Constraints on short, hard gamma-ray burst beaming angles from gravitational wave observations

The first detection of a binary neutron star merger, GW170817, and an associated short gamma-ray burst confirmed that neutron star mergers are responsible for at least some of these bursts. The prompt gamma-ray emission from these events is thought to be highly relativistically beamed. We present a method for inferring limits on the extent of this beaming by comparing the number of short gamma-ray bursts (SGRBs) observed electromagnetically with the number of neutron star binary mergers detected in gravitational waves. We demonstrate that an observing run comparable to the expected Advanced LIGO (aLIGO) 2016–2017 run would be capable of placing limits on the beaming angle of approximately \theta \in (2\buildrel{\circ}\over{.} 88,14\buildrel{\circ}\over{.} 15), given one binary neutron star detection, under the assumption that all mergers produce a gamma-ray burst, and that SGRBs occur at an illustrative rate of ${{ \mathcal R }}_{\mathrm{grb}}=10\,{\mathrm{Gpc}}^{-3}\,{\mathrm{yr}}^{-1}$. We anticipate that after a year of observations with aLIGO at design sensitivity in 2020, these constraints will improve to \theta \in (8\buildrel{\circ}\over{.} 10,14\buildrel{\circ}\over{.} 95), under the same efficiency and SGRB rate assumptions

A Comparison of Grassland Management Systems for Beef Cattle Using Self-Contained Farmlets: Effects of Contrasting Nitrogen Inputs and Management Strategies on the Farm Economy

The financial implications of manipulating nitrogen (N) inputs and management strategies for beef production systems were assessed. One-hectare grassland farmlets were grazed to a target sward height by beef steers; herbage surplus to grazing requirements was cut for silage. Three systems were compared: ‘CN’, conventional mineral N application to a grass monoculture and broadcast slurry; ‘TN’, tactical mineral N application at fortnightly intervals to a grass monoculture with slurry injection and the early housing of cattle; ‘GC’, a mixed grass/white clover sward with no mineral N addition and slurry injection. Comparisons were made on two contrasting soil types: a freely-draining sandy loam (site 1) and a poorly drained clay (site 2). Financial budgets for 1999-2000 show that estimated gross profit margins (gross outputs minus variable costs), after deducting contractor’s charges for sward preparation and fertiliser spreading, were highest for treatment CN at both sites Î(€1552, €1356 and €1461 ha-1 for site 1 and €1562, €1281 and €1287 ha-1 for site 2, for treatments CN, TN and GC, respectively). Treatment TN was penalised by increased costs associated with an extended housed period and the need to purchase additional silage for winter feeding which cost €242 ha-1 at site 1 and €250 ha-1 at site 2. Savings in N fertiliser for TN in comparison with CN (€44 ha-1 at site 1 and €39 ha-1 at site 2) were more than offset by the increased costs of fortnightly fertiliser applications (€54 ha-1 at site 1 and €46 ha-1 at site 2). Treatment GC benefited from zero costs for the purchase and spreading of mineral N fertiliser but was penalised by increased variation in forage DM production which resulted in a shortfall in winter fodder requirements with a replacement cost of €250 at site 1 and €435 at site 2. The best overall economic performance after the allocation of all possible relevant costs (variable, fixed and capital) in terms of the relative net profit margin, was for GC at site 1 and for CN at site 2 (-€1358, -€2399 and -€1304 ha-1 at site 1 and -€1122, -€2810 and - €1380 ha-1 at site 2, for CN, TN and GC, respectively). The opportunity costs of reducing N surpluses at the gross profit margin level (after contractor’s charges) for treatments TN and GC over treatment CN were calculated at €2.29 kg-1 N surplus for TN and €0.67 kg-1 N surplus for GC at site 1, with corresponding values of €4.91 and €1.57 at site 2.Farmlets, Systems, Beef cattle, Nitrogen, Slurry, Animal production, Economics, UK, Farm Management,

Photon Funnels for One-Way Energy Transfer: Multimetallic Assemblies Incorporating Cyclometallated Iridium or Rhodium Units Accessed by Sequential Cross-Coupling and Bromination

The generation of multimetallic assemblies is a widely explored theme, owing to the relevance of controlling energy and electron transfer between metal centres to many fields of contemporary importance. Boronic acid substituted coordination and organometallic complexes have been shown to be useful synthons in the formation of such structures through cross-coupling with halogenated complexes. In this work we used such a methodology to generate an octanuclear mixed-metal compound of composition Ir7Ru having a dendrimer wedge-like structure. The method combined cross-coupling with regiospecific bromination of phenylpyridine (ppy) ligands at the position para to the C–Ir bond. The propensity of Ir(ppy)2-based complexes to electrophilic bromination was found to be deactivated by the introduction of fluorine atoms. The coupling methodology was extended to rhodium-containing systems, exemplified by a tetranuclear system of composition Rh2Ir1Ru1. The synthesis required the use of boronic acid appended RhIII complexes, which could be accessed by the introduction of a neopentyl boronate ester appended bipyridine into the coordination sphere of RhIII. The excited-state energies of the constituent metal units in the resulting multinuclear complexes are such that unidirectional energy transfer occurs from the RhIII/IrIII branches to the RuII core. The luminescence thus resembles that of an isolated [Ru(bpy)3]2+ unit, but the ability of the structure to collect light is greatly enhanced

Assessment of the environmental impacts of ASR schemes.

This report describes the results of modelling studies undertaken to assess the impacts of ASR on the local environment. Understanding and quantifying these impacts, in relation to other existing or proposed schemes, will be vital in the development, and subsequent licensing of any ASR scheme. As each individual scheme has its own hydrogeological and environmental setting, as well as operational requirements, an all-encompassing model cannot be prescribed. Rather, a set of models, of increasing complexity, have been run for ‘typical’ scenarios to illustrate their use and limitations. They are designed to act as screening tools to assist practitioners, at all stages of an investigation, to decide on the suitability of a site and to identify what additional data are required in order to proceed to the next stage. The models are appended to the report so practitioners can apply them to their specific site, as appropriate

Impact of climate change and population growth on a risk assessment for endocrine disruption in fish due to steroid estrogens in England and Wales

In England and Wales, steroid estrogens: estrone, estradiol and ethinylestradiol have previously been identified as the main chemicals causing endocrine disruption in male fish. A national risk assessment is already available for intersex in fish arising from estrogens under current flow conditions. This study presents, to our knowledge, the first set of national catchment-based risk assessments for steroid estrogen under future scenarios. The river flows and temperatures were perturbed using three climate change scenarios (ranging from relatively dry to wet). The effects of demographic changes on estrogen consumption and human population served by sewage treatment works were also included. Compared to the current situation, the results indicated increased future risk:the percentage of high risk category sites, where endocrine disruption is more likely to occur, increased. These increases were mainly caused by changes in human population. This study provides regulators with valuable information to prepare for this potential increased risk

Luminescent bis-tridentate iridium(III) complexes: Overcoming the undesirable reactivity of trans-disposed metallated rings using –N^N^N–coordinating bis(1,2,4-triazolyl)pyridine ligands

Nine new iridium(III) complexes featuring two tridentate ligands have been synthesised of the form Ir(N^C^N)(–N^N^N–), where N^C^N represents a cyclometallating ligand based on 1,3-di(2-pyridyl)benzene and –N^N^N– is a doubly deprotonated bis(1,2,4-triazolyl)pyridine. Three examples of each ligand have been used, with different substituents in the central aryl ring of the former and para-substituted aryl groups in the 5-positions of the triazole rings of the latter. Two of the complexes have been structurally characterised in the solid-state by X-ray diffraction, confirming the mutually orthogonal arrangement of the two ligands. Unlike related tris-cyclometallated complexes of the type Ir(N^C^N)(C^N^C), which are unstable with respect to photoactivated cleavage of the trans-disposed Ir–C bonds, the new complexes show no evidence of instability. They are phosphorescent in the green region of the spectrum with lifetimes around 200 ns and quantum yields up to 3%, apparently limited by non-radiative decay processes in particular. Although there is some variation in performance with substitution pattern, the only discernible trend is that complexes of the 4-methoxy-substituted N^C^N ligand are the better emitters. Three examples of related complexes of the form Ir(N^C^N)(N^N–)Cl – incorporating a bidentate 1,2,4-triazolylpyridine – have also been prepared. They show no room-temperature emission but the properties at 77 K are similar to those of the bis-tridentate systems

Unexpectedly Low Rangewide Population Genetic Structure of the Imperiled Eastern Box Turtle Terrapene c. carolina.

Rangewide studies of genetic parameters can elucidate patterns and processes that operate only over large geographic scales. Herein, we present a rangewide population genetic assessment of the eastern box turtle Terrapene c. carolina, a species that is in steep decline across its range. To inform conservation planning for this species, we address the hypothesis that disruptions to demographic and movement parameters associated with the decline of the eastern box turtle has resulted in distinctive genetic signatures in the form of low genetic diversity, high population structuring, and decreased gene flow. We used microsatellite genotype data from (n = 799) individuals from across the species range to perform two Bayesian population assignment approaches, two methods for comparing historical and contemporary migration among populations, an evaluation of isolation by distance, and a method for detecting barriers to gene flow. Both Bayesian methods of population assignment indicated that there are two populations rangewide, both of which have maintained high levels of genetic diversity (HO = 0.756). Evidence of isolation by distance was detected in this species at a spatial scale of 300 – 500 km, and the Appalachian Mountains were identified as the primary barrier to gene flow across the species range. We also found evidence for historical but not contemporary migration between populations. Our prediction of many, highly structured populations across the range was not supported. This may point to cryptic contemporary gene flow, which might in turn be explained by the presence of rare transients in populations. However these data may be influenced by historical signatures of genetic connectivity because individuals of this species can be long-lived