948 research outputs found

    Unstable capillary waves on surface of separation of two viscous fluids

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    The study of the breakup of a liquid jet moving in another medium, for example, a jet of fuel from a nozzle, shows that for sufficiently large outflow velocities the jet breaks up into a certain number of drops of different diameters. At still larger outflow velocities, the continuous part of the jet practically vanishes and the jet immediately breaks up at the nozzle into a large number of droplets of varying diameters (the case of "atomization"). The breakup mechanism in this case has a very complicated character and is quite irregular, with the droplets near the nozzle forming a divergent cone

    Impact of nanosecond proton beam processing on nanoblocks of copper

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    X-ray studies in conjunction with the method of recoil nuclei and electron microscopy of irradiated plates polycrystalline Cu by nanosecond high power density proton beams (E=120 keV; I=80 A/cm{2}, t=50 ns) showed nano block nature of the formation of structure in the surface layer target and condensed-formed film

    Convective Term and Transversely Driven Charge-Density Waves

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    We derive the convective terms in the damping which determine the structure of the moving charge-density wave (CDW), and study the effect of a current flowing transverse to conducting chains on the CDW dynamics along the chains. In contrast to a recent prediction we find that the effect is orders of magnitude smaller, and that contributions from transverse currents of electron- and hole-like quasiparticles to the force exerted on the CDW along the chains act in the opposite directions. We discuss recent experimental verification of the effect and demonstrate experimentally that geometry effects might mimic the transverse current effect.Comment: RevTeX, 9 pages, 1 figure, accepted for publications in PR

    Extreme value statistics from the Real Space Renormalization Group: Brownian Motion, Bessel Processes and Continuous Time Random Walks

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    We use the Real Space Renormalization Group (RSRG) method to study extreme value statistics for a variety of Brownian motions, free or constrained such as the Brownian bridge, excursion, meander and reflected bridge, recovering some standard results, and extending others. We apply the same method to compute the distribution of extrema of Bessel processes. We briefly show how the continuous time random walk (CTRW) corresponds to a non standard fixed point of the RSRG transformation.Comment: 24 pages, 5 figure

    Conformational and Structural Relaxations of Poly(ethylene oxide) and Poly(propylene oxide) Melts: Molecular Dynamics Study of Spatial Heterogeneity, Cooperativity, and Correlated Forward-Backward Motion

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    Performing molecular dynamics simulations for all-atom models, we characterize the conformational and structural relaxations of poly(ethylene oxide) and poly(propylene oxide) melts. The temperature dependence of these relaxation processes deviates from an Arrhenius law for both polymers. We demonstrate that mode-coupling theory captures some aspects of the glassy slowdown, but it does not enable a complete explanation of the dynamical behavior. When the temperature is decreased, spatially heterogeneous and cooperative translational dynamics are found to become more important for the structural relaxation. Moreover, the transitions between the conformational states cease to obey Poisson statistics. In particular, we show that, at sufficiently low temperatures, correlated forward-backward motion is an important aspect of the conformational relaxation, leading to strongly nonexponential distributions for the waiting times of the dihedrals in the various conformational statesComment: 13 pages, 13 figure

    A Unified Approach to Distance-Two Colouring of Graphs on Surfaces

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    In this paper we introduce the notion of Σ\Sigma-colouring of a graph GG: For given subsets Σ(v)\Sigma(v) of neighbours of vv, for every vV(G)v\in V(G), this is a proper colouring of the vertices of GG such that, in addition, vertices that appear together in some Σ(v)\Sigma(v) receive different colours. This concept generalises the notion of colouring the square of graphs and of cyclic colouring of graphs embedded in a surface. We prove a general result for graphs embeddable in a fixed surface, which implies asymptotic versions of Wegner's and Borodin's Conjecture on the planar version of these two colourings. Using a recent approach of Havet et al., we reduce the problem to edge-colouring of multigraphs, and then use Kahn's result that the list chromatic index is close to the fractional chromatic index. Our results are based on a strong structural lemma for graphs embeddable in a fixed surface, which also implies that the size of a clique in the square of a graph of maximum degree Δ\Delta embeddable in some fixed surface is at most 32Δ\frac32\,\Delta plus a constant.Comment: 36 page

    Schur function averages for the real Ginibre ensemble

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    We derive an explicit simple formula for expectations of all Schur functions in the real Ginibre ensemble. It is a positive integer for all entries of the partition even and zero otherwise. The result can be used to determine the average of any analytic series of elementary symmetric functions by Schur function expansion

    Increase the strength characteristics of polymer films by radiation graft polymerization

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    The possibility of increasing the strength characteristics of polymer films based on polyethylene and polyamide by radiation graft polymerization was investigated. Two methods of graft polymerization (direct method and the method of polymer mixtures cross-linking) on the PMMA films surface were studied. The possibility of increasing the strength and elasticity of polymeric films by radiation modification of polymethyl methacrylate was shown

    Screening Methodology for the Efficient Pairing of Ionic Liquids and Carbonaceous Electrodes Applied to Electric Energy Storage

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    A model is presented that correlates the measured electric capacitance with the energy that comprises the desolvation, dissociation and adsorption energy of an ionic liquid into carbonaceous electrode (represented by single-wall carbon nanotubes). An original methodology is presented that allows for the calculation of the adsorption energy of ions in a host system that does not necessarily compensate the total charge of the adsorbed ions, leaving an overall net charge. To obtain overall negative (favorable) energies, adsorption energies need to overcome the energy cost for desolvation of the ion pair and its dissociation into individual ions. Smaller ions, such as BF4 −, generally show larger dissociation energies than anions such as PF6 − or TFSI−. Adsorption energies gradually increase with decreasing pore size of the CNT and show a maximum when the pore size is slightly greater than the dimensions of the adsorbed ion and the attractive van der Waals forces dominate the interaction. At smaller pore diameters, the adsorption energy sharply declines and becomes repulsive as a result of geometry deformations of the ion. Only for those diameters where the adsorption reaches maximum values is the adsorption energy sufficiently negative to balance the positive dissociation and desolvation energies. We present for each ion (and ionic liquid) what the most adequate electrode pore size should be for maximum capacitance
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