A simple approach to the correlation of rotovibrational states in four-atomic molecules

The problem of correlation between quantum states of four-atomic molecules in different geometrical configurations is reviewed in detail. A general, still simple rule is obtained which allows one to correlate states of a linear four-atomic molecule with those of any kind of non-linear four-atomic molecule.Comment: 16 pages (+8 figures), Postscript (ready to print!

Physical conditions in the Protoplanetary Nebula CRL 618 derived from observations of vibrationally excited HCCCN

We used the Effelsberg 100m and IRAM 30m telescopes to observe vibrationally excited cyanoacetylene (HCCCN) in several rotational transitions toward the proto-planetary nebula CRL618. Lines from 9 different vibrationally excited states with energies ranging up to 1600 K above ground were detected. The lines show P Cygni profiles indicating that the HCCCN emission originates from an expanding and accelerating molecular envelope. The HCCCN rotational temperature varies with velocity, peaks at 520 K, 3 km/s blue-shifted from the systemic velocity and decreases with higher blueshift of the gas. The column density of the absorbing HCCCN is 3-6 x 1E17 cm^2. We modeled spectra based on spherical models of the expanding envelope which provide an excellent fit to the observations, and discuss the implications of the models. Additionally, lines from 13C substituted cyanoacetylene were observed. They can be used to constrain the 12C/13C ratio in this source to 10+-2.Comment: 27 pages, 9 figures, to appear in Ap

A 492 GHz cooled Schottky receiver for radio-astronomy

We developed a 492 GHz cooled GaAs Schottky receiver driven by a solid state local oscillator with a DSB noise temperature of 550 K measured at the telescope. The receiver-bandwidth is approx. equal to 1.0 GHz. Quasi-optical mirrors focus the sky and local oscillator radiation into the mixer. Stability analysis via the Allan variance method shows that the total system including a 1 GHz bandwidth acousto-optical spectrometer built in Cologne allows integration times up to 100 sec per half switching cycle. We successfully used the receiver at the KOSMA 3 m telescope on Gornergrat (3150m) located in the central Swiss Alps near Zermatt during January-February 1992 for observations of the 492 GHz, (CI) (3)P1 to (3)P0 fine structure line in several galactic sources. These observations confirm that Gornergrat is an excellent winter submillimeter site in accordance with previous predictions based on the atmospheric opacity from KOSMA 345 GHz measurements

A Pre-Protostellar Core in L1551

Large field surveys of NH3, C2S, 13CO and C18O in the L1551 dark cloud have revealed a prolate, pre-protostellar molecular core (L1551-MC) in a relatively quiescent region to the northwest of the well-known IRS 5 source. The kinetic temperature is measured to be 9K, the total mass is ~2Msun, and the average particle density is 10^4-10^5 cm^(-3). L1551-MC is 2.25' x 1.11' in projection oriented at a position angle of 133deg. The turbulent motions are on the order of the sound speed in the medium and contain 4% of the gravitational energy, E_{grav}, of the core. The angular momentum vector is projected along the major axis of L1551-MC corresponding to a rotational energy of 2.5E-3(sin i)^(-2)|E_{grav}|. The thermal energy constitutes about a third of |E_{grav}| and the virial mass is approximately equal to the total mass. L1551-MC is gravitationally bound and in the absence of strong, ~160 microgauss, magnetic fields will likely contract on a ~0.3 Myr time scale. The line profiles of many molecular species suggest that the cold quiescent interior is surrounded by a dynamic, perhaps infalling envelope which is embedded within the ambient molecular gas of L1551.Comment: 27 pages, 7 figures, ApJ accepte

Notations and conventions in molecular spectroscopy: part 1. General spectroscopic notation

The field of Molecular Spectroscopy was surveyed in order to determine a set of conventions and symbols which are in common use in the spectroscopic literature. This document, which is Part I in a series, establishes the notations and conventions used for general spectroscopic notations and deals with quantum mechanics, quantum numbers (vibrational states, angular momentum and energy levels), spectroscopic transitions, and miscellaneous notations (e.g. spectroscopic terms). Further parts will follow, dealing inter alia with symmetry notation, permutation and permutation-inversion symmetry notation, vibration-rotation spectroscopy and electronic spectroscopy

Notations and conventions in molecular spectroscopy: part 2. Symmetry notation

The field of Molecular Spectroscopy was surveyed in order to determine a set of conventions and symbols which are in common use in the spectroscopic literature. This document, which is Part 2 in a series, establishes the notations and conventions used for the description of symmetry in rigid molecules, using the Schoenflies notation. It deals firstly with the symmetry operators of the molecular point groups (also drawing attention to the difference between symmetry operators and elements). The conventions and notations of the molecular point groups are then established, followed by those of the representations of these groups as used in molecular spectroscopy. Further parts will follow, dealing inter alia with permutation and permutation-inversion symmetry notation, vibration-rotation spectroscopy and electronic spectroscopy

Detection of FeO towards SgrB2

We have observed the J=5-4 ground state transition of FeO at a frequency of 153 GHz towards a selection of galactic sources. Towards the galactic center source SgrB2, we see weak absorption at approximately the velocity of other features towards this source (62 km s$^{-1}$ LSR). Towards other sources, the results were negative as they were also for MgOH(3-2) and FeC(6-5). We tentatively conclude that the absorption seen toward SgrB2 is due to FeO in the hot ($\sim$ 500 K) relatively low density absorbing gas known to be present in this line of sight. This is the first (albeit tentative) detection of FeO or any iron--containing molecule in the interstellar gas. Assuming the observed absorption to be due to FeO, we estimate [FeO]/[SiO] to be of order or less than 0.002 and [FeO]/[H$_{2}$] of order $3 10^{-11}$. This is compatible with our negative results in other sources. Our results suggest that the iron liberated from grains in the shocks associated with SgrB2 remains atomic and is not processed into molecular form.Comment: 1 postscrit figure,10 page

The Distribution of Water Emission in M17SW

We present a 17-point map of the M17SW cloud core in the 1_{10}-1_{01} transition of ortho-water at 557 GHz obtained with the Submillimeter Wave Astronomy Satellite. Water emission was detected in 11 of the 17 observed positions. The line widths of the water emission vary between 4 and 9 km s^{-1}, and are similar to other emission lines that arise in the M17SW core. A direct comparison is made between the spatial extent of the water emission and the ^{13}CO J = 5\to4 emission; the good agreement suggests that the water emission arises in the same warm, dense gas as the ^{13}CO emission. A spectrum of the H_2^{18}O line was also obtained at the center position of the cloud core, but no emission was detected. We estimate that the average abundance of ortho-water relative to H_2 within the M17 dense core is approximately 1x10^{-9}, 30 times smaller than the average for the Orion core. Toward the H II region/molecular cloud interface in M17SW the ortho-water abundance may be about 5 times larger than in the dense core.Comment: 4 pages, 3 Postscript figures, uses aastex.cls, emulateapj5.sty (included), and apjfonts.sty (included

Water Abundance in Molecular Cloud Cores

We present Submillimeter Wave Astronomy Satellite (SWAS) observations of the 1_{10}-1_{01} transition of ortho-water at 557 GHz toward 12 molecular cloud cores. The water emission was detected in NGC 7538, Rho Oph A, NGC 2024, CRL 2591, W3, W3(OH), Mon R2, and W33, and was not detected in TMC-1, L134N, and B335. We also present a small map of the water emission in S140. Observations of the H_2^{18}O line were obtained toward S140 and NGC 7538, but no emission was detected. The abundance of ortho-water relative to H_2 in the giant molecular cloud cores was found to vary between 6x10^{-10} and 1x10^{-8}. Five of the cloud cores in our sample have previous water detections; however, in all cases the emission is thought to arise from hot cores with small angular extents. The water abundance estimated for the hot core gas is at least 100 times larger than in the gas probed by SWAS. The most stringent upper limit on the ortho-water abundance in dark clouds is provided in TMC-1, where the 3-sigma upper limit on the ortho-water fractional abundance is 7x10^{-8}.Comment: 5 pages, 3 Postscript figures, uses aastex.cls, emulateapj5.sty (included), and apjfonts.sty (included

Accurate laboratory rest frequencies of vibrationally excited CO up to varv=3varv = 3 and up to 2 THz

Astronomical observations of (sub)millimeter wavelength pure rotational emission lines of the second most abundant molecule in the Universe, CO, hold the promise of probing regions of high temperature and density in the innermost parts of circumstellar envelopes. The rotational spectrum of vibrationally excited CO up to \varv = 3 has been measured in the laboratory between 220 and 1940 GHz with relative accuracies up to $5.2 \times 10^{-9}$, corresponding to $\sim 5$ kHz near 1 THz. The rotational constant $B$ and the quartic distortion parameter $D$ have been determined with high accuracy and even the sextic distortion term $H$ was determined quite well for \varv = 1 while reasonable estimates of $H$ were obtained for \varv = 2 and 3. The present data set allows for the prediction of accurate rest frequencies of vibrationally excited CO well beyond 2 THz.Comment: Astron. Astrophys, accepted; 5 pages, 2 Figures, 2 Table