Improved Oxygen Sources for Breathing Apparatus

Research is described which is directed toward the preparation of chemical oxygen sources which exhibited improved O2 storage and reaction characteristics when compared to potassium superoxide (KO2). The initial focus of the research was the preparation of calcium superoxide (Ca(O2)2) by the disproportionation of calcium peroxide diperoxyhydrate. the Ca(O2)2 was characterized by chemical, thermal, and x ray analyses. Several methods for scaling up the Ca(O2)2 syntheis process were studied. The reactivity of Ca(O2)2 toward humidified carbon dioxide (CO2) was evaluated and was compared to that of KO2 under flow test conditions approximating those existing in portable breathing apparatus. The reactivities of mixtures of KO2 and Ca(O2)2 or lithium peroxide towards humidified CO2 were also studied. Finally, an analysis of two commercial, KO2-based, self contained self rescuers was conducted to determine the potential weight and volume savings which would be possible if Ca(O2)2 or a mixture of KO2 and Ca(O2)2 were used as a replacement for KO2

Thermomagnetic torques in polyatomic gases

The application of the Scott effect to the dynamics of galactic and stellar rotation is investigated. Efforts were also made to improve the sensitivity and stability of torque measurements and understand the microscopic mechanism that causes the Scott effect

The role of courage in the development and practice of coaches

This study seeks to understand the role that courage plays in the development and practice of coaches. Courage is mentioned frequently in the coaching literature, but this research is the first study to investigate its significance. Within the precepts of constructivist grounded theory, which is appropriate for the investigation of under-represented topics, the perspectives of 12 coaches of varying levels of experience revealed that courage is required throughout a coaching career. It was found that courage enables coaches to deliver their best work and is integral to an ongoing cycle of increasing self-awareness and professional development

Structured Prediction of Sequences and Trees using Infinite Contexts

Linguistic structures exhibit a rich array of global phenomena, however commonly used Markov models are unable to adequately describe these phenomena due to their strong locality assumptions. We propose a novel hierarchical model for structured prediction over sequences and trees which exploits global context by conditioning each generation decision on an unbounded context of prior decisions. This builds on the success of Markov models but without imposing a fixed bound in order to better represent global phenomena. To facilitate learning of this large and unbounded model, we use a hierarchical Pitman-Yor process prior which provides a recursive form of smoothing. We propose prediction algorithms based on A* and Markov Chain Monte Carlo sampling. Empirical results demonstrate the potential of our model compared to baseline finite-context Markov models on part-of-speech tagging and syntactic parsing

Use of glow discharge in fluidized beds

Static charges and agglomerization of particles in a fluidized bed systems are minimized by maintaining in at least part of the bed a radio frequency glow discharge. This approach is eminently suitable for processes in which the conventional charge removing agents, i.e., moisture or conductive particle coatings, cannot be used. The technique is applied here to the disproportionation of calcium peroxide diperoxyhydrate to yield calcium superoxide, an exceptionally water and heat sensitive reaction

Quantifying frequency of use of methods of body mass loss in competing UK powerlifters

Previous research in Powerlifting (PL) has qualitatively investigated rapid weight-loss (RWL) in PL athletes and body image, however limited research exists in quantifying such methods adopted in PL. This study aimed to assess the frequency of RWL methods are adopted by male and female PL athletes in the United Kingdom (UK) during competition preparation. A total of n = 37 (n = 19 female, n = 18 male) competitive powerlifters completed an anonymous online questionnaire assessing RWL methods. A Chi-square cross tabulation was utilised to identify any significant differences between independent and dependent variables. Multiple regression analyses were then conducted to assess the contribution of biological sex and PL category on RWL methods. Commonly reported methods of weight loss were gradual dieting (49%), fluid restriction (46%), and water loading (51%). Differences between PL category (Junior, Open, Masters One) and adopting RWL were observed (X2 =4.220, p<0.05). PL category was a predictor of undertaking RWL (R2adj = 0.160, F(2, 34) = 4.429, p ≤ 0.05), whilst biological sex was a predictor of timeframe of undertaking RWL (R2adj = 0.123, F(2, 34) = 3.534, p ≤ 0.05). RWL strategies are adopted by PL athletes in order to make weight for competition. Despite known effects of RWL on strength performance, limited research currently exists on these strategies specifically within PL, therefore this may be a consideration for future research. Practitioners working with PL athletes may wish to consider appropriate nutrition and weight loss strategies in preparation for PL competitions

Process for the preparation of calcium superoxide

Calcium superoxide is prepared in high yields by spreading a quantity of calcium peroxide diperoxyhydrate on the surface of a container, positioning said container in a vacuum chamber on a support structure through which a coolant fluid can be circulated, partially evacuating said vacuum chamber, allowing the temperature of the diperoxyhydrate to reach the range of about 0 to about 40 C; maintaining the temperature selected for a period of time sufficient to complete the disproproriation of the diperoxyhydrate to calcium superoxide, calcium hydroxide, oxygen, and water; constantly and systematically removing the water as it is formed by sweeping the reacting material with a current of dry inert gas and/or by condensation of said water on a cold surface; backfilling the chamber with a dry inert gas; and finally, recovering the calcium superoxide produced

Stochastic models which separate fractal dimension and Hurst effect

Fractal behavior and long-range dependence have been observed in an astonishing number of physical systems. Either phenomenon has been modeled by self-similar random functions, thereby implying a linear relationship between fractal dimension, a measure of roughness, and Hurst coefficient, a measure of long-memory dependence. This letter introduces simple stochastic models which allow for any combination of fractal dimension and Hurst exponent. We synthesize images from these models, with arbitrary fractal properties and power-law correlations, and propose a test for self-similarity.Comment: 8 pages, 2 figure

How the Cervical Microbiota Contributes to Cervical Cancer Risk in Sub-Saharan Africa

Despite ongoing efforts, sub-Saharan Africa faces a higher cervical cancer burden than anywhere else in the world. Besides HPV infection, definitive factors of cervical cancer are still unclear. Particular states of the cervicovaginal microbiota and viral infections are associated with increased cervical cancer risk. Notably, HIV infection, which is prevalent in sub-Saharan Africa, greatly increases risk of cervicovaginal dysbiosis and cervical cancer. To better understand and address cervical cancer in sub-Saharan Africa, a better knowledge of the regional cervicovaginal microbiome is required This review establishes current knowledge of HPV, HIV, cervicovaginal infections, and the cervicovaginal microbiota in sub-Saharan Africa. Because population statistics are not available for the region, estimates are derived from smaller cohort studies. Microbiota associated with cervical inflammation have been found to be especially prevalent in sub-Saharan Africa, and to associate with increased cervical cancer risk. In addition to high prevalence and diversity of HIV and HPV, intracellular bacterial infections such as Chlamydia, Gonorrhea, and Mycoplasma hominis are much more common than in regions with a low burden of cervical cancer. This suggests the prevalence of cervical cancer in sub-Saharan Africa may be partially attributed to increased cervical inflammation resulting from higher likelihood of cervical infection and/or microbial dysbiosis