Determination of the dimensions of the heat-affected zone in welding gas pipeline components

Analytical decisions supported by experimental data were used to determine the dependences for calculating the size of the heat-affected zone (HAZ) in multilayer welding of circumferential joints in transmission gas pipelines. Data on the dimensions of this zone are essential for evaluating the possibility of applying cold cutting in the rejection of elements of gas pipelines because of defects in circumferential welded joints or welded joints in transition rings in the vicinity of circumferential welded joints. © 2013 Copyright Taylor and Francis Group, LLC

Synthesis and reactivity of 5-polyfluoroalkyl-5-deazaalloxazines

Reaction of 6-arylamino-1,3-dialkyluracils with anhydrides of polyfluorocarboxylic acids in the presence of pyridine and subsequent cyclization with concentrated H2SO4 gave the corresponding 1,3-dialkyl-5-(polyfluoroalkyl)pyrimido[4,5-b]quinoline-2,4(1H,3H)-diones (5-polyfluoroalkyl-5-deazaalloxazines). The reactivity of these compounds towards nucleophilic reagents, such as sodium cyanoborohydride, acetophenone, nitromethane, potassium cyanide, indole and p-thiocresol, as well as Suzuki and Sonogashira couplings are described. The nucleophilic addition takes place at the 5-position of the 5-deazaalloxazine system and is in many cases irreversible to give 5,10-dihydropyrimido[4,5-b]quinoline-2,4(1H,3H)-dione derivatives in good to excellent yields.© 2013 The Royal Society of Chemistry

Efficient synthesis of novel thieno[3,2-b]-, [2,3-c]- and [3,2-c]pyridones by Sonogashira coupling of bromothiophenes with terminal alkynes and subsequent intramolecular C-N bond-forming reaction

The coupling of bromothiophenes with terminal alkynes using triethylamine or diisopropyl amine under Sonogashira conditions (PdCl2(PPh 3)2, CuI) followed by subsequent addition of amines or ammonium to the intermediate thienyl acetylenes represents a novel access to a wide range of thieno[3,2-b]-, [2,3-c]-, and [3,2-c]pyridones under basic conditions and in excellent yields. © 2013 Elsevier Ltd. All rights reserved

Метод эмболизации маточных артерий в лечении миомы матки

МАТКИ НОВООБРАЗОВАНИЯМИОМАЭМБОЛИЗАЦИЯ ТЕРАПЕВТИЧЕСКАЯАРТЕРИ

Nonlinear Bogolyubov-Valatin transformations and quaternions

In introducing second quantization for fermions, Jordan and Wigner (1927/1928) observed that the algebra of a single pair of fermion creation and annihilation operators in quantum mechanics is closely related to the algebra of quaternions H. For the first time, here we exploit this fact to study nonlinear Bogolyubov-Valatin transformations (canonical transformations for fermions) for a single fermionic mode. By means of these transformations, a class of fermionic Hamiltonians in an external field is related to the standard Fermi oscillator.Comment: 6 pages REVTEX (v3: two paragraphs appended, minor stylistic changes, eq. (39) corrected, references [10]-[14], [36], [37], [41], [67]-[69] added; v4: few extensions, references [62], [63] added, final version to be published in J. Phys. A: Math. Gen.