holes. The Ta3N5/g-C3N4 hybrid nitride exhibited excellent photostability and reusability. The possible mechanism for improved photocatalytic performance was proposed. Overall, this work may provide a facile way to synthesize the highly efficient metal/metal-free hybrid nitride photocatalysts with promising applications in environmental purification and energy conversion

Sheep 7SK promoter for short hairpin RNA expression

Background: Gene silencing mediated by small interfering RNA (siRNA) has become a powerful biological tool for the regulation of gene expression. For the synthesis of siRNA by vector-based expression systems, several mammalian small nuclear RNA (snRNA) promoters have been cloned and shown different transcriptional efficiencies. Results: In this study, we identified a sheep 7SK snRNA (s7SK) promoter based on the highly conserved polymerase III promoter elements. Promoter activity was measured by promoter-driven shRNA expression to suppress expression of an exogenous reporter gene and endogenous sheep gene. Conclusions: The knock down assay demonstrated that the s7SK induced more stronger inhibition effect than human U6 and H1 promoters. The use of this native sheep 7SK promoter for shRNA expressionis an important component for development of RNAi-based gene therapy and production of transgenic animals in sheep species

Second-generation bio-based plastics are becoming a reality - Non-renewable energy and greenhouse gas (GHG) balance of succinic acid-based plastic end products made from lignocellulosic biomass:NREU and GHG balance of succinic acid-based PBS products made from lignocellulosic biomass

Bio-based and bio-degradable plastics such as polybutylene succinate (PBS) have the potential to become sustainable alternatives to petrochemical-based plastics. Polybutylene succinate can be produced from bio-based succinic acid and 1,4-butanediol using first-generation (1G) or second-generation (2G) sugars. A cradle-to-grave environmental assessment was performed for PBS products in Europe to investigate the non-renewable energy use (NREU) and greenhouse gas (GHG) impacts. The products investigated are single-use trays and agricultural film, with incineration, industrial composting and degradation on agricultural land as end-of-life scenarios. Both end products manufactured from fully bio-based PBS and from partly bio-based PBS (made from bio-based succinic acid and fossil fuel-based 1,4 butanediol) were analysed. We examine corn (1G) as well as corn stover, wheat straw, miscanthus and hardwood as 2G feedstocks. For the cradle-to-grave system, 1G fully bio-based PBS plastic products were found to have environmental impacts comparable with their petrochemical incumbents, while 2G fully bio-based PBS plastic products allow to reduce NREU and GHG by around one third under the condition of avoidance of concentration of sugars and energy integration of the pretreatment process with monomer production. Without energy integration and with concentration of sugars (i.e., separate production), the impacts of 2G fully bio-based PBS products are approximately 15–20% lower than those of 1G fully bio-based PBS products. The environmental analysis of PBS products supports the value proposition related to PBS products while also pointing out areas requiring further research and development

TRY plant trait database – enhanced coverage and open access

Plant traits - the morphological, anatomical, physiological, biochemical and phenological characteristics of plants - determine how plants respond to environmental factors, affect other trophic levels, and influence ecosystem properties and their benefits and detriments to people. Plant trait data thus represent the basis for a vast area of research spanning from evolutionary biology, community and functional ecology, to biodiversity conservation, ecosystem and landscape management, restoration, biogeography and earth system modelling. Since its foundation in 2007, the TRY database of plant traits has grown continuously. It now provides unprecedented data coverage under an open access data policy and is the main plant trait database used by the research community worldwide. Increasingly, the TRY database also supports new frontiers of trait‐based plant research, including the identification of data gaps and the subsequent mobilization or measurement of new data. To support this development, in this article we evaluate the extent of the trait data compiled in TRY and analyse emerging patterns of data coverage and representativeness. Best species coverage is achieved for categorical traits - almost complete coverage for ‘plant growth form’. However, most traits relevant for ecology and vegetation modelling are characterized by continuous intraspecific variation and trait–environmental relationships. These traits have to be measured on individual plants in their respective environment. Despite unprecedented data coverage, we observe a humbling lack of completeness and representativeness of these continuous traits in many aspects. We, therefore, conclude that reducing data gaps and biases in the TRY database remains a key challenge and requires a coordinated approach to data mobilization and trait measurements. This can only be achieved in collaboration with other initiatives

Assessing Sea Surface Temperatures Estimated from Fused Infrared and Microwave Data

Sea surface temperature (SST), a critical parameter of the global ocean–atmosphere system, is an essential element in the study and in the application of marine science. Satellite–infrared observations currently represent the only available method for continuous, large-scale observation of SST. Although passive microwave observations are not blocked by clouds, allowing for data collection in all weather conditions, this technological tool is characterized by low spatial resolution. Conversely, infrared observations offer high resolution but are susceptible to cloud obscuration. Accordingly, a technique that effectively fuses microwave and infrared satellite observations into a high-resolution SST field with global coverage close to the actual distribution is of practical significance. This paper describes fusing MODIS infrared remote sensing and AMSR-2 microwave remote sensing SST data with an optimal interpolation (OI) approach to produce a high-resolution SST data. The study chose the coastal Kuroshio region of China to establish an appropriate scale for examining the spatial structure of SST and attaining a more realistic picture of SST observations and impacts. The included discussion of the sources of error in the fusion process provides a reference for improving the accuracy of fused marine remote sensing data. The study also compared the fused SST results and the current international mainstream multi-temporal resolution of the three using the OI algorithm. We compared the fusion product with ARGO data with and without typhoon impact to explore and practice the OI in SST fusion when evaluating the accuracy of different data in the case of external disturbance being present. The research results have great significance for improving regional SST forecast accuracy while ensuring the applicability of various approaches to fusing SST data by incorporating the influence of typhoons in the offshore region of the East China Sea (ECS). Implications for the future development of SST fusion data are also included in the discussion

¹³C Labelling of Litter Added to Tea (<i>Camellia sinensis</i> L.) Plantation Soil Reveals a Significant Positive Priming Effect That Leads to Less Soil Organic Carbon Accumulation

Although annual return of litter occurs in tea (Camellia sinensis L.) plantations, the level of soil organic carbon (SOC) therein remains relatively low. The exact impacts of pruned litter on soil and its association with SOC accumulation in tea plantations remain unclear. In this study, we prepared 13C-labeled tea plant material and incubated it with soils collected at a tea plantation. Carbon dioxide (CO2) efflux and its sources were measured and distinguished based on the 13C isotopic method. Soil microbial community and the utilization of litter C were assessed by phospholipid fatty acid (PLFA) analysis combined with a stable isotope probing (SIP) technique. Litter incorporation initially significantly increased CO2 efflux. The majority of CO2 production (>90%) arose from native SOC mineralization, which was reflected by a strong positive priming effect (PE) that decreased over time. During the incubation period, β-glucosidase activity significantly decreased in both the control and litter-amended soil. A significant difference in the microbial community was observed between control and litter-amended soil, in which litter incorporation significantly increased the biomass of each microbial group relative to control soil. Based on PLFA-SIP, 78% of the C incorporated into individual microbes was derived from native SOC, while only 22% was derived from litter. Additionally, partial least squares regression path modeling (PLS-PM) revealed that the microbes associated with native SOC mineralization directly affected the changes in SOC (ΔCSOC+litter), whereas microbes related to litter degradation exhibited an indirect effect on ΔCSOC+litter by affecting β-glucosidase activity under litter incorporation. Taken together, SOC accumulated less in the tea plantation system despite the annual return of pruned litter to the field