Spin-polarized x-ray emission of 3d transition-metal ions: A comparison via K a and K ß detection

This paper demonstrates that spin-polarized x-ray-excitation spectra can be obtained using K a emission as well as K ß lines. A spin-polarized analysis of K a x-ray emission and the excitation spectra by K a detection on a Ni compound is reported. A systematic analysis of the first-row transition-metal ions using the ligand-field multiplet calculation is presented for K a and K ß emission spectra

Presacral Teratocarcinoma Presenting as Anal Fistula and Rectal Adenocarcinoma: A Unique Case Presentation and Literature Review

Somatic malignancy arising from presacral or retroperitoneal primary teratoma is extremely rare. We report the case of a 37-year-old male patient with adenocarcinoma of respiratory type arising from primary presacral teratoma, but which first presented as anal fistula and rectal adenocarcinoma. The two tumors show the same morphology and immunophenotype (CK7–CK20+CDx2+). Malignant adenocarcinoma transformations from the normal respiratory epithelium are also found. To the best of our knowledge, this is the second case of respiratory type adenocarcinoma arising from primary presacral mature cystic teratoma

Comparison of homogeneous and heterogeneous motorised traffic at signalised and two-way stop control single lane intersection

Results of a microscopic model of mixed motorised traffic consisting of short vehicles, (e.g. cars), and long vehicles, (taken to be double the length of the short vehicles), for an urban two-way single lane intersection are presented here. We model the intersection using both signalised and un-signalised stop control rules. The model allows for the detection of bottleneck activity in both homogenous and heterogeneous traffic conditions, and was validated by means of field data collected in Dublin, Ireland. The validated model was used to study the impact of inclusion of long vehicles on traffic performance in an urban environment. Traffic mix is, however, taken to be dominated by short vehicles overall, in argument with observed live data collected

Effect of Chinese herbal medicines on rumen fermentation, methanogenesis and microbial flora in vitro

This study was carried out to evaluate the effects of three Chinese herbal medicines (CHMs) on rumen fermentation, methane emission and population of ruminal microbes using an in vitro gas production technique. Three healthy wethers of Dazu Black goats with similar bodyweights and permanent rumen fistulae were utilized as donors of ruminal fluid. The three botanical medicines were cablin patchouli herb (CPH), atractylodes rhizome (AR) and Amur cork tree (AC). Each CHM was added at a level of 25 g/kg to the substrate dry matter. In vitro gas production was recorded, and methane concentration was determined at 12 and 24 hours of incubation. After 24 hours, the incubation was stopped, and the inoculants were measured for pH, ammonia nitrogen and volatile fatty acids (VFAs) concentrations. Total deoxyribonucleic acid of ruminal microbes was extracted from the inocula, and populations were determined by a real-time quantitative polymerase chain reaction. Populations of total rumen methanogens, protozoa, total fungi, Ruminococcus albus, Fibrobacter succinogenes and Ruminococcus flavefaciens were expressed as a proportion of total rumen bacterial 16S ribosomal deoxyribonucleic acid. Compared to the control, CPH decreased gas production and methane production at 12 and 24 hours of incubation, and inhibited methanogens and total fungi growth. AR decreased acetate to propionate ratio, and methanogens and total fungi populations, but increased propionate molar proportion. AC decreased total VFA concentration, acetate to propionate ratio, gas production at 12 and 24 hours of incubation, methane production at 12 and 24 hours of incubation, and methanogens and total fungi growth, but increased the propionate molar proportion. In conclusion, CPH and AC both suppressed methanogenesis significantly, and the suppression was mediated primarily via the direct action against the rumen microbes involved in methane formation. AC also indirectly abates methane release by occupying the hydrogen (H2) normally utilized for methanogenesis.Keywords: In vitro gas production, methane, rumen fermentation parameter, rumen microbe

Neutrino oscillations in magnetically driven supernova explosions

We investigate neutrino oscillations from core-collapse supernovae that produce magnetohydrodynamic (MHD) explosions. By calculating numerically the flavor conversion of neutrinos in the highly non-spherical envelope, we study how the explosion anisotropy has impacts on the emergent neutrino spectra through the Mikheyev-Smirnov-Wolfenstein effect. In the case of the inverted mass hierarchy with a relatively large theta_(13), we show that survival probabilities of electron type neutrinos and antineutrinos seen from the rotational axis of the MHD supernovae (i.e., polar direction), can be significantly different from those along the equatorial direction. The event numbers of electron type antineutrinos observed from the polar direction are predicted to show steepest decrease, reflecting the passage of the magneto-driven shock to the so-called high-resonance regions. Furthermore we point out that such a shock effect, depending on the original neutrino spectra, appears also for the low-resonance regions, which leads to a noticeable decrease in the electron type neutrino signals. This reflects a unique nature of the magnetic explosion featuring a very early shock-arrival to the resonance regions, which is in sharp contrast to the neutrino-driven delayed supernova models. Our results suggest that the two features in the electron type antineutrinos and neutrinos signals, if visible to the Super-Kamiokande for a Galactic supernova, could mark an observational signature of the magnetically driven explosions, presumably linked to the formation of magnetars and/or long-duration gamma-ray bursts.Comment: 25 pages, 21 figures, JCAP in pres

Occlusion of Sulfate-based Diblock Copolymer Nanoparticles within Calcite: Effect of Varying the Surface Density of Anionic Stabilizer Chains

Polymerization-induced self-assembly (PISA) offers a highly versatile and efficient route to a wide range of organic nanoparticles. In this article, we demonstrate for the first time that poly(ammonium 2-sulfatoethyl methacrylate)-poly(benzyl methacrylate) [PSEM–PBzMA] diblock copolymer nanoparticles can be prepared with either a high or low PSEM stabilizer surface density using either RAFT dispersion polymerization in a 2:1 v/v ethanol/water mixture or RAFT aqueous emulsion polymerization, respectively. We then use these model nanoparticles to gain new insight into a key topic in materials chemistry: the occlusion of organic additives into inorganic crystals. Substantial differences are observed for the extent of occlusion of these two types of anionic nanoparticles into calcite (CaCO3), which serves as a suitable model host crystal. A low PSEM stabilizer surface density leads to uniform nanoparticle occlusion within calcite at up to 7.5% w/w (16% v/v), while minimal occlusion occurs when using nanoparticles with a high PSEM stabilizer surface density. This counter-intuitive observation suggests that an optimum anionic surface density is required for efficient occlusion, which provides a hitherto unexpected design rule for the incorporation of nanoparticles within crystals

Responses of chemical composition, amino acid and fatty acid profiles of breast muscle to dietary crude fibre levels in China Micro-Ducks

The effects of dietary crude fibre (CF) levels on the chemical composition, amino acid (AA) and fatty acid (FA) profiles of breast muscle in male China Micro-ducks (21 - 56 d) were investigated in this study. The birds were randomly allocated to four treatments, of which dietary CF levels were 16.7, 42.6, 77.9 and 101.6 g/kg of dry matter (DM), respectively. No influences on the proportions of crude ash, crude protein, lysine, methionine, threonine, phenylalanine, histidine, arginine, aspartic acid, glutamic acid, glycine, alanine, serine, cysteine, tyrosine, proline, C12:0, C18:0, C18:1n9, C20:0 and C22:1n9 in muscle were observed across the treatments. Consequently, the concentrations of semi-essential AA, non-essential AA, total AA, aromatic AA and delicious AA in muscle, along with the Δ-9-desaturase (18) index, were not affected by the treatments. Significant lower concentrations of valine, leucine, isoleucine, essential AA, branched-chain AA, C16:1n7 and monounsaturated FA in muscle, along with a lower ratio of branched-chain to aromatic AA, were noted in a dietary treatment with a CF level of 16.7 g/kg DM compared to other dietary treatments. The rise of the dietary CF level significantly increased the proportions of DM, ether extract, gross energy, C18:2n6, C18:3n3, C20:4n6, unsaturated FA, total FA, polyunsaturated FA, n-3 polyunsaturated FA, n-6 polyunsaturated FA, essential FA, and the Δ-9-desaturase (16) index. Furthermore, the rise of the dietary CF level increased the ratios of unsaturated to saturated FA, polyunsaturated to saturated FA, and n-6 to n-3 polyunsaturated FA in muscle. However, it decreased the atherogenic index and the proportions of C14:0, C16:0, and saturated FA significantly. In conclusion, depending largely on dietary levels, CF profoundly and positively influenced the nutritional quality of breast muscle, especially the FA profile.Keywords: China Micro-duck, dietary fibre, fatty acid, nutritional quality of meat, fatty aci

Transcriptome analysis of hepatic gene expression and DNA methylation in methionine- and betaine-supplemented geese (Anser cygnoides domesticus)

Dietary methionine (Met) restriction produces a coordinated series of transcriptional responses in the liver that limits growth performance and amino acid metabolism. Methyl donor supplementation with betaine (Bet) may protect against this disturbance and affect the molecular basis of gene regulation. However, a lack of genetic information remains an obstacle to understand the mechanisms underlying the relationship between Met and Bet supplementation and its effects on genetic mechanisms. The goal of this study was to identify the effects of dietary supplementation of Met and Bet on growth performance, transcriptomic gene expression, and epigenetic mechanisms in geese on a Met-deficient diet. One hundred and fifty 21-day-old healthy male Yangzhou geese of similar body weight were randomly distributed into 3 groups with 5 replicates per treatment and 10 geese per replicate: Met-deficient diet (Control), Control+1.2 g/kg of Met (Met), and Control+0.6 g/kg of Bet (Bet). All geese had free access to the diet and water throughout rearing. Our results indicated that supplementation of 1.2 g/kg of Met in Met-deficient feed increased growth performance and plasma homocysteine (HCY) levels, indicating increased transsulfuration flux in the liver. Supplementation of 0.6 g/kg Bet had no apparent sparing effect on Met needs for growth performance in growing geese. The expression of many genes critical for Met metabolism is increased in Met supplementation group. In the Bet-supplemented group, genes involved in energy production and conversion were up-regulated. Dietary supplementation with Bet and Met also altered DNA methylation. We observed changes in the methylation of the LOC106032502 promoter and corresponding changes in mRNA expression. In conclusion, Met and Bet supplementation in geese affects the transcriptional regulatory network and alters the hepatic DNA methylation of LOC106032502