Molecular Distribution, 13C-Isotope, and Enantiomeric Compositions of Carbonaceous Chondrite Monocarboxylic Acids

The watersoluble organic compounds in carbonaceous chondrite meteorites constitute a record of the synthetic reactions occurring at the birth of the solar system and those taking place during parent body alteration and may have been important for the later origins and development of life on Earth. In this present work, we have developed a novel methodology for the simultaneous analysis of the molecular distribution, compoundspecific 13C, and enantiomeric compositions of aliphatic monocarboxylic acids (MCA) extracted from the hotwater extracts of 16 carbonaceous chondrites from CM, CR, CO, CV, and CK groups. We observed high concentrations of meteoritic MCAs, with total carbon weight percentages which in some cases approached those of carbonates and insoluble organic matter. Moreover, we found that the concentration of MCAs in CR chondrites is higher than in the other meteorite groups, with acetic acid exhibiting the highest concentration in all samples. The abundance of MCAs decreased with increasing molecular weight and with increasing aqueous and/or thermal alteration experienced by the meteorite sample. The 13C isotopic values of MCAs ranged from 52 to +27, and aside from an inverse relationship between 13C value and carbon straightchain length for C3C6 MCAs in Murchison, the 13Cisotopic values did not correlate with the number of carbon atoms per molecule. We also observed racemic compositions of 2methylbutanoic acid in CM and CR chondrites. We used this novel analytical protocol and collective data to shed new light on the prebiotic origins of chondritic MCAs

Laser-like X-ray Sources Based on Optical Reflection from Relativistic Electron Mirror

A novel scheme is proposed to generate uniform relativistic electron layers for coherent Thomson backscattering. A few-cycle laser pulse is used to produce the electron layer from an ultra-thin solid foil. The key element of the new scheme is an additional foil that reflects the drive laser pulse, but lets the electrons pass almost unperturbed. It is shown by analytic theory and by 2D-PIC simulation that the electrons, after interacting with both drive and reflected laser pulse, form a very uniform flyer freely cruising with high relativistic gamma-factor exactly in drive laser direction (no transverse momentum). It backscatters probe light with a full Doppler shift factor of 4*gamma^2. The reflectivity and its decay due to layer expansion is discussed.Comment: 5 pages, 3 figures, submitted, invited talk on the workshop of Frontiers in Intense Laser-Matter Interaction Theory, MPQ, March 1-3, 2010

On the density-potential mapping in time-dependent density functional theory

The key questions of uniqueness and existence in time-dependent density functional theory are usually formulated only for potentials and densities that are analytic in time. Simple examples, standard in quantum mechanics, lead however to non-analyticities. We reformulate these questions in terms of a non-linear Schr\"odinger equation with a potential that depends non-locally on the wavefunction.Comment: 8 pages, 2 figure

Cultural respect encompassing simulation training: being heard about health through broadband

Background. Cultural Respect Encompassing Simulation Training (CREST) is a learning program that uses simulation to provide health professional students and practitioners with strategies to communicate sensitively with culturally and linguistically diverse (CALD) patients. It consists of training modules with a cultural competency evaluation framework and CALD simulated patients to interact with trainees in immersive simulation scenarios. The aim of this study was to test the feasibility of expanding the delivery of CREST to rural Australia using live video streaming; and to investigate the fidelity of cultural sensitivity – defined within the process of cultural competency which includes awareness, knowledge, skills, encounters and desire – of the streamed simulations. Design and Methods. In this mixed-methods evaluative study, health professional trainees were recruited at three rural academic campuses and one rural hospital to pilot CREST sessions via live video streaming and simulation from the city campus in 2014. Cultural competency, teaching and learning evaluations were conducted. Results. Forty-five participants rated 26 reliable items before and after each session and reported statistically significant improvement in 4 of 5 cultural competency domains, particularly in cultural skills (P<0.05). Qualitative data indicated an overall acknowledgement amongst participants of the importance of communication training and the quality of the simulation training provided remotely by CREST. Conclusions. Cultural sensitivity education using live video-streaming and simulation can contribute to health professionals’ learning and is effective in improving cultural competency. CREST has the potential to be embedded within health professional curricula across Australian universities to address issues of health inequalities arising from a lack of cultural sensitivity training

Using formal methods to support testing

Formal methods and testing are two important approaches that assist in the development of high quality software. While traditionally these approaches have been seen as rivals, in recent years a new consensus has developed in which they are seen as complementary. This article reviews the state of the art regarding ways in which the presence of a formal specification can be used to assist testing

Non-linear soil behaviour on high speed rail lines

This paper gives new insights into non-linear subgrade behaviour on high speed railway track dynamics. First, a novel semi-analytical model is developed which allows for soil stiffness and damping to dynamically change as a function of strain. The model uses analytical expressions for the railroad track, coupled to a thin-layer element formulation for the ground. Material non-linearity is accounted for using a ‘linear equivalent’ approach which iteratively updates the soil material properties. It is validated using published datasets and in-situ field data. Four case studies are used to investigate non-linear behaviour, each with contrasting subgrade characteristics. Considering an 18 tonne axle load, the critical velocity is significantly lower than the linear case, and rail deflections are up to 30% higher. Furthermore, at speeds close-to, but below the non-linear critical velocity, dynamic amplification is highly sensitive to small increases in train speed. These findings are dependent upon soil material properties, and are important for railway track-earthwork designers because often 70% of the linear critical velocity is used as a design limit. This work shows that designs close to this limit may be still at risk of high dynamic effects, particularly if line speed is increased in the future