6,210 research outputs found
Caracterització morfològica i limnològica del Clot d'Espolla i les surgències del pla d'Usall (pla de l'Estany)
Characterization of reciprocity gaps from interference tests in fractured media through a dual porosity model
We analyze drawdown reciprocity gaps emerging in interference tests performed in a confined fissured karstic formation. Modeling the system as a dual porosity continuum allows characterizing the dynamics of the relative contribution of the connected fractures and the rock matrix to the total flow rate extracted at the pumping wells. Observed lack of reciprocity of drawdowns can then be linked to the occurrence of processes that are not accounted for in the classical flow models based on a single-continuum representation of the system through flow equations grounded on Darcy's law only. We show that interpreting the system as a dual porosity continuum can cause drawdown reciprocity gaps to emerge as a consequence of local effects associated with an identifiable contribution of the matrix to the total fluid extracted at the well location during pumping. These theoretical results are then employed to identify the contribution to the flow being supplied to the pumping well by the low conductivity matrix constituting the host rock formation, in contrast to that provided by the fractures. An application to data from two interference tests performed at the Hydrogeological Experimental Site (HES) in Poitiers, France, illustrates the approach. We show that, whenever the matrix is assumed to provide a contribution to the total flow rate extracted, nonreciprocity is expected, the latter being linked to the occurrence of a differential drawdown between fracture and matrix at the pumping well. This difference decreases with time in the example presented, displaying a power law late time behavior, with nonreciprocity effects persisting up to remarkably long times
Cortinarius mahiquesii, a new subhypogeous species from Catalonia (Iberian Peninsula)
We describe and comment on a new species of Cortinarius (Basidiomycota), C. mahiquesii, collected in a pure Cistus monspeliensis scrub community in Catalonia (NE of the Iberian Peninsula). Drawings of microscopic characters, scanning microphotographs of the basidiospores, and colour pictures of the basidiomes in their natural habitat are provided. A molecular analysis was carried out to characterize the new species using ITS sequences
Radical Cyclization of Trichloroacetamides: Synthesis of Lactams
Trichloroacetamides can act as radical precursors to synthesize nitrogen-containing heterocycles in a variety of processes, mainly involving atom transfer radical cyclizations (ATRC), mediated by Cu(I) or Ru(II) catalysts, and the hydride reductive method, employing either Bu3SnH or (Me3Si)3SiH, or recently NaBH3CN. Additionally, amine-mediated single-electron transfer cyclizations, as well as radical processes promoted by Ni, Fe, Mn, Ti, and Ag, have been developed
Computability of simple games: A characterization and application to the core
The class of algorithmically computable simple games (i) includes the class
of games that have finite carriers and (ii) is included in the class of games
that have finite winning coalitions. This paper characterizes computable games,
strengthens the earlier result that computable games violate anonymity, and
gives examples showing that the above inclusions are strict. It also extends
Nakamura's theorem about the nonemptyness of the core and shows that computable
games have a finite Nakamura number, implying that the number of alternatives
that the players can deal with rationally is restricted.Comment: 35 pages; To appear in Journal of Mathematical Economics; Appendix
added, Propositions, Remarks, etc. are renumbere
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