127,141 research outputs found
The vibrational predissociation spectroscopy of hydrogen cluster ions
The first infrared spectra of protonated hydrogen clusters in the gas phase have been observed. Predissociation spectra were taken with a tandem mass spectrometer: mass selected hydrogen cluster ions were irradiated inside a rf ion trap by a tunable infrared laser, and the fragment ions created by photodissociation of the clusters were mass selected and detected. Spectra for each product channel were measured by counting fragment ions as a function of laser frequency. Low resolution spectra (Deltanu=10 cm^−1) in the region from 3800 to 4200 cm^−1 were observed for the ions H + 5, H + 7, and H + 9 at 3910, 3980, and 4020 cm−1, respectively. A band was also observed for H + 5 at 3532 cm^−1. No rotational structure was resolved. The frequencies of the band maxima agree well with the frequencies predicted by previous ab initio calculations for the highest modes
Theoretical studies of the transport and removal processes of Sahara dust
The processes controlling the evolution of aerosol particles may be divided into dynamic processes concerned with the motions of air currents and microphysical processes concerned with the growth of the individual particles. The Ames planetary boundary layer model was modified to construct a subsynoptic scale aerosol model to study the long term fate of the Saharan dust. The transport model consists of a mixed layer, a convection layer, and free atmosphere. Conditions used for a preliminary test run and results obtained are described
Subleading Shape-Function Effects and the Extraction of |V_ub|
We derive a class of formulae relating moments of B -> Xu l nu to B -> Xs
gamma in the shape function region, where m_X^2 ~ m_b Lambda_QCD. We also
derive an analogous class of formulae involving the decay B -> Xs l+ l-. These
results incorporate Lambda_QCD/m_b power corrections, but are independent of
leading and subleading hadronic shape functions. Consequently, they enable one
to determine |V_ub|/|V_tb V_ts*| to subleading order in a model-independent
way.Comment: 23 page
Renormalization Group Technique Applied to the Pairing Interaction of the Quasi-One-Dimensional Superconductivity
A mechanism of the quasi-one-dimensional (q1d) superconductivity is
investigated by applying the renormalization group techniques to the pairing
interaction. With the obtained renormalized pairing interaction, the transition
temperature Tc and corresponding gap function are calculated by solving the
linearized gap equation. For reasonable sets of parameters, Tc of p-wave
triplet pairing is higher than that of d-wave singlet pairing due to the
one-dimensionality of interaction. These results can qualitatively explain the
superconducting properties of q1d organic conductor (TMTSF)2PF6 and the ladder
compound Sr2Ca12Cu24O41.Comment: 18 pages, 9 figures, submitted to J. Phys. Soc. Jp
Infrared spectra of the cluster ions H7O<sup> + </sup><sub>3</sub>·H2 and H9O<sup> + </sup><sub>4</sub>·H2
Infrared spectra of hydrated hydronium ions weakly bound to an H2 molecule, specifically H7O + 3 ·H2 and H9O + 4 ·H2, have been observed. Mass-selected parent ions, trapped in a radio frequency ion trap, are excited by a tunable infrared laser; following absorption, the complex predissociates with loss of the H2, and the resulting fragment ions are detected. Spectra have been taken from 3000 to 4000 cm^−1, with a resolution of 1.2 cm^−1. They are compared to recent theoretical and experimental spectra of the hydronium ion hydrates alone. Binding an H2 molecule to these clusters should only weakly perturb their vibrations; if so, our spectra should be similar to spectra of the hydrated hydronium ions H7O + 3 and H9O + 4
Symmetric Triple Well with Non-Equivalent Vacua: Instantonic Approach
We show that for the triple well potential with non-equivalent vacua,
instantons generate for the low lying energy states a singlet and a doublet of
states rather than a triplet of equal energy spacing. Our energy splitting
formulae are also confirmed numerically. This splitting property is due to the
presence of non-equivalent vacua. A comment on its generality to multi-well is
presented.Comment: 10 pages, 3 figures, 2 tables; minor changes; added reference
Acetylene terminated matrix resins
The synthesis of resins with terminal acetylene groups has provided a promising technology to yield high performance structural materials. Because these resins cure through an addition reaction, no volatile by-products are produced during the processing. The cured products have high thermal stability and good properties retention after exposure to humidity. Resins with a wide variety of different chemical structures between the terminal acetylene groups are synthesized and their mechanical properties studied. The ability of the acetylene cured polymers to give good mechanical properties is demonstrated by the resins with quinoxaline structures. Processibility of these resins can be manipulated by varying the chain length between the acetylene groups or by blending in different amounts of reactive deluents. Processing conditions similar to the state-of-the-art epoxy can be attained by using backbone structures like ether-sulfone or bis-phenol-A. The wide range of mechanical properties and processing conditions attainable by this class of resins should allow them to be used in a wide variety of applications
Monolithic arrays of surface emitting laser NOR logic devices
Monolithic, cascadable, laser-logic-device arrays have been realized and characterized. The monolithic surface-emitting laser logic (SELL) device consists of an AlGaAs superlattice lasing around 780 nm connected to a heterojunction phototransistor (HPT) in parallel and a resistor in series. Arrays up to 8×8 have been fabricated, and 2×2 arrays show uniform characteristics. The optical logic output is switched off with 40 μW incident optical input
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