413 research outputs found
Core hole-electron correlation in coherently coupled molecules
We study the core hole-electron correlation in coherently coupled molecules
by energy dispersive near edge X-ray absorption fine-structure spectroscopy. In
a transient phase, which exists during the transition between two bulk
arrangements, 1,4,5,8-naphthalene-tetracarboxylicacid-dianhydride multilayer
films exhibit peculiar changes of the line shape and energy position of the
X-ray absorption signal at the C K-edge with respect to the bulk and gas phase
spectra. By a comparison to a theoretical model based on a coupling of
transition dipoles, which is established for optical absorption, we demonstrate
that the observed spectroscopic differences can be explained by an
intermolecular delocalized core hole-electron pair. By applying this model we
can furthermore quantify the coherence length of the delocalized core-exciton.Comment: 5 pages, 3 figures, Accepted Version, PRL, minor wording change
New Tensor Particles from pi -> e nu gamma and K -> pi e nu Decays
The inserting of antisymmetric tensor fields into the standard electroweak
theory may explain the recent experiments on pi -> e nu gamma and K -> pi e nu
decays. New intermediate particles can induce the destructive interference in
the pion decay and the nonzero tensor and scalar form factors in the kaon
decay.Comment: 11 pages, 4 figures, LaTex version of a published paper, the work is
actual in connection with the confirmation of pi -> e nu gamma anomaly by
PIBETA Collaboration (hep-ex/0312029
Adsorption geometry and electronic structure of iron phthalocyanine on Ag surfaces: A LEED and photoelectron momentum mapping study
We present a comprehensive study of the adsorption behavior of iron
phthalocyanine on the low-index crystal faces of silver. By combining
measurements of the reciprocal space by means of photoelectron momentum mapping
and low energy electron diffraction, the real space adsorption geometries are
reconstructed. At monolayer coverage ordered superstructures exist on all
studied surfaces containing one molecule in the unit cell in case of Ag(100)
and Ag(111), and two molecules per unit cell for Ag(110). The azimuthal tilt
angle of the molecules against the high symmetry directions of the substrate is
derived from the photoelectron momentum maps. A comparative analysis of the
momentum patterns on the substrates with different symmetry indicates that both
constituents of the twofold degenerate FePc lowest unoccupied molecular orbital
are occupied by charge transfer from the substrate at the interface
Quasi-periodic spin chains in a magnetic field
We study the interplay between a (quasi) periodic coupling array and an
external magnetic field in a spin-1/2 XXZ chain. A new class of magnetization
plateaux are obtained by means of Abelian bosonization methods which give rise
to a sufficient quantization condition. The investigation of magnetic phase
diagrams via exact diagonalization of finite clusters finds a complete
agreement with the continuum treatment in a variety of situations.Comment: 4 pages RevTeX, 5 PostScript figures included. Final version to
appear in PR
Phase diagram of an asymmetric spin ladder
We investigate an asymmetric zig-zag spin ladder with different exchange
integrals on both legs using bosonization and renormalization group. When the
leg exchange integrals and frustration both are sufficiently small,
renormalization group analysis shows that the Heisenberg critical point flows
to an intermediate-coupling fixed point with gapless excitations and a
vanishing spin velocity. When they are large, a spin gap opens and a dimer
liquid is realized. Here, we find a continuous manifold of Hamiltonians with
dimer product ground states, interpolating between the Majumdar-Ghosh and
sawtooth spin-chain model.Comment: 4 pages, 2 EPS figures, to be published in PR
A Genome-Wide Association Study Using a Custom Genotyping Array Identifies Variants in GPR158 Associated with Reduced Energy Expenditure in American Indians
Pima Indians living in Arizona have a high prevalence of obesity, and we have previously shown that a relatively lower energy expenditure (EE) predicts weight and fat mass gain in this population. EE is a familial trait (heritability = 0.52); therefore, in the current study, we aimed to identify genetic variants that affect EE and thereby influence BMI and body fatness in Pima Indians. Genotypic data from 491,265 variants were analyzed for association with resting metabolic rate (RMR) and 24-h EE assessed in a whole-room calorimeter in 507 and 419 Pima Indians, respectively. Variants associated with both measures of EE were analyzed for association with maximum BMI and percent body fat (PFAT) in 5,870 and 912 Pima Indians, respectively. rs11014566 nominally associated with both measures of EE and both measures of adiposity in Pima Indians, where the G allele (frequency: Pima Indians = 0.60, Europeans <0.01) associated with lower 24-h EE ( = -33 kcal/day per copy), lower RMR ( = -31 kcal/day), higher BMI ( = +0.6 kg/m(2)), and higher PFAT ( = +0.9%). However, the association of rs11014566 with BMI did not directionally replicate when assessed in other ethnic groups. rs11014566 tags rs144895904, which affected promoter function in an in vitro luciferase assay. These variants map to GPR158, which is highly expressed in the brain and interacts with two other genes (RGS7 and CACNA1B) known to affect obesity in knockout mice. Our results suggest that common ethnic-specific variation in GPR158 may influence EE; however, its role in weight gain remains controversial, as it either had no association with BMI or associated with BMI but in the opposite direction in other ethnic groups
Style, Function and Cultural Transmission
Recent evolutionary approaches to the understanding of lithic variability take us back to long-standing issues in lithic studies to do with the claimed contrast between style and function and the Binford-Bordes debate of the 1960s concerning the factors that affect inter-assemblage variation. In fact, the style and function contrast is an unhelpful one, not least when considering the question of convergence. Taking the definition of style as ‘a way of doing’, all functions are carried out in locally specific ways that have a transmission history, although the extent to which the history of the attributes relevant to the function have been subject to random drift and innovation patterns, as opposed to selection, will vary. Moreover, in a subtractive technology like lithics the extent to which a transmission signal will be visible in an attribute like the angle of a cutting edge is unclear. The contrasting view is that, in the case of lithics, functional requirements will always call into existence the technical innovations to satisfy them, which in any case are not that difficult to find. The paper addresses these and related issues with reference to previous work by Shennan and colleagues on the use of material culture to identify within and between group variation, the extent to which isolation-by-distance in space and time can account for the similarities and differences between assemblages, and the role of phylogenetic methods
Lithic technological responses to Late Pleistocene glacial cycling at Pinnacle Point Site 5-6, South Africa
There are multiple hypotheses for human responses to glacial cycling in the Late Pleistocene, including changes in population size, interconnectedness, and mobility. Lithic technological analysis informs us of human responses to environmental change because lithic assemblage characteristics are a reflection of raw material transport, reduction, and discard behaviors that depend on hunter-gatherer social and economic decisions. Pinnacle Point Site 5-6 (PP5-6), Western Cape, South Africa is an ideal locality for examining the influence of glacial cycling on early modern human behaviors because it preserves a long sequence spanning marine isotope stages (MIS) 5, 4, and 3 and is associated with robust records of paleoenvironmental change. The analysis presented here addresses the question, what, if any, lithic assemblage traits at PP5-6 represent changing behavioral responses to the MIS 5-4-3 interglacial-glacial cycle? It statistically evaluates changes in 93 traits with no a priori assumptions about which traits may significantly associate with MIS. In contrast to other studies that claim that there is little relationship between broad-scale patterns of climate change and lithic technology, we identified the following characteristics that are associated with MIS 4: increased use of quartz, increased evidence for outcrop sources of quartzite and silcrete, increased evidence for earlier stages of reduction in silcrete, evidence for increased flaking efficiency in all raw material types, and changes in tool types and function for silcrete. Based on these results, we suggest that foragers responded to MIS 4 glacial environmental conditions at PP5-6 with increased population or group sizes, 'place provisioning', longer and/or more intense site occupations, and decreased residential mobility. Several other traits, including silcrete frequency, do not exhibit an association with MIS. Backed pieces, once they appear in the PP5-6 record during MIS 4, persist through MIS 3. Changing paleoenvironments explain some, but not all temporal technological variability at PP5-6.Social Science and Humanities Research Council of Canada; NORAM; American-Scandinavian Foundation; Fundacao para a Ciencia e Tecnologia [SFRH/BPD/73598/2010]; IGERT [DGE 0801634]; Hyde Family Foundations; Institute of Human Origins; National Science Foundation [BCS-9912465, BCS-0130713, BCS-0524087, BCS-1138073]; John Templeton Foundation to the Institute of Human Origins at Arizona State Universit
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