Star-Like Micelles with Star-Like Interactions: A quantitative Evaluation of Structure Factor and Phase Diagram

PEP-PEO block copolymer micelles offer the possibility to investigate phase behaviour and interactions of star polymers (ultra-soft colloids). A star-like architecture is achieved by an extremely asymmetric block ratio (1:20). Micellar functionality f can be smoothly varied by changing solvent composition (interfacial tension). Structure factors obtained by SANS can be quantitatively described in terms of an effective potential developed for star polymers. The experimental phase diagram reproduces to a high level of accuracy the predicted liquid/solid transition. Whereas for intermediate f a bcc phase is observed, for high f the formation of a fcc phase is preempted by glass formation.Comment: 5 pages, 4 figures, PRL in pres

Coherent electronic and nuclear dynamics in a rhodamine heterodimer-DNA supramolecular complex

Elucidating the role of quantum coherences in energy migration within biological and artificial multichromophoric antenna systems is the subject of an intense debate. It is also a practical matter because of the decisive implications for understanding the biological processes and engineering artificial materials for solar energy harvesting. A supramolecular rhodamine heterodimer on a DNA scaffold was suitably engineered to mimic the basic donor-acceptor unit of light-harvesting antennas. Ultrafast 2D electronic spectroscopic measurements allowed identifying clear features attributable to a coherent superposition of dimer electronic and vibrational states contributing to the coherent electronic charge beating between the donor and the acceptor. The frequency of electronic charge beating is found to be 970 cm-1 (34 fs) and can be observed for 150 fs. Through the support of high level ab initio TD-DFT computations of the entire dimer, we established that the vibrational modes preferentially optically accessed do not drive subsequent coupling between the electronic states on the 600 fs of the experiment. It was thereby possible to characterize the time scales of the early time femtosecond dynamics of the electronic coherence built by the optical excitation in a large rigid supramolecular system at a room temperature in solution. © 2017 the Owner Societies.Multi valued and parallel molecular logi

The Most Luminous z~9-10 Galaxy Candidates yet Found: The Luminosity Function, Cosmic Star-Formation Rate, and the First Mass Density Estimate at 500 Myr

[abridged] We present the discovery of four surprisingly bright (H_160 ~ 26 - 27 mag AB) galaxy candidates at z~9-10 in the complete HST CANDELS WFC3/IR GOODS-N imaging data, doubling the number of z~10 galaxy candidates that are known, just ~500 Myr after the Big Bang. Two similarly bright sources are also detected in a systematic re-analysis of the GOODS-S data set. Three of the four galaxies in GOODS-N are significantly detected at 4.5-6.2sigma in the very deep Spitzer/IRAC 4.5 micron data, as is one of the GOODS-S candidates. Furthermore, the brightest of our candidates (at z=10.2+-0.4) is robustly detected also at 3.6 micron (6.9sigma), revealing a flat UV spectral energy distribution with a slope beta=-2.0+-0.2, consistent with demonstrated trends with luminosity at high redshift. The abundance of such luminous candidates suggests that the luminosity function evolves more significantly in phi_* than in L_* at z>~8 with a higher number density of bright sources than previously expected. Despite the discovery of these luminous candidates, the cosmic star formation rate density for galaxies with SFR >0.7 M_sun/yr shows an order-of-magnitude increase in only 170 Myr from z ~ 10 to z ~ 8, consistent with previous results. Based on the IRAC detections, we derive galaxy stellar masses at z~10, finding that these luminous objects are typically 10^9 M_sun. The cosmic stellar mass density at z~10 is log10 rho_* = 4.7^+0.5_-0.8 M_sun Mpc^-3 for galaxies brighter than M_UV~-18. The remarkable brightness, and hence luminosity, of these z~9-10 candidates highlights the opportunity for deep spectroscopy to determine their redshift and nature, demonstrates the value of additional search fields covering a wider area to understand star-formation in the very early universe, and highlights the opportunities for JWST to map the buildup of galaxies at redshifts much earlier than z~10.Comment: 20 pages, 12 figures, changed to match resubmitted version to Ap

The AGN Contribution to the Mid-IR Emission of Luminous Infrared Galaxies

We determine the contribution of AGN to the mid-IR emission of luminous infrared galaxies (LIRGs) at z>0.6 by measuring the mid-IR dust continuum slope of 20,039 mid-IR sources. The 24 micron sources are selected from a Spitzer/MIPS survey of the NOAO Deep Wide-Field Survey Bo\"otes field and have corresponding 8 micron data from the IRAC Shallow Survey. There is a clear bimodal distribution in the 24 micron to 8 micron flux ratio. The X-ray detected sources fall within the peak corresponding to a flat spectrum in nufnu, implying that it is populated by AGN-dominated LIRGs, whereas the peak corresponding to a higher 24 micron to 8 micron flux ratio is likely due to LIRGs whose infrared emission is powered by starbursts. The 24 micron emission is increasingly dominated by AGN at higher 24 micron flux densities (f_24): the AGN fraction of the z>0.6 sources increases from ~9% at f_24 ~ 0.35 mJy to 74+/-20% at f_24 ~ 3 mJy in good agreement with model predictions. Deep 24 micron, small area surveys, like GOODS, will be strongly dominated by starburst galaxies. AGN are responsible for ~ 3-7% of the total 24 micron background.Comment: 6 pages, accepted for publication in Ap

Development of new all-optical signal regeneration technique

All-optical signal regeneration have been the active research area since last decade due to evolution of nonlinear optical signal processing. Existing all-optical signal regeneration techniques are agitated in producing low Bit Error Rate (BER) of 10-10 at below than -10 dBm power received. In this paper, a new all-optical signal regeneration technique is developed by using phase sensitive amplification and designed optical phase locked signal mechanism. The developed all-optical signal regeneration technique is tested for different 10 Gb/s Differential Phase Shift Keying degraded signals. It is determined that the designed all-optical signal regeneration technique is able to provide signal regeneration with noise mitigation for degraded signals. It is analyzed that overall, for all degraded test signals, average BER of 10-13 is achieved at received power of -14 dBm. The designed technique will be helpful to enhance the performance of existing signal regeneration systems in the presence of severe noise by providing minimum BER at low received power

The role of AGN in the colour transformation of galaxies at redshifts z~1

We explore the role of AGN in establishing and/or maintaining the bimodal colour distribution of galaxies by quenching their star-formation and hence, causing their transition from the blue to the red cloud. Important tests for this scenario include (i) the X-ray properties of galaxies in the transition zone between the two clouds and (ii) the incidence of AGN in post-starbursts, i.e. systems observed shortly after (<1Gyr) the termination of their star-formation. We perform these tests by combining deep Chandra observations with multiwavelength data from the AEGIS survey. Stacking the X-ray photons at the positions of galaxies (0.4<z<0.9) not individually detected at X-ray wavelengths suggests a population of obscured AGN among sources in the transition zone and in the red cloud. Their mean X-ray and mid-IR properties are consistent with moderately obscured low-luminosity AGN, Compton thick sources or a mix of both. Morphologies show that major mergers are unlikely to drive the evolution of this population but minor interactions may play a role. The incidence of obscured AGN in the red cloud (both direct detections and stacking results) suggests that BH accretion outlives the termination of the star-formation. This is also supported by our finding that post-starburst galaxies at z~0.8 and AGN are associated, in agreement with recent results at low-z. A large fraction of post-starbursts and red cloud galaxies show evidence for at least moderate levels of AGN obscuration. This implies that if AGN outflows cause the colour transformation of galaxies, then some nuclear gas and dust clouds either remain unaffected or relax to the central galaxy regions after the quenching their star-formation.Comment: Accepted for publication in MNRA

Spitzer IRS Spectra of Optically Faint Infrared Sources with Weak Spectral Features

Spectra have been obtained with the low-resolution modules of the Infrared Spectrograph (IRS) on the Spitzer Space Telescope (Spitzer) for 58 sources having f$_{\nu}$(24 micron) > 0.75 mJy. Sources were chosen from a survey of 8.2 deg$^{2}$ within the NOAO Deep Wide-Field Survey region in Bootes (NDWFS) using the Multiband Imaging Photometer (MIPS) on the Spitzer Space Telescope. Most sources are optically very faint (I > 24mag). Redshifts have previously been determined for 34 sources, based primarily on the presence of a deep 9.7 micron silicate absorption feature, with a median z of 2.2. Spectra are presented for the remaining 24 sources for which we were previously unable to determine a confident redshift because the IRS spectra show no strong features. Optical photometry from the NDWFS and infrared photometry with MIPS and the Infrared Array Camera on the Spitzer Space Telescope (IRAC) are given, with K photometry from the Keck I telescope for some objects. The sources without strong spectral features have overall spectral energy distributions (SEDs) and distributions among optical and infrared fluxes which are similar to those for the sources with strong absorption features. Nine of the 24 sources are found to have feasible redshift determinations based on fits of a weak silicate absorption feature. Results confirm that the "1 mJy" population of 24 micron Spitzer sources which are optically faint is dominated by dusty sources with spectroscopic indicators of an obscured AGN rather than a starburst. There remain 14 of the 58 sources observed in Bootes for which no redshift could be estimated, and 5 of these sources are invisible at all optical wavelengths.Comment: Accepted by Ap

The Bursty Star Formation Histories of Low-mass Galaxies at 0.4<z<10.4<z<1 Revealed by Star Formation Rates Measured from Hβ\beta and FUV

We investigate the burstiness of star formation histories (SFHs) of galaxies at $0.4<z<1$ by using the ratio of star formation rates (SFRs) measured from H$\beta$ and FUV (1500 \AA) (H$\beta$--to--FUV ratio). Our sample contains 164 galaxies down to stellar mass (M*) of $10^{8.5} M_\odot$ in the CANDELS GOODS-N region, where Team Keck Redshift Survey DEIMOS spectroscopy and HST/WFC3 F275W images from CANDELS and Hubble Deep UV Legacy Survey are available. When the {\it ratio} of H$\beta$- and FUV-derived SFRs is measured, dust extinction correction is negligible (except for very dusty galaxies) with the Calzetti attenuation curve. The H$\beta$--to--FUV ratio of our sample increases with M* and SFR. The median ratio is $\sim$0.7 at M*$\sim10^{8.5} M_\odot$ (or SFR$\sim 0.5 M_\odot/yr$) and increases to $\sim$1 at M*$\sim10^{10} M_\odot$ (or SFR $\sim 10 M_\odot/yr$). At M*$<10^{9.5} M_\odot$, our median H$\beta$--to--FUV ratio is lower than that of local galaxies at the same M*, implying a redshift evolution. Bursty SFH on a timescale of a few tens of megayears on galactic scales provides a plausible explanation of our results, and the importance of the burstiness increases as M* decreases. Due to sample selection effects, our H$\beta$--to--FUV ratio may be an upper limit of the true value of a complete sample, which strengthens our conclusions. Other models, e.g., non-universal initial mass function or stochastic star formation on star cluster scales, are unable to plausibly explain our results.Comment: 13 pages, 8 figures. ApJ accepted. The main conclusions are not changed. Major modifications include: (1) to be consistent with the literature, now reporting H\beta--to--FUV ratio (rather than FUV--to--H\beta\ in the first version); (2) detailed discussions on dust extinction correction; (3) new SF bustiness calculation; and (4) enriched discussions in Introductio

The Mid-Infrared Properties of X-ray Sources

We combine the results of the Spitzer IRAC Shallow Survey and the Chandra XBootes Survey of the 8.5 square degrees Bootes field of the NOAO Deep Wide- Field Survey to produce the largest comparison of mid-IR and X-ray sources to date. The comparison is limited to sources with X-ray fluxes >8x10-15 erg cm-2s-1 in the 0.5-7.0 keV range and mid-IR sources with 3.6 um fluxes brighter than 18.4 mag (12.3 uJy). In this most sensitive IRAC band, 85% of the 3086 X-ray sources have mid-IR counterparts at an 80% confidence level based on a Bayesian matching technique. Only 2.5% of the sample have no IRAC counterpart at all based on visual inspection. Even for a smaller but a significantly deeper Chandra survey in the same field, the IRAC Shallow Survey recovers most of the X-ray sources. A majority (65%) of the Chandra sources detected in all four IRAC bands occupy a well-defined region of IRAC [3.6] - [4.5] vs [5.8] - [8.0] color-color space. These X-ray sources are likely infrared luminous, unobscured type I AGN with little mid-infrared flux contributed by the AGN host galaxy. Of the remaining Chandra sources, most are lower luminosity type I and type II AGN whose mid-IR emission is dominated by the host galaxy, while approximately 5% are either Galactic stars or very local galaxies.Comment: Accepted for publication in Ap