Ancient xenocrystic zircon in young volcanic rocks of the southern Lesser Antilles island arc

The Lesser Antilles arc is one of the best global examples in which to examine the effects of the involvement of subducted sediment and crustal assimilation in the generation of arc crust. Most of the zircon recovered in our study of igneous and volcaniclastic rocks from Grenada and Carriacou (part of the Grenadines chain) is younger than 2 Ma. Within some late Paleogene to Neogene (~ 34–0.2 Ma) lavas and volcaniclastic sediments however, there are Paleozoic to Paleoarchean (~ 250–3469 Ma) xenocrysts, and Late Jurassic to Precambrian zircon (~ 158–2667 Ma) are found in beach and river sands. The trace element characteristics of zircon clearly differentiate between different types of magmas generated in the southern Lesser Antilles through time. The zircon population from the younger arc (Miocene, ~ 22–19 Ma, to Present) has minor negative Eu anomalies, well-defined positive Ce anomalies, and a marked enrichment in heavy rare earth elements (HREE), consistent with crystallization from very oxidized magmas in which Eu2 + was in low abundance. In contrast, zircon from the older arc (Eocene to mid-Oligocene, ~ 30–28 Ma) has two different REE patterns: 1) slight enrichment in the light (L)REE, small to absent Ce anomalies, and negative Eu anomalies and 2) enriched High (H)REE, positive Ce anomalies and negative Eu anomalies (a similar pattern is observed in the xenocrystic zircon population). The combination of positive Ce and negative Eu anomalies in the zircon population of the older arc indicates crystallization from magmas that were variably, but considerably less oxidized than those of the younger arc. All the igneous zircon has positive εHf(t), reflecting derivation from a predominantly juvenile mantle source. However, the εHf(t) values vary significantly within samples, reflecting considerable Hf isotopic heterogeneity in the source. The presence of xenocrystic zircon in the southern Lesser Antilles is evidence for the assimilation of intra-arc crustal sediments and/or the recycling and incorporation of sediments into the magma sources in the mantle wedge. Most likely however, primitive magmas stalling and fractionating during their ascent through the Antilles crust entrained ancient zircon. This is evidence by the geochemistry of the study samples, which is inconsistent with any involvement of partially melted subducted sediment. Paleogeographic reconstructions show that the old zircon could derive from distant regions such as the Eastern Andean Cordillera of Colombia, the Merida Andes, and the northern Venezuela coastal ranges, transported for example by the Proto-Maracaibo River precursor of the Orinoco River.This study was supported by Deutsche Forschungsgemeinschaft (DFG) grants KR590/85-1 to AK and RO4174/2-1 to YRA, and Spanish MINECO grants CGL2015-65824 and CGL2012-36263 and University of Granada research program (CIC) to AGC and CLC. This research also received support from the SYNTHESYS Project (http://www.synthesys.info/) which is financed by the European Community Research Infrastructure Action under the FP7 “Capacities” Program, the Intra-University Research Support Program of Mainz University (Universitätsinterne Forschungsförderung (FoFö)

SHRIMP zircon dating and LA-ICPMS Hf analysis of early Precambrian rocks from drill holes into the basement beneath the Central Hebei Basin, North China Craton

The Central Hebei Basin (CHB) is one of the largest sedimentary basins in the North China Craton, extending in a northeast–southwest direction with an area of >350 km2. We carried out SHRIMP zircon dating, Hf-in-zircon isotopic analysis and a whole-rock geochemical study on igneous and metasedimentary rocks recovered from drill holes that penetrated into the basement of the CHB. Two samples of gneissic granodiorite (XG1-1) and gneissic quartz diorite (J48-1) have magmatic ages of 2500 and 2496 Ma, respectively. Their zircons also record metamorphic ages of 2.41–2.51 and ∼2.5 Ga, respectively. Compared with the gneissic granodiorite, the gneissic quartz diorite has higher ΣREE contents and lower Eu/Eu* and (La/Yb)n values. Two metasedimentary samples (MG1, H5) mainly contain ∼2.5 Ga detrital zircons as well as late Paleoproterozoic metamorphic grains. The zircons of different origins have εHf (2.5 Ga) values and Hf crustal model ages ranging from 0 to 5 and 2.7 to 2.9 Ga, respectively. Therefore, ∼2.5 Ga magmatic and Paleoproterozoic metasedimentary rocks and late Neoarchean to early Paleoproterozoic and late Paleoproterozoic tectono-thermal events have been identified in the basement beneath the CHB. Based on regional comparisons, we conclude that the early Precambrian basement beneath the CHB is part of the North China Craton

Source composition, fractional crystallization and magma mixing processes in the 3.48-3.43 Ga Tsawela tonalite suite (Ancient Gneiss Complex, Swaziland) - Implications for Palaeoarchaean geodynamics

The ca. 3480-3430 Ma Tsawela Gneiss (TG) is a well-preserved coarse-grained diorite to tonalite suite within the Ancient Gneiss Complex of Swaziland, eastern Kaapvaal craton. These gneisses are texturally and compositionally distinct from the hosting oldest components of the ca. 3200-3660 Ma TTG-type Ngwane Gneisses (NG). Major and trace elements, in combination with whole-rock hafnium-neodymium isotopic data, were analyzed in the TG and in three samples of ca. 3450 Ma grey NG to constrain sources and magmatic processes. High-field-strength element data (HFSE) were combined with U-Pb SHRIMP II ages and Hf-in-zircon data for key samples to constrain their ages and petrogenesis. In contrast to the widespread view that Archaean crust is mainly composed of TTG igneous suites that formed from juvenile sources, the geochemical and isotopic compositions of the TG indicate that these rocks represent a calc-alkaline plutonic suite which possibly formed by magma mixing processes involving juvenile, mantle-derived tholeiitic melts as well as partial melts of the older Ngwane gneiss. Alternatively, the TG may represent a magmatic suite that formed by fractional crystallization of a hydrous intermediate magma. These results contrast with field evidence of a relatively uniform and homogeneous composition. Our geochronological and isotopic data show that the TG intruded the NG during a time span of at least 50 Ma without any significant compositional change of the source. The predominant influence of fractional crystallization of a tholeiitic mafic magma, as well as assimilation-fractional-crystallization processes (AFC) can be excluded for the TG from major and trace element modelling. The magma processes proposed here suggest efficient mixing of approximately equal amounts of TG magmas with those derived from the NG basement and is supported by the largely homogeneous Hf-Nd isotopic compositions of the whole-rock samples. We propose that melting and mixing occurred in the lower crust that mainly consisted of >3.50 Ga NG and was possibly triggered by plume-related underplated and intraplated tholeiitic magmas in sills and/or laccoliths. This model is supported by geochemical evidence for a mafic end member lacking a negative Nb anomaly and implying that subduction processes were not involved in the formation of the TG. (C) 2016 Elsevier B.V. All rights reserved