4,366 research outputs found
Differential Scattering Cross-Sections for the Different Product Vibrational States in the Ion-Molecule Reaction Ar+ + N2
The charge transfer reaction Ar+ + N2 --> Ar + N2+ has been investigated in a
crossed beam experiment in combination with three-dimensional velocity map
imaging. Angular differential state-to-state cross sections were determined as
a function of the collision energy. We found that scattering into the first
excited vibrational level dominates as expected, but only for scattering in the
forward direction. Higher vibrational excitations up to v'=6 have been observed
for larger scattering angles. For decreasing collision energy, scattering into
higher scattering angles becomes increasingly important for all kinematically
allowed quantum states. Our detailed measurements indicate that a quantitative
agreement between experiment and theory for this basic ion-molecule reaction
now comes within reach.Comment: accepted to Phys. Rev. Let
Enantiomer fractions instead of enantiomer ratios
The use of enantiomer ratios (ERs) to indicate the relative amounts of a pair of enantiomers in a sample has some disadvantages. Enantiomer fractions (EFs) are proposed as all alternative expression to eliminate the difficulties. (C) 2000 Elsevier Science Ltd
HABITAT UTILIZATION BY THE TEXAS HORNED LIZARD (PHRYNOSOMA CORNUTUM) FROM TWO SITES IN CENTRAL TEXAS
The Texas Horned Lizard (Phrynosoma cornutum) is found in a variety of habitats. Although several studies have been conducted on habitat use by this species, none have been performed in central Texas, a more mesic habitat than most of those previously studied. This area is of special interest because horned lizard populations have been experiencing sharp declines in central Texas over the last approximately 50 years. We collected habitat data at two sites in central Texas, Camp Bowie and Blue Mountain Peak Ranch. Microhabitat data included canopy cover and ground cover from digitized photographs of Daubenmire quadrats; macrohabitat variables included vegetation height and length, cactus height, soil penetrability, woody plant species richness, tree density, tree diameter at breast height (DBH), and density of ant mounds collected along 100-m by 2-m transects. Similar patterns of habitat use were observed between the two sites. At Blue Mountain Peak Ranch, lizards appeared to be located in areas with a diversity of ground cover types, as observed in previous studies. At Camp Bowie, vegetation encroachment limited lizards in some areas to the use of roads and road margins. Implementation of prescribed burns or other vegetation management could create the preferred ground cover mosaic at such sites
How can a 22-pole ion trap exhibit 10 local minima in the effective potential?
The column density distribution of trapped OH ions in a 22-pole ion trap
is measured for different trap parameters. The density is obtained from
position-dependent photodetachment rate measurements. Overall, agreement is
found with the effective potential of an ideal 22-pole. However, in addition we
observe 10 distinct minima in the trapping potential, which indicate a breaking
of the 22-fold symmetry. Numerical simulations show that a displacement of a
subset of the radiofrequency electrodes can serve as an explanation for this
symmetry breaking
Evaporation of buffer gas-thermalized anions out of a multipole rf ion trap
We identify plain evaporation of ions as the fundamental loss mechanism out
of a multipole ion trap. Using thermalized negative Cl- ions we find that the
evaporative loss rate is proportional to a Boltzmann factor. This thermodynamic
description sheds new light on the dynamics of particles in time-varying
confining potentials. It specifically allows us to extract the effective depth
of the ion trap as the activation energy for evaporation. As a function of the
rf amplitude we find two distinct regimes related to the stability of motion of
the trapped ions. For low amplitudes the entire trap allows for stable motion
and the trap depth increases with the rf field. For larger rf amplitudes,
however, rapid energy transfer from the field to the ion motion can occur at
large trap radii, which leads to a reduction of the effective trapping volume.
In this regime the trap depth decreases again with increasing rf amplitude. We
give an analytical parameterization of the trap depth for various multipole
traps that allows predictions of the most favorable trapping conditions.Comment: Phys. Rev. Lett., in pres
Photodetachment of cold OH- in a multipole ion trap
The absolute photodetachment cross section of OH- anions at a rotational and
translational temperature of 170K is determined by measuring the
detachment-induced decay rate of the anions in a multipole radio-frequency ion
trap. In comparison with previous results, the obtained cross section shows the
importance of the initial rotational state distribution. Using a tomography
scan of the photodetachment laser through the trapped ion cloud, the derived
cross section is model-independent and thus features a small systematic
uncertainty. The tomography also yields the column density of the OH- anions in
the 22-pole ion trap in good agreement with the expected trapping potential of
a large field free region bound by steep potential walls.Comment: Phys. Rev. Lett., in pres
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