691 research outputs found

    Shale weathering rates across a continental-scale climosequence

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    A transect of sites has been established in North America and England as part of the Critical Zone Exploration Network (CZEN) to investigate the rates of soil formation across a climate gradient. Sites reported here are all underlain by an organic-poor, iron-rich Silurian-age shale, providing a constant parent material lithology from which soil is forming. This climosequence includes relatively cold and wet sites in Wales, New York and Pennsylvania, with temperature increasing to the south in Virginia, Tennessee and Alabama. Puerto Rico provides a warm/wet end member for the transect, although this site does not lie on the same shale formation as the Appalachian Mountain sites. Geochemical, mineralogical, and cosmogenic isotope analyses are being completed similarly at all sites to allow direct comparisons and eventual modelling of the weathering processes. Preliminary results from Wales, Pennsylvania and Virginia show soils become more sodium-depleted and the depth to bedrock is significantly deeper at the wet/warm site in Virginia. The fraction of Na lost relative to parent material composition at each site varies linearly as a function of mean annual temperature. Overall, results from the transect will promote a better understanding of how climate changes and human activities impact soil formation rates

    Shale weathering rates across a continental-scale climosequence

    Get PDF
    A transect of sites has been established in North America and England as part of the Critical Zone Exploration Network (CZEN) to investigate the rates of soil formation across a climate gradient. Sites reported here are all underlain by an organic-poor, iron-rich Silurian-age shale, providing a constant parent material lithology from which soil is forming. This climosequence includes relatively cold and wet sites in Wales, New York and Pennsylvania, with temperature increasing to the south in Virginia, Tennessee and Alabama. Puerto Rico provides a warm/wet end member for the transect, although this site does not lie on the same shale formation as the Appalachian Mountain sites. Geochemical, mineralogical, and cosmogenic isotope analyses are being completed similarly at all sites to allow direct comparisons and eventual modelling of the weathering processes. Preliminary results from Wales, Pennsylvania and Virginia show soils become more sodium-depleted and the depth to bedrock is significantly deeper at the wet/warm site in Virginia. The fraction of Na lost relative to parent material composition at each site varies linearly as a function of mean annual temperature. Overall, results from the transect will promote a better understanding of how climate changes and human activities impact soil formation rates

    Sentiment analysis and the impact of employee satisfaction on firm earnings

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    Prior text mining studies of corporate reputational sentiment based on newswires, blogs and Twitter feeds have mostly captured reputation from the perspective of two groups of stakeholders – the media and consumers. In this study we examine the sentiment of a potentially overlooked stakeholder group, namely, the firm’s employees. First, we present a novel dataset that uses online employee reviews to capture employee satisfaction. We employ LDA to identify salient aspects in employees’ reviews, and manually infer one latent topic that appears to be associated with the firm’s outlook. Second, we create a composite document by aggregating employee reviews for each firm and measure employee sentiment as the polarity of the composite document using the General Inquirer dictionary to count positive and negative terms. Finally, we define employee satisfaction as a weighted combination of the firm outlook topic cluster and employee sentiment. The results of our joint aspect-polarity model suggest that it may be beneficial for investors to incorporate a measure of employee satisfaction into their method for forecasting firm earnings

    Ultracold Atoms in 1D Optical Lattices: Mean Field, Quantum Field, Computation, and Soliton Formation

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    In this work, we highlight the correspondence between two descriptions of a system of ultracold bosons in a one-dimensional optical lattice potential: (1) the discrete nonlinear Schr\"{o}dinger equation, a discrete mean-field theory, and (2) the Bose-Hubbard Hamiltonian, a discrete quantum-field theory. The former is recovered from the latter in the limit of a product of local coherent states. Using a truncated form of these mean-field states as initial conditions, we build quantum analogs to the dark soliton solutions of the discrete nonlinear Schr\"{o}dinger equation and investigate their dynamical properties in the Bose-Hubbard Hamiltonian. We also discuss specifics of the numerical methods employed for both our mean-field and quantum calculations, where in the latter case we use the time-evolving block decimation algorithm due to Vidal.Comment: 14 pages, 2 figures; to appear in Journal of Mathematics and Computers in Simulatio

    The Density Matrix Renormalization Group technique with periodic boundary conditions

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    The Density Matrix Renormalization Group (DMRG) method with periodic boundary conditions is introduced for two dimensional classical spin models. It is shown that this method is more suitable for derivation of the properties of infinite 2D systems than the DMRG with open boundary conditions despite the latter describes much better strips of finite width. For calculation at criticality, phenomenological renormalization at finite strips is used together with a criterion for optimum strip width for a given order of approximation. For this width the critical temperature of 2D Ising model is estimated with seven-digit accuracy for not too large order of approximation. Similar precision is reached for critical indices. These results exceed the accuracy of similar calculations for DMRG with open boundary conditions by several orders of magnitude.Comment: REVTeX format contains 8 pages and 6 figures, submitted to Phys. Rev.

    Simple, reliable protocol for high-yield solubilization of seedless amyloid-β monomer

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    Self-assembly of the amyloid-β (Aβ) peptide to form toxic oligomers and fibrils is a key causal event in the onset of Alzheimer’s disease, and Aβ is the focus of intense research in neuroscience, biophysics, and structural biology aimed at therapeutic development. Due to its rapid self-assembly and extreme sensitivity to aggregation conditions, preparation of seedless, reproducible Aβ solutions is highly challenging, and there are serious ongoing issues with consistency in the literature. In this paper, we use a liquid-phase separation technique, asymmetric flow field-flow fractionation with multiangle light scattering (AF4-MALS), to develop and validate a simple, effective, economical method for re-solubilization and quality control of purified, lyophilized Aβ samples. Our findings were obtained with recombinant peptide but are physicochemical in nature and thus highly relevant to synthetic peptide. We show that much of the variability in the literature stems from the inability of overly mild solvent treatments to produce consistently monomeric preparations and is rectified by a protocol involving high-pH (>12) dissolution, sonication, and rapid freezing to prevent modification. Aβ treated in this manner is chemically stable, can be stored over long timescales at −80 °C, and exhibits remarkably consistent self-assembly behavior when returned to near-neutral pH. These preparations are highly monomeric, seedless, and do not require additional rounds of size exclusion, eliminating the need for this costly procedure and increasing the flexibility of use. We propose that our improved protocol is the simplest, fastest, and most effective way to solubilize Aβ from diverse sources for sensitive self-assembly and toxicity assays

    SU(N) Evolution of a Frustrated Spin Ladder

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    Recent studies indicate that the weakly coupled spin-1/2 Heisenberg antiferromagnet with next nearest neighbor frustration supports massive spinons when suitably tuned. The straightforward SU(N) generalization of the low energy ladder Hamiltonian yields two independent SU(N) Thirring models with N-1 multiplets of massive ``spinon'' excitations. We study the evolution of the complete set of low-energy dynamical structure factors using form factors. Those corresponding to the smooth (staggered) magnetizations are qualitatively different (the same) in the N=2 and N>2 cases. The absence of single-particle peaks preserves the notion of spinons stabilized by frustration. In contrast to the ladder, we note that the N=infinity limit of the four chain magnet is not a trivial free theory.Comment: 10 pages, RevTex, 5 figures; SU(N) approach clarifie
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