Development and evaluation of die and container materials

X = 0.75 Beta prime Sialon (a silicon aluminum oxynitride) and Sibeon (silicon beryllium oxynitride) are promising die materials. In sessile drop tests in contact with molten silicon, beryllium contamination was less than ppm and aluminum contamination 50 ppm. A shaping die of the Sialon material was successfully fabricated. Dry milling studies for the preparation of Si3N4-Al2O3-ALN mixtures were performed with butanol, acetic anhydride, oleic acid, and triethanolamine milling aids. Optimum mixing was achieved with 0.15 percent triethanolamine using a milling time of 8 hours. Preliminary evaluation of Sibeon materials indicates that they are more resistent to molten silicon attack than Sialon. Silicon contamination from the beryllium was less than aluminum contamination even though the aluminum impurity level in the Sibeon was only 450 to 1300 ppm. Work designed to produce an aluminum-free Sibeon is described

Rotating black hole hair

A Kerr black hole sporting cosmic string hair is studied in the context of the abelian Higgs model vortex. It is shown that such a system displays much richer phenomenology than its static Schwarzschild or Reissner-Nordstrom cousins, for example, the rotation generates a near horizon ‘electric’ field. In the case of an extremal rotating black hole, two phases of the Higgs hair are possible: large black holes exhibit standard hair, with the vortex piercing the event horizon. Small black holes on the other hand, exhibit a flux-expelled solution, with the gauge and scalar field remaining identically in their false vacuum state on the event horizon. This solution however is extremely sensitive to confirm numerically, and we conjecture that it is unstable due to a supperradiant mechanism similar to the Kerr-adS instability. Finally, we compute the gravitational back reaction of the vortex, which turns out to be far more nuanced than a simple conical deficit. While the string produces a conical effect, it is conical with respect to a local co-rotating frame, not with respect to the static frame at infinity

van der Waals phase transition in protein solutions

The van der Waals equation of state for imperfect gases is applied to solutions of macromolecules, especially to explain the fluid-fluid phase transition in protein solutions, a phenomenon of much interest in relation to protein crystallization. The van der Waals b parameter corresponds to the total excluded volume per pair of molecules and can be calculated from independently known molecular properties. It is comprised of terms resulting from hard-sphere and net charge-charge interactions. The experimentally determined second virial coefficient B can then be used to obtain the equilibrium constant for dimerization K, a phenomenologically accessible measure of the van der Waals a parameter. Sedimentation equilibrium is recommended as the technique for measuring B most accurately. More general results are used to make a minor quantitative correction to the van der Waals prediction concerning the criterion for the fluid-fluid phase transition. Calculations of the effect of inert co-solutes on the phase transition may prove useful in choosing crystallization conditions

Predictive learning, prediction errors, and attention: evidence from event-related potentials and eye tracking

Prediction error (‘‘surprise’’) affects the rate of learning: We learn more rapidly about cues for which we initially make incorrect predictions than cues for which our initial predictions are correct. The current studies employ electrophysiological measures to reveal early attentional differentiation of events that differ in their previous involvement in errors of predictive judgment. Error-related events attract more attention, as evidenced by features of event-related scalp potentials previously implicated in selective visual attention (selection negativity, augmented anterior N1). The earliest differences detected occurred around 120 msec after stimulus onset, and distributed source localization (LORETA) indicated that the inferior temporal regions were one source of the earliest differences. In addition, stimuli associated with the production of prediction errors show higher dwell times in an eyetracking procedure. Our data support the view that early attentional processes play a role in human associative learning

Second Epoch Global VLBI Observations of Compact Radio Sources in the M82 Starburst Galaxy

We have presented the results of a second epoch of global Very Long Baseline Interferometry observations, taken on 23 February 2001 at a wavelength of 18 cm, of the central kiloparsec of the nearby starburst galaxy Messier 82. These observations were aimed at studying the structural and flux evolution of some of the compact radio sources in the central region that have been identified as supernova remnants. The objects 41.95+575 and 43.31+592 have been studied, expansion velocities of 2500 +/- 1200 km/s and 7350 +/- 2100 km/s respectively have been derived. Flux densities of 31.1 +/- 0.3 mJy and 17.4 +/- 0.3 mJy have been measured for the two objects. These results are consistent with measurements and predictions from previous epochs.Comment: 5 pages, 3 figures. To be published on the accompanying CD of the Proceedings of IAU Colloquium 192: Supernova

Toward Perfection: Kapellasite, Cu3Zn(OH)6Cl2, a New Model S = 1/2 Kagome Antiferromagnet

The search for the resonating valence bond (RVB) state continues to underpin many areas of condensed matter research. The RVB is made from the dimerisation of spins on different sites into fluctuating singlets, and was proposed by Anderson to be the reference state from which the transition to BCS superconductivity occurs. Little is known about the state experimentally, due to the scarcity of model materials. Theoretical work has put forward the S = 1/2 kagome antiferromagnet (KAFM) as a good candidate for the realization of the RVB state. In this paper we introduce a new model system, the S = 1/2 KAFM Kapellasite, Cu3Zn(OH)6Cl2. We show that its crystal structure is a good approximation to a 2-dimensional kagome antiferromagnet and that susceptibility data indicate a collapse of the magnetic moment below T = 25 K that is compatible with the spins condensing into the non-magnetic RVB state.Comment: Communication, 3 pages, 3 figure

Prototype Backscatter Moessbauer Spectrometer for Measurement of Martian Surface Mineralogy

We have designed and successfully tested a prototype of a backscatter Moessbauer spectrometer (BaMS) targeted for use on the Martian surface to (1) determine oxidation states of iron, and (2) identify and determine relative abundances of iron-bearing mineralogies. No sample preparation is required to perform measurements; it is only necessary to bring sample and instrument into physical contact. The prototype meets our projected specification for a flight instrument in terms of mass, power, and volume. A Moessbauer spectrometer on the Martian surface would provide wide variety of information about the current state of the Martian surface, and this information is described

High-velocity-resolution observations of OH main line lasers in the M82 starburst

Using the VLA, a series of high velocity resolution observations have been made of the M82 starburst at 1.6 GHz. These observations follow up on previous studies of the main line OH maser emission in the central kiloparsec of this starburst region, but with far greater velocity resolution, showing significant velocity structure in some of the maser spots for the first time. A total of thirteen masers were detected, including all but one of the previously known sources. While some of these masers are still unresolved in velocity, these new results clearly show velocity structure in spectra from several of the maser regions. Position-velocity plots show good agreement with the distribution of H{\sc i} including interesting velocity structure on the blueward feature in the west of the starburst which traces the velocity distribution seen in the ionised gas.Comment: MNRAS in press. 15 pages, 9 figure

Deceleration and Dispersion of Large-scale Coronal Bright Fronts

One of the most dramatic manifestations of solar activity are large-scale coronal bright fronts (CBFs) observed in extreme ultraviolet (EUV) images of the solar atmosphere. To date, the energetics and kinematics of CBFs remain poorly understood, due to the low image cadence and sensitivity of previous EUV imagers and the limited methods used to extract the features. In this paper, the trajectory and morphology of CBFs was determined in order to investigate the varying properties of a sample of CBFs, including their kinematics and pulse shape, dispersion, and dissipation. We have developed a semi-automatic intensity profiling technique to extract the morphology and accurate positions of CBFs in 2.5-10 min cadence images from STEREO/EUVI. The technique was applied to sequences of 171A and 195A images from STEREO/EUVI in order to measure the wave properties of four separate CBF events. Following launch at velocities of ~240-450kms^{-1} each of the four events studied showed significant negative acceleration ranging from ~ -290 to -60ms^{-2}. The CBF spatial and temporal widths were found to increase from ~50 Mm to ~200 Mm and ~100 s to ~1500 s respectively, suggesting that they are dispersive in nature. The variation in position-angle averaged pulse-integrated intensity with propagation shows no clear trend across the four events studied. These results are most consistent with CBFs being dispersive magnetoacoustic waves.Comment: 15 pages, 18 figure

15 years of VLBI observations of two compact radio sources in Messier 82

We present the results of a second epoch of 18cm global Very Long-Baseline Interferometry (VLBI) observations, taken on 23 February 2001, of the central kiloparsec of the nearby starburst galaxy Messier 82. These observations further investigate the structural and flux evolution of the most compact radio sources in the central region of M82. The two most compact radio objects in M82 have been investigated (41.95+575 and 43.31+592). Using this recent epoch of data in comparison with our previous global VLBI observations and two earlier epochs of European VLBI Network observations we measure expansion velocities in the range of 1500-2000km/s for 41.95+575, and 9000-11000km/s for 43.31+592 using various independent methods. In each case the measured remnant expansion velocities are significantly larger than the canonical expansion velocity (500km/s) of supernova remnants within M82 predicted from theoretical models. In this paper we discuss the implications of these measured expansion velocities with respect to the high density environment that the SNR are expected to reside in within the centre of the M82 starburst.Comment: Accepted for publication in MNRAS, 9 pages, 8 figure