Mapping QTLs for mineral accumulation and shoot dry biomass under different Zn nutritional conditions in Chinese cabbage ( Brassica rapa L. ssp. pekinensis )

Abstract Chinese cabbage (Brassica rapa L. ssp. pekinensis) is one of the most important vegetables in China. Genetic dissection of leaf mineral accumulation and tolerance to Zn stress is important for the improvement of the nutritional quality of Chinese cabbage by breeding. A mapping population with 183 doubled haploid (DH) lines was used to study the genetics of mineral accumulation and the growth response to Zn. The genetic map was constructed based on 203 AFLPs, 58 SSRs, 22 SRAPs and four ESTPs. The concentration of 11 minerals was determined in leaves for 142 DH lines grown in an open field. In addition shoot dry biomass (SDB) under normal, deficient and excessive Zn nutritional conditions were investigated in hydroponics experiments. Ten QTLs, each explaining 11.1¿17.1% of the Na, Mg, P, Al, Fe, Mn, Zn and Sr concentration variance, were identified by multiple-QTL model (MQM) mapping. One common QTL was found affecting SDB under normal, deficient and excessive Zn nutritional conditions. An additional QTL was detected for SDB under Zn excess stress only. These results offer insights into the genetic basis of leaf mineral accumulation and plant growth under Zn stress conditions in Chinese cabbag

Variable metric proximal stochastic variance reduced gradient methods for nonconvex nonsmooth optimization

We study the problem of minimizing the sum of two functions. The first function is the average of a large number of nonconvex component functions and the second function is a convex (possibly nonsmooth) function that admits a simple proximal mapping. With a diagonal Barzilai-Borwein stepsize for updating the metric, we propose a variable metric proximal stochastic variance reduced gradient method in the mini-batch setting, named VM-SVRG. It is proved that VM-SVRG converges sublinearly to a stationary point in expectation. We further suggest a variant of VM-SVRG to achieve linear convergence rate in expectation for nonconvex problems satisfying the proximal Polyak-Lojasiewicz inequality. The complexity of VM-SVRG is lower than that of the proximal gradient method and proximal stochastic gradient method, and is the same as the proximal stochastic variance reduced gradient method. Numerical experiments are conducted on standard data sets. Comparisons with other advanced proximal stochastic gradient methods show the efficiency of the proposed method

Bifunctional highly fluorescent hollow porous microspheres made of BaMoO4:Pr3+ nanocrystals via a template-free synthesis

We report a bifunctional hollow porous microsphere composed of single-component BaMoO4:Pr3+ nanocrystals by a facile template-free synthesis. All the as-synthesized hollow microspheres are well-dispersed with a diameter of 2-4 μm and the BaMoO4:Pr 3+ nanocrystals measure 30-60 nm in diameter. It is observed that there are a large amount of pores with an average diameter is 17.5 nm in the shell of these BaMoO4:Pr3+ hollow microspheres, thereby exhibiting a great promise for drug delivery. Meanwhile, the strong, narrow-bandwidth red emission centered at 643 nm from these nanostructures can be efficiently excited from 430 nm to 500 nm. The combination of excellent luminescent properties and a hollow porous nanostructure suggest a great promise in the application of these nanostructures in lighting and displays, and in biomedicine such as targeted drug delivery, integrated imaging, diagnosis, and therapeutics. In addition, the template-free solution synthesis can be applied to the design and fabrication of other functional architectures. © 2011 The Royal Society of Chemistry

Comparison of genetic diversity and growth traits among Fangzheng silver crucian carp (Carassius auratus gibelio) gynogenetic clones

The silver crucian carp (Carassius auratus gibelio), a gynogenetic teleost, is a promising model for the study of evolutionary genetics in vertebrates. We identified ten gynogenetic clones (FZ-I~FZ-X) from triploid silver crucian carp, collected from Fangzheng County in Heilongjiang Province, China, using microsatellite markers. The genetic diversity of these gynogenetic clones was analyzed using 52 microsatellite markers. A total of 413 alleles were detected and the length of fragments ranged from 96 to 340 bp. The number of alleles per locus varied from 2~19 (mean=7.9423). The observed heterozygosity at polymorphic loci ranged from 0.10~1.00 (mean=0.80). The average allele count per gynogenetic clone ranged from 1.9423~2.1923. The ratio of the polymorphic locus was from 71.15% (VII) to 84.61% (IX) per clone. The number of genotypes ranged from 2~10 per locus. Ten genotypes were observed by analyzing each of 14 microsatellites. As a result, each gynogenetic clone could be accurately identified. In addition, the growth traits, including body weight, length, and height, among five gynogenetic clones were compared. There was a significant difference among gynogenetic clones. Clone FZ-V exhibited the best growth traits, with the largest body weight (53.17±5.24 g), length (11.38±0.37 cm) and height (4.69±0.18 cm). Our results provide basic data for the identification of silver crucian carp gynogenetic clones and can be used as a guide genetic breeding programs

Efficient synthesis of plate-like crystalline hydrated tungsten trioxide thin films with highly improved electrochromic performance

Plate-like hydrated tungsten trioxide (3WO3·H 2O) films were grown on a fluorine doped tin oxide (FTO) coated transparent conductive substrate via an efficient, facile and template-free hydrothermal method. The film exhibited a fast coloration/bleaching response (tc90% = 4.3 s and tb90% = 1.4 s) and a high coloration efficiency (112.7 cm2 C-1), which were probably due to a large surface area

Superior warm-White light-emitting diodes integrated with quantum dot nanophosphors for high luminous efficacy and color rendering

Quantum dot nanophoshor hybridized warm-white LEDs are reported to exhibit high photometric performance of luminous efficacy exceeding 350 lm/Wopt and color rendering index close to 90 at correlated color temperatures <3000 K. ©2011 Optical Society of America

High-quality InP/ZnS nanocrystals with high photometric performance and their application to white quantum dot light-emitting diodes

Full visible range covering InP/ZnS core-shell nanocrystals with high photometric performance have been prepared. Making use of these nanocrystals, we demonstrate a white quantum dot LED with a high color rendering index of 91. © 2012 IEEE

Top-illuminated dye-sensitized solar cells with a room-temperature- processed ZnO photoanode on metal substrates and a Pt-coated Ga-doped ZnO counter electrode

We report on top-illuminated, fluorine tin oxide/indium tin oxide-free (FTO/ITO-free), dye-sensitized solar cells (DSCs) using room-temperature- processed ZnO layers on metal substrates as the working electrodes and Pt-coated Ga-doped ZnO layers (GZO) as the counter electrodes. These top-illuminated DSCs with GZO render comparable efficiency to those employing commercial FTO counter electrodes. Despite a lower current density, the top-illuminated DSCs result in a higher fill factor than conventional DSCs due to a low ohmic loss at the electrode/semiconductor interface. The effect of metal substrate on the performance of the resulting top-illuminated DSCs is also studied by employing various metals with different work functions. Ti is shown to be a suitable metal to be used as the working electrode in the top-illuminated device architecture owing to its low ohmic loss at the electrode/semiconductor interface, minimum catalytic activity on redox reactions and high resistance to corrosion by liquid electrolytes. © 2011 IOP Publishing Ltd

Singlet and Triplet Exciton Harvesting in the Thin Films of Colloidal Quantum Dots Interfacing Phosphorescent Small Organic Molecules

Efficient nonradiative energy transfer is reported in an inorganic/organic thin film that consists of a CdSe/ZnS core/shell colloidal quantum dot (QD) layer interfaced with a phosphorescent small organic molecule (FIrpic) codoped fluorescent host (TCTA) layer. The nonradiative energy transfer in these thin films is revealed to have a cascaded energy transfer nature: first from the fluorescent host TCTA to phosphorescent FIrpic and then to QDs. The nonradiative energy transfer in these films enables very efficient singlet and triplet state harvesting by the QDs with a concomitant fluorescence enhancement factor up to 2.5-fold, while overall nonradiative energy transfer efficiency is as high as 95%. The experimental results are successfully supported by the theoretical energy transfer model developed here, which considers exciton diffusion assisted Förster-type near-field dipole-dipole coupling within the hybrid films. © 2014 American Chemical Society

Nanocrystal LEDs with enhanced external quantum efficiency enabled by the use of phosphorescent molecules

We report efficiency enhancement in quantum dot (QD) based LEDs with the aid of excitonic energy transfer from co-doped TCTA:Ir(ppy)3 layer to CdSe/ZnS QDs while providing spectrally pure emission. © 2013 IEEE