427 research outputs found
The effect of the liquid-solid system properties on the interline heat transfer coefficient
A theoretical procedure to determine the heat transfer characteristics of the interline region of an evaporating meniscus using the macroscopic optical and thermophysical properties of the system is outlined. The analysis is based on the premise that the interline transport processes are controlled by the London-van der Waals forces between condensed phases (solid and liquid). The procedure is used to compare the relative size of the interline heat sink of various systems using a constant heat flux model. This solution demonstrates the importance of the interline heat flow number which is evaluated for various systems. The heat transfer characteristics of the decane-steel system are numerically compared with those of the carbon tetrachloride-quartz system
An augmented Young-Laplace model of an evaporating meniscus in a micro-channel with high heat flux
High flux evaporations from a steady meniscus formed in a 2 micron channel is modeled using the augmented Young-Laplace equation. The heat flux is found to be a function of the long range van der Waals dispersion force which represents interfacial conditions between heptane and various substrates. Heat fluxes of (1.3-1.6) x 10(exp 6) W/m(exp 2) based on the width of the channel are obtained for heptane completely wetting the substrate at 100 C. Small channels are used to obtain these large fluxes. Even though the real contact angle is 0 deg, the apparent contact angle is found to vary between 24.8 deg and 25.6 deg. The apparent contact angle, which represents viscous losses near the contact line, has a large effect on the heat flow rate because of its effect on capillary suction and the area of the meniscus. The interfacial heat flux is modeled using kinetic theory for the evaporation rate. The superheated state depends on the temperature and the pressure of the liquid phase. The liquid pressure differs from the pressure of the vapor phase due to capillarity and long range van der Waals dispersion forces which are relevant in the ultra think film formed at the leading edge of the meniscus. Important pressure gradients in the thin film cause a substantial apparent contact angle for a complete wetting system. The temperature of the liquid is related to the evaporation rate and to the substrate temperature through the steady heat conduction equation. Conduction in the liquid phase is calculated using finite element analysis except in the vicinity of the thin film. A lubrication theory solution for the thin film is combined with the finite element analysis by the method of matched asymptotic expansions
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Microcomputer enhanced optical investigation of spreading and evaporative processes in ultra thin films
The general objective of the research is to determine the heat transfer characteristics of evaporating ultra-thin films. The immediate objective is to develop a microscopic image-processing system (IPS) to measure the film thickness profile. The IPS has two parts: an image analyzing interferometer (IAI) and an image analyzing ellipsometer (IAE). An IAI was designed and used to measure the thickness profiles of an extended meniscus in the contact line region of completely wetting liquid films. Both steady state and oscillating menisci were studied. We find that the convenience and efficiency of mirocomputer enhanced video microscopy naturally leads to a better understanding of the transport processes in the contact line region. We also find that the processes of change-of-phase heat transfer and fluid flow in thin films are intrinsically connected because of their common dependence on the intermolecular force field. The design of an image analyzing ellipsometer (IAE) was completed and the system was successfully tested by measuring the thickness and refractive index profiles of various solid films of known thicknesses. The profile of draining isothermal films will be measured next
Code wars: steganography, signals intelligence, and terrorism
This paper describes and discusses the process of secret communication known as steganography. The argument advanced here is that terrorists are unlikely to be employing digital steganography to facilitate secret intra-group communication as has been claimed. This is because terrorist use of digital steganography is both technically and operationally implausible. The position adopted in this paper is that terrorists are likely to employ low-tech steganography such as semagrams and null ciphers instead
On Identifying the Appropriate Boundary Conditions'at a Moving Contact Line: An Experimental Investigation
and is slightly tapered as it merges with the adsorbed film. However, in employing this method, attention must be paid to the discontinuity in the interfacial curvature, which can be made negligible by properly selecting the matching point between an interline and thin film solutions
DâAgents: Security in a Multiple-Language, Mobile-Agent System
Abstract. Mobile-agent systems must address three security issues: protecting an individual machine, protecting a group of machines, and protecting an agent. In this chapter, we discuss these three issues in the context of DâAgents, a mobile-agent system whose agents can be written in Tcl, Java and Scheme. (DâAgents was formerly known as Agent Tcl.) First we discuss mechanisms existing in DâAgents for protecting an individual machine: (1) cryptographic authentication of the agentâs owner, (2) resource managers that make policy decisions based on the ownerâs identity, and (3) secure execution environments for each language that enforce the decisions of the resource managers. Then we discuss our planned market-based approach for protecting machine groups. Finally we consider several (partial) solutions for protecting an agent from a malicious machine.
Mechanical tuning of the evaporation rate of liquid on crossed fibers
We investigate experimentally the drying of a small volume of perfectly
wetting liquid on two crossed fibers. We characterize the drying dynamics for
the three liquid morphologies that are encountered in this geometry: drop,
column and a mixed morphology, in which a drop and a column coexist. For each
morphology, we rationalize our findings with theoretical models that capture
the drying kinetics. We find that the evaporation rate depends significantly on
the liquid morphology and that the drying of liquid column is faster than the
evaporation of the drop and the mixed morphology for a given liquid volume.
Finally, we illustrate that shearing a network of fibers reduces the angle
between them, changes the morphology towards the column state, and so enhances
the drying rate of a volatile liquid deposited on it
An Electrochemical Study of Frustrated Lewis Pairs: A Metal-free Route to Hydrogen Oxidation
[Image: see text] Frustrated Lewis pairs have found many applications in the heterolytic activation of H(2) and subsequent hydrogenation of small molecules through delivery of the resulting proton and hydride equivalents. Herein, we describe how H(2) can be preactivated using classical frustrated Lewis pair chemistry and combined with in situ nonaqueous electrochemical oxidation of the resulting borohydride. Our approach allows hydrogen to be cleanly converted into two protons and two electrons in situ, and reduces the potential (the required energetic driving force) for nonaqueous H(2) oxidation by 610 mV (117.7 kJ mol(â1)). This significant energy reduction opens routes to the development of nonaqueous hydrogen energy technology
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