566 research outputs found
Bonding-Compatible Corrosion Inhibitor for Rinsing Metals
A corrosion-inhibiting mixture of compounds has been developed for addition to the water used to rinse metal parts that have been cleaned with aqueous solutions in preparation for adhesive bonding of the metals to rubber and rubber-like materials. Prior to the development of this corrosion inhibitor, the parts (made, variously, of D6AC steel and 7075-T73 aluminum) were rinsed by deionized water, which caused corrosion in some places on the steel parts especially in such occluded places as sealing surfaces and threaded blind holes. An integral part of the particular cleaning process is the deposition of a thin layer of silicates and silane primers that increase the strength of the adhesive bond. The corrosion inhibitor is formulated, not only to inhibit corrosion of both D6AC steel and 7075- T73 aluminum, but also to either increase or at least not reduce the strength of the adhesive bond to be formed subsequently. The corrosion inhibitor is a mixture of sodium silicate and sodium tetraborate. The sodium silicate functions as both a corrosion inhibitor and a bond-strength promoter in association with the silane primers. The sodium tetraborate buffers the rinse solution at the optimum pH and functions as a secondary corrosion inhibitor for the steel. For a given application, the concentrations of sodium silicate and sodium tetraborate must be chosen in a compromise among the needs to inhibit corrosion of steel, inhibit corrosion of aluminum, and minimize cosmetic staining of both steel and aluminum. Concentrations of sodium silicate in excess of 150 parts of silicon per million parts of solution (ppm Si) have been determined to enhance inhibition of corrosion; unfortunately, because of the alkalinity of sodium silicate, even a small concentration can raise the pH of the rinse solution to such a level that aluminum becomes corroded despite the inhibiting effect. The pH of a solution that contains a high concentration of sodium silicate can be decreased by adding sodium tetraborate. On the other hand, the addition of sodium tetraborate increases the concentration of dissolved solids to such a high level that cosmetic staining becomes an issue
MF2952
Caleb E. Wurth et al., Defining Sieving Methods Used to Determine and Express Fineness of Feed Materials, Kansas State University, October 2010
Seeded x-ray free-electron laser generating radiation with laser statistical properties
The invention of optical lasers led to a revolution in the field of optics
and even to the creation of completely new fields of research such as quantum
optics. The reason was their unique statistical and coherence properties. The
newly emerging, short-wavelength free-electron lasers (FELs) are sources of
very bright coherent extreme-ultraviolet (XUV) and x-ray radiation with pulse
durations on the order of femtoseconds, and are presently considered to be
laser sources at these energies. Most existing FELs are highly spatially
coherent but in spite of their name, they behave statistically as chaotic
sources. Here, we demonstrate experimentally, by combining Hanbury Brown and
Twiss (HBT) interferometry with spectral measurements that the seeded XUV FERMI
FEL-2 source does indeed behave statistically as a laser. The first steps have
been taken towards exploiting the first-order coherence of FELs, and the
present work opens the way to quantum optics experiments that strongly rely on
high-order statistical properties of the radiation.Comment: 24 pages, 10 figures, 37 reference
Interplay of Mott Transition and Ferromagnetism in the Orbitally Degenerate Hubbard Model
A slave boson representation for the degenerate Hubbard model is introduced.
The location of the metal to insulator transition that occurs at commensurate
densities is shown to depend weakly on the band degeneracy M. The relative
weights of the Hubbard sub-bands depend strongly on M, as well as the magnetic
properties. It is also shown that a sizable Hund's rule coupling is required in
order to have a ferromagnetic instability appearing. The metal to insulator
transition driven by an increase in temperature is a strong function of it.Comment: 5 pages, revtex, 5 postscript figures, submitted to Phys. Rev.
The most pathogenic transthyretin variant, L55P, forms amyloid fibrils under acidic conditions and protofilaments under physiological conditions
The L55P transthyretin (TTR) familial amyloid polyneuropathy-associated variant is distinct from the other TTR variants studied to date and the wild-type protein in that the L55P tetramer can dissociate to the monomeric amyloidogenic intermediate and form fibril precursors under physiological conditions (pH 7.0, 37 degrees C). The activation barrier associated with L55P-TTR tetramer dissociation is lower than the barrier for wild-type transthyretin dissociation, which does not form fibrils under physiological conditions. The L55P-TTR tetramer is also very sensitive to acidic conditions, readily dissociating to form the monomeric amyloidogenic intermediate between pH 5.5-5.0 where the wild-type TTR adopts a nonamyloidogenic tetrameric structure. The formation of the L55P monomeric amyloidogenic intermediate involves subtle tertiary structural changes within the beta-sheet rich subunit as discerned from Trp fluorescence, circular dichroism analysis, and ANS binding studies. The assembly of the L55P-TTR amyloidogenic intermediate at physiological pH (pH 7.5) affords protofilaments that elongate with time. TEM studies suggest that the entropic barrier associated with filament assembly (amyloid fibril formation) is high in vitro, amyloid being defined by the laterally assembled four filament structure observed by Blake upon isolation of "fibrils" from the eye of a FAP patient. The L55P-TTR protofilaments formed in vitro bind Congo red and thioflavin T (albeit more weakly than the fibrils produced at acidic pH), suggesting that the structure observed probably represents an amyloid precursor. The structural continuum from misfolded monomer through protofilaments, filaments, and ultimately fibrils must be considered as a possible source of pathology associated with these diseases
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Towards time resolved core level photoelectron spectroscopy with femtosecond x-ray free-electron lasers
We have performed core level photoelectron spectroscopy on a W(110) single crystal with femtosecond XUV pulses from the free-electron laser at Hamburg (FLASH). We demonstrate experimentally and through theoretical modelling that for a suitable range of photon fluences per pulse, time-resolved photoemission experiments on solid surfaces are possible. Using FLASH pulses in combination with a synchronized optical laser, we have performed femtosecond time-resolved core-level photoelectron spectroscopy and observed sideband formation on the W 4f lines indicating a cross correlation between femtosecond optical and XUV pulses. © IOP Publishing Ltd and Deutsche Physikalische Gesellschaft
Exact single spin flip for the Hubbard model in
It is shown that the dynamics of a single -electron interacting
with a band of -electrons can be calculated exactly in the limit of
infinite dimension. The corresponding Green function is determined as a
continued fraction. It is used to investigate the stability of saturated
ferromagnetism and the nature of the ground state for two generic non-bipartite
infinite dimensional lattices. Non Fermi liquid behavior is found. For certain
dopings the -electron is bound to the -holes.Comment: 4 pages, 3 figures included with psfig, Revtex; Phys. Rev. Lett. in
press; some amendments made to clarify the calculation of the self-energy,
the extrapolation of the continued fraction, and the statements on
Fermi-liquid theor
Lattice dependence of saturated ferromagnetism in the Hubbard model
We investigate the instability of the saturated ferromagnetic ground state
(Nagaoka state) in the Hubbard model on various lattices in dimensions d=2 and
d=3. A variational resolvent approach is developed for the Nagaoka instability
both for U = infinity and for U < infinity which can easily be evaluated in the
thermodynamic limit on all common lattices. Our results significantly improve
former variational bounds for a possible Nagaoka regime in the ground state
phase diagram of the Hubbard model. We show that a pronounced particle-hole
asymmetry in the density of states and a diverging density of states at the
lower band edge are the most important features in order to stabilize Nagaoka
ferromagnetism, particularly in the low density limit.Comment: Revtex, 18 pages with 18 figures, 7 pages appendices, section on bcc
lattice adde
Three-body correlations in the Nagaoka state on the square lattice
A three-body scattering theory previously proposed by one of the present
authors is developed to be applied to the saturated ferromagnetic state in the
two-dimensional Hubbard model. The single-particle Green's function is
calculated by taking account of the multiple scattering between two electrons
and one hole. Several limiting cases are discussed and the relation to the
variational principle is examined. The importance of the three-body correlation
is demonstrated in comparison with the results of the ladder approximation. A
possible phase boundary for the Nagaoka ground state is presented for the
square lattice, which improves the previous variational results.Comment: 13 pages, 8 Postscript figures, submitted to Phys.Rev.
Ferromagnetism in the large-U Hubbard model
We study the Hubbard model on a hypercubic lattice with regard to the
possibility of itinerant ferromagnetism. The Dynamical Mean Field theory is
used to map the lattice model on an effective local problem, which is treated
with help of the Non Crossing Approximation. By investigating spin dependent
one-particle Green's functions and the magnetic susceptibility, a region with
nonvanishing ferromagnetic polarization is found in the limit . The
-T-phase diagram as well as thermodynamic quantities are discussed. The
dependence of the Curie temperature on the Coulomb interaction and the
competition between ferromagnetism and antiferromagnetism are studied in the
large limit of the Hubbard model.Comment: 4 pages, 5 figures, accepted for publication in Physical Review B,
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