1,826 research outputs found
1,3,4,6-Tetramethyl-1,4-dihydro-1,2,4,5-tetrazine, C_6H_(12)N_4
M_r =140∙19, monoclinic, P2_1/n, a = 10∙612(3), b=6∙820(1), c= 10∙975 (2) Å, β=95∙31(2)°, V=790.9(5) Å^3, Z=4, D_m=1.13(5) (flotation), D_x = 1∙177 g cm^(-3), Mo Kα, λ = 0.71073 Å, μ= 0.848 cm^(-1), F(000) = 304, T= 295 K, R = 0∙077 for 704 observed reflections. This potentially antiaromatic or homoaromatic ring system has a flattened boat conformation with both N-methyls in equatorial positions. Bond angles and distances (excluding H's) predicted to be symmetry equivalent exhibit variations of 0.002-0.014 Å and 0.0-2.0°. Substantial delocalization of the electron lone pairs of N(1) and N(4) is found
Statistical Properties of Radio Emission from the Palomar Seyfert Galaxies
We have carried out an analysis of the radio and optical properties of a
statistical sample of 45 Seyfert galaxies from the Palomar spectroscopic survey
of nearby galaxies. We find that the space density of bright galaxies (-22 mag
<= M_{B_T} <= -18 mag) showing Seyfert activity is (1.25 +/- 0.38) X 10^{-3}
Mpc^{-3}, considerably higher than found in other Seyfert samples. Host galaxy
types, radio spectra, and radio source sizes are uncorrelated with Seyfert
type, as predicted by the unified schemes for active galaxies. Approximately
half of the detected galaxies have flat or inverted radio spectra, more than
expected based on previous samples. Surprisingly, Seyfert 1 galaxies are found
to have somewhat stronger radio sources than Seyfert 2 galaxies at 6 and 20 cm,
particularly among the galaxies with the weakest nuclear activity. We suggest
that this difference can be accommodated in the unified schemes if a minimum
level of Seyfert activity is required for a radio source to emerge from the
vicinity of the active nucleus. Below this level, Seyfert radio sources might
be suppressed by free-free absorption associated with the nuclear torus or a
compact narrow-line region, thus accounting for both the weakness of the radio
emission and the preponderance of flat spectra. Alternatively, the flat spectra
and weak radio sources might indicate that the weak active nuclei are fed by
advection-dominated accretion disks.Comment: 18 pages using emulateapj5, 13 embedded figures, accepted by Ap
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English individualism refuted - and reasserted: the land market of Earls Colne (Essex), 1550-1750
This is the author's post-print version of an article whose final and definitive form has been published in The Economic History Review. © 2003 Blackwell Publishing Ltd. The definitive version is available at: http://www3.interscience.wiley.com/journal/118509292/homeEarls Colne first came to the notice of historians through Macfarlane's study of its seventeenth-century vicar, Ralph Josselin, and then Macfarlane's use of evidence from the village in his The Origins of English Individualism (1978). This article presents preliminary results drawn from a computer-based reconstruction of the copyhold land market, 1546-1750, to contest Macfarlane's reading of the family-land bond in the manor. The familial possession of land over long periods is shown to be normal, and consistent with an active land market predominantly in smaller parcels. Little consolidation took place in the manor although some growth in holding size was achieved through subtenancy. Finally, the article asks whether the experience of copyholders is typical of the general.University of Central Lancashir
Epidermal growth factor receptors in intracranial and breast tumours: their clinical significance.
A method to determine the binding of epidermal growth factor (EGF) to the particulate fraction of the cell has been established and evaluated using rat liver, human placenta, and tumours of human breast and brain. Little EGF receptor (EGFR) activity was detected in normal or benign tumour tissues except for meningioma (positive in 95% samples), but EGFR were present in 43% of 131 breast tumours and 75% of 55 primary cerebral tumours. Despite the strong inverse correlation between EGFR activity and oestrogen receptors in breast tumours and a tendency for high levels of EGFR activity to be associated with glioblastoma multiforme, analysis showed that EGFR was of little prognostic significance in patients with tumours of either breast or brain
Granger causality and transfer entropy are equivalent for Gaussian variables
Granger causality is a statistical notion of causal influence based on
prediction via vector autoregression. Developed originally in the field of
econometrics, it has since found application in a broader arena, particularly
in neuroscience. More recently transfer entropy, an information-theoretic
measure of time-directed information transfer between jointly dependent
processes, has gained traction in a similarly wide field. While it has been
recognized that the two concepts must be related, the exact relationship has
until now not been formally described. Here we show that for Gaussian
variables, Granger causality and transfer entropy are entirely equivalent, thus
bridging autoregressive and information-theoretic approaches to data-driven
causal inference.Comment: In review, Phys. Rev. Lett., Nov. 200
A Quantum Langevin Formulation of Risk-Sensitive Optimal Control
In this paper we formulate a risk-sensitive optimal control problem for
continuously monitored open quantum systems modelled by quantum Langevin
equations. The optimal controller is expressed in terms of a modified
conditional state, which we call a risk-sensitive state, that represents
measurement knowledge tempered by the control purpose. One of the two
components of the optimal controller is dynamic, a filter that computes the
risk-sensitive state.
The second component is an optimal control feedback function that is found by
solving the dynamic programming equation. The optimal controller can be
implemented using classical electronics.
The ideas are illustrated using an example of feedback control of a two-level
atom
Probing the Ionizing Continuum of Narrow-Line Seyfert 1 Galaxies. I.Observational Results
We present optical spectra and emission-line ratios of 12 Narrow-Line Seyfert
1 (NLS1) galaxies that we observed to study the ionizing EUV continuum. A
common feature in the EUV continuum of active galactic nuclei is the big blue
bump (BBB), generally associated with thermal accretion disk emission. While
Galactic absorption prevents direct access to the EUV range, it can be mapped
by measuring the strength of a variety of forbidden optical emission lines that
respond to different EUV continuum regions. We find that narrow emission-line
ratios involving [OII]3727, Hbeta, [OIII]5007, [OI]6300, Halpha,[NII]6583, and
[SII]6716,6731 indicate no significant difference between NLS1s and Broad-Line
Seyfert 1 (BLS1) galaxies, which suggests that the spectral energy
distributions of their ionizing EUV - soft X-ray continua are similar. The
relative strength of important forbidden high ionization lines like [NeV]3426
compared to HeII4686 and the relative strength of [FeX]6374 appear to show the
same range as in BLS1 galaxies. However, a trend of weaker
F([OI]6300)/F(Halpha) emission-line ratios is indicated for NLS1s compared to
BLS1s. To recover the broad emission-line profiles we used Gaussian components.
This approach indicates that the broad Hbeta profile can be well described with
a broad component (FWHM = 3275 +- 800 km/s) and an intermediate broad component
(FWHM = 1200 +- 300 km/s). The width of the broad component is in the typical
range of normal BLS1s. The emission-line flux that is associated with the broad
component in these NLS1s amounts to at least 60% of the total flux. Thus it
dominates the total line flux, similar to BLS1 galaxies.Comment: 34 pages, 9 figures. accepted for publication in the
Astrophys.Journa
ISO-SWS spectroscopy of NGC 1068
We present ISO-SWS spectroscopy of NGC 1068 for the wavelength range 2.4 to
45um, detecting a total of 36 emission lines. Most of the observed transitions
are fine structure and recombination lines originating in the narrow line
region. We compare the line profiles of optical lines and reddening-insensitive
infrared lines to constrain the dynamical structure and extinction properties
of the NLR. The considerable differences found are most likely explained by two
effects. (1) The spatial structure of the NLR is a combination of a highly
ionized outflow cone and lower excitation extended emission. (2) Parts of the
NLR, mainly in the receding part at velocities above systemic, are subject to
extinction that is significantly suppressing optical emission. Line asymmetries
and net blueshifts remain, however, even for infrared fine structure lines
suffering very little obscuration. This may be either due to an intrinsic
asymmetry of the NLR, or due to a very high column density obscuring component
which is hiding part of the NLR even from infrared view. Mid-infrared emission
of molecular hydrogen in NGC 1068 arises in a dense molecular medium at
temperatures of a few hundred Kelvin that is most likely closely related to the
warm and dense components seen in the near-infrared H2 transitions, and in
millimeter wave tracers of molecular gas. Any emission of the putative pc-scale
molecular torus is likely overwhelmed by this larger scale emission.Comment: aastex (V4), 9 eps figures. Accepted by Ap
The origin of the Narrow Line Region of Mrk 3: an overpressured jet cocoon
We have obtained HST FOC long-slit optical spectroscopy of the Narrow Line
Region of the Seyfert 2 galaxy Mrk 3. In the region cospatial with the
radio-jet the velocity field is highly perturbed and shows two velocity systems
separated by as much as 1700 km/s. We interpret this to be the consequence of
the rapid expansion of a cocoon of hot gas, shocked and heated by the
radio-emitting outflow, which compresses and accelerates the ambient gas. The
NLR itself is essentially a cylindrical shell expanding supersonically. From
the size and velocity of the expanding region, we derive an upper limit to the
radio-source age, ~ 2
E42 erg/s required to inflate the cocoon and estimate that the jet minimum
advance speed is 3 E-3 pc per year. The total kinetic energy of the high
velocity NLR gas can be estimated as ~6 E54 erg, comparable to the total energy
carried by the jet over its lifetime and this quantitatively supports the idea
that the NLR gas is accelerated by the jet. If the advance speed of Mrk 3 is
representative of the Seyfert population then these sources must also be short
lived and probably recurrent. The jet kinetic luminosity of Mrk 3 is between 2
and 3 orders of magnitude smaller than that derived for radio-loud AGNs with
similar emission-line luminosity. On the other hand, the fraction of jet power
dissipated in radio-emission is similar. We speculate that the main distinction
between radio-quiet and radio-loud AGN is ascribed to a difference in jet power
rather than to a different efficiency in synchrotron emission production.Comment: 13 pages, 8 figures, Astrophysical Journal in pres
Physical Conditions in the Narrow-Line Region of M51
We have investigated the physical conditions in the narrow-line region (NLR)
of M51 using long-slit spectra obtained with the Space Telescope Imaging
Spectrograph (STIS) aboard the Hubble Space Telescope (HST) and 3.6 cm radio
continuum observations obtained with the Very Large Array (VLA). Emission-line
diagnostics were employed for nine NLR clouds, which extend 2.5" (102 pc) from
the nucleus, to examine the electron density, temperature, and ionization state
of the NLR gas. The emission-line ratios are consistent with those typically
found in Seyfert nuclei and indicate that within the inner near-nuclear region
(r ~< 1") the ionization decreases with increasing radius. Upper-limits to the
[O III] electron temperature (T ~< 11,000 K) for the inner NLR clouds indicate
that photoionization is the dominant ionization mechanism close to the nucleus.
The emission-line fluxes for most of the NLR clouds can be reproduced
reasonably well by simple photoionization models using a central power-law
continuum source and supersolar nitrogen abundances. Shock+precursor models,
however, provide a better fit to the observed fluxes of an NLR cloud ~2.5"
south of the nucleus that is identified with the extra-nuclear cloud (XNC). The
large [O III] electron temperature of this cloud (T = 24,000 K) further
suggests the presence of shocks. This cloud is straddled by two radio knots and
lies near the location where a weak radio jet, ~2.5" (102pc) in extent,
connects the near-nuclear radio emission with a diffuse lobe structure spanning
\~4" (163 pc). It is plausible that this cloud represents the location where
the radio jet impinges on the disk ISM.Comment: 25 pages, 26 figures (9 color), 7 tables. Accepted for publication in
the Astrophysical Journa
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