9 research outputs found

    Structural, electronic, and magneto-optical properties of YVO3_3

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    Optical and magneto-optical properties of YVO3_3 single crystal were studied in FIR, visible, and UV regions. Two structural phase transitions at 75 K and 200 K were observed and established to be of the first and second order, respectively. The lattice has an orthorhombic PbnmPbnm symmetry both above 200 K as well as below 75 K, and is found to be dimerized monoclinic Pb11Pb11 in between. We identify YVO3_3 as a Mott-Hubbard insulator with the optical gap of 1.6 eV. The electronic excitations in the visible spectrum are determined by three dd-bands at 1.8, 2.4, and 3.3 eV, followed by the charge-transfer transitions at about 4 eV. The observed structure is in good agreement with LSDA+UU band structure calculations. By using ligand field considerations, we assigned these bands to the transitions to the 4A2g^4A_{2g}, 2Eg+2T1g^2E_{g} + ^2T_{1g}, and 2T2g^2T_{2g} states. The strong temperature dependence of these bands is in agreement with the formation of orbital order. Despite the small net magnetic moment of 0.01 μB\mu_B per vanadium, the Kerr effect of the order of 0.010.01^\circ was observed for all three dd-bands in the magnetically ordered phase TNeˊel<116KT_{\text{N\'eel}}<116 K. A surprisingly strong enhancement of the Kerr effect was found below 75 K, reaching a maximum of 0.10.1^\circ. The effect is ascribed to the non-vanishing net orbital magnetic moment.Comment: Submitted to Phys. Rev.

    Anisotropy of the orbital methods and the magnetic dipole term TzT_z in CrO2{\rm CrO_2}: An {\it ab-initio} studt

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    A systematic study is performed by the {\it ab-initio} density functional theory of the anisotropy of the orbital moments andthemagneticdipoleterm and the magnetic dipole term in bulk CrO2{\rm CrO_2}. Two different band-structure techniques are used (FLAPW and LMTO-ASA), and the electronic correlations are treated by the local-spin-density approximation (LSDA), the LSDA+ orbital polarization method, and the LSDA+UU method. The calculated anisotropies of and and are very large compared to Fe, Ni and Co but still a factor of 5 and 2 smaller than the anisotropies obtained from a recently suggested analysis of the X-ray magnetic circular dichroism spectra for a thick layer of CrO2{\rm CrO_2}

    Very-large-mode-area photonic bandgap Bragg fiber polarizing in a wide spectral range

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    International audienceA design of a polarizing all-glass Bragg fiber with a microstructure core has been proposed for the first time. This design provides suppression of high-order modes and of one of the polarization states of the fundamental mode. The polarizing fiber was fabricated by a new, simple method based on a combination of the modified chemical vapor deposition (MCVD) process and the rod-in-tube technique. The mode field area has been found to be about 870 μm2 near λ=1064 nm . The polarization extinction ratio better than 13 dB has been observed over a 33% wavelength range (from 1 to 1.4 μm ) after propagation in a 1.7 m fiber piece bent to a radius of 70 cm
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