186 research outputs found

    Evidence for Disk Truncation at Low Accretion States of the Black Hole Binary MAXI J1820+070 Observed by NuSTAR and XMM-Newton

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    We present results from NuSTAR and XMM-Newton observations of the new black hole X-ray binary MAXI J1820+070 at low accretion rates (below 1% of the Eddington luminosity). We detect a narrow Fe Kα emission line, in contrast to the broad and asymmetric Fe Kα line profiles commonly present in black hole binaries at high accretion rates. The narrow line, with weak relativistic broadening, indicates that the Fe Kα line is produced at a large disk radius. Fitting with disk reflection models assuming standard disk emissivity finds a large disk truncation radius (a few tens to a few hundreds of gravitational radii, depending on the disk inclination). In addition, we detect a quasi-periodic oscillation (QPO) varying in frequency between 11.6 ± 0.2 mHz and 2.8 ± 0.1 mHz. The very low QPO frequencies suggest a large size for the optically thin Comptonization region according to the Lense–Thirring precession model, supporting that the accretion disk recedes from the innermost stable circular orbit and is replaced by advection-dominated accretion flow at low accretion rates. We also discuss the possibility of an alternative accretion geometry that the narrow Fe Kα line is produced by a lamppost corona with a large height illuminating the disk

    Evidence for Disk Truncation at Low Accretion States of the Black Hole Binary MAXI J1820+070 Observed by NuSTAR and XMM-Newton

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    We present results from NuSTAR and XMM-Newton observations of the new black hole X-ray binary MAXI J1820+070 at low accretion rates (below 1% of the Eddington luminosity). We detect a narrow Fe Kα emission line, in contrast to the broad and asymmetric Fe Kα line profiles commonly present in black hole binaries at high accretion rates. The narrow line, with weak relativistic broadening, indicates that the Fe Kα line is produced at a large disk radius. Fitting with disk reflection models assuming standard disk emissivity finds a large disk truncation radius (a few tens to a few hundreds of gravitational radii, depending on the disk inclination). In addition, we detect a quasi-periodic oscillation (QPO) varying in frequency between 11.6 ± 0.2 mHz and 2.8 ± 0.1 mHz. The very low QPO frequencies suggest a large size for the optically thin Comptonization region according to the Lense–Thirring precession model, supporting that the accretion disk recedes from the innermost stable circular orbit and is replaced by advection-dominated accretion flow at low accretion rates. We also discuss the possibility of an alternative accretion geometry that the narrow Fe Kα line is produced by a lamppost corona with a large height illuminating the disk

    Incorporation of square-planar Pd2+ in fluorite CeO2 : hydrothermal preparation, local structure, redox properties and stability

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    The direct hydrothermal crystallisation at 240 °C of Pd2+-containing ceria is investigated to study the extent to which precious metal dopants may be introduced into the cubic fluorite lattice. Samples of composition Ce1−xPdxO2−δ, where 0 ≤ x ≤ 0.15 can be produced in which Pd is included within the CeO2 structure to give a linear lattice expansion. Attempts to produce higher Pd2+-substitution result in the formation of PdO as a secondary phase. Ce and Pd were determined to be in the +4 and +2 oxidation states, respectively, by X-ray absorption near edge structure, suggesting oxide deficiency as the mechanism of charge balance. Extended X-ray absorption fine structure (EXAFS) analysis at the Pd K-edge reveals that Pd2+ has local square-planar coordination, as expected, and that a structural model can fitted in which the average fluorite structure is maintained, but with Pd2+ sitting in the square faces of oxide ions present in the local cubic geometry of Ce. This model, consistent with previous modelling studies, gives an excellent fit to the EXAFS spectra, and explains the observed lattice expansion. Transmission electron microscopy analysis shows that Pd is well dispersed in the nanocrystalline ceria particles, and in situ powder XRD shows that upon heating in air the samples remain stable up to 800 °C. H2-TPR shows that Pd-substitution leads to low temperature (<200 °C) reduction of the oxide, which increases in magnitude with increasing Pd-substitution. On prolonged heating, however, the Pd is lost from the ceria lattice to give dispersed Pd metal, suggesting an inherent instability of Pd-doped CeO2

    Integration of Electrodeposited Ni-Fe in MEMS with Low-Temperature Deposition and Etch Processes

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    This article presents a set of low-temperature deposition and etching processes for the integration of electrochemically deposited Ni-Fe alloys in complex magnetic microelectromechanical systems, as Ni-Fe is known to suffer from detrimental stress development when subjected to excessive thermal loads. A selective etch process is reported which enables the copper seed layer used for electrodeposition to be removed while preserving the integrity of Ni-Fe. In addition, a low temperature deposition and surface micromachining process is presented in which silicon dioxide and silicon nitride are used, respectively, as sacrificial material and structural dielectric. The sacrificial layer can be patterned and removed by wet buffered oxide etch or vapour HF etching. The reported methods limit the thermal budget and minimise the stress development in Ni-Fe. This combination of techniques represents an advance towards the reliable integration of Ni-Fe components in complex surface micromachined magnetic MEMS

    Climate Projections Very Likely Underestimate Future Volcanic Forcing and Its Climatic Effects

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    Standard climate projections represent future volcanic eruptions by a constant forcing inferred from 1850 to 2014 volcanic forcing. Using the latest ice-core and satellite records to design stochastic eruption scenarios, we show that there is a 95% probability that explosive eruptions could emit more sulfur dioxide (SO2) into the stratosphere over 2015–2100 than current standard climate projections (i.e., ScenarioMIP). Our simulations using the UK Earth System Model with interactive stratospheric aerosols show that for a median future eruption scenario, the 2015–2100 average global-mean stratospheric aerosol optical depth (SAOD) is double that used in ScenarioMIP, with small-magnitude eruptions (<3 Tg of SO2) contributing 50% to SAOD perturbations. We show that volcanic effects on large-scale climate indicators, including global surface temperature, sea level and sea ice extent, are underestimated in ScenarioMIP because current climate projections do not fully account for the recurrent frequency of volcanic eruptions of different magnitudes

    Instrumented cervical fusion using patient specific end-plate conforming interbody devices with a micro-porous structure in nine dogs with disk-associated cervical spondylomyelopathy

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    ObjectiveTo report the medium and long-term outcome of nine dogs with disk-associated cervical spondylomyelopathy (DA-CSM), treated by instrumented interbody fusion using patient specific end-plate conforming device that features a micro-porous structure to facilitate bone in-growth.Study designA retrospective clinical study.AnimalsNine medium and large breed dogs.MethodsMedical records at two institutions were reviewed between January 2020 and 2023. Following magnetic resonance imaging (MRI) diagnosis of DA-CSM, pre-operative computed tomography (CT) scans were exported to computer software for in-silico surgical planning. Interbody devices were 3D-manufactured by selecting laser melting in titanium alloy. These were surgically implanted at 13 segments alongside mono-or bi-cortical vertebral stabilization systems. Follow-up included neurologic scoring and CT scans post-operative, at medium-term follow up and at long-term follow-up where possible. Interbody fusion and implant subsidence were evaluated from follow-up CT scans.ResultsNine dogs were diagnosed with DA-CSM between C5-C7 at a total of 13 operated segments. Medium-term follow up was obtained between 2 and 8 months post-operative (3.00 ± 1.82 months). Neurologic scoring improved (p = 0.009) in eight of nine dogs. Distraction was significant (p &lt; 0.001) at all segments. Fusion was evident at 12/13 segments. Subsidence was evident at 3/13 operated segments but was only considered clinically relevant in one dog that did not improve; as clinical signs were mild, revision surgery was not recommended. Long-term follow up was obtained between 9 and 33 months (14.23 ± 8.24 months); improvement was sustained in 8 dogs. The dog that suffered worsened thoracic limb paresis at medium-term follow up was also diagnosed with immune-mediated polyarthropathy (IMPA) and was euthanased 9 months post-operative due to unacceptable side-effects of corticosteroid therapy.ConclusionEnd-plate conforming interbody devices with a micro-porous structure were designed, manufactured, and successfully implanted in dog with DA-CSM. This resulted in CT-determined fusion with minimal subsidence in the majority of operated segments.Clinical significanceThe technique described can be used to distract and fuse cervical vertebrae in dogs with DA-CSM, with favorable medium-and long-term outcomes

    Тепловой баланс помещения с электрической кабельной системой отопления

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    Solvothermal oxidation of metallic gallium in monoethanolamine for 72 h at 240 °C yields a crystalline sample of γ-Ga<sub>2</sub>O<sub>3</sub> (∼30 nm crystallites). While Rietveld refinement (cubic spinel structure, <i>Fd</i>3̅<i>m</i>; <i>a</i> = 8.23760(9) Å) reveals that Ga occupies two pairs of octahedral and tetrahedral sites (ideal spinel and nonspinel), it provides no information about their local distribution, which cannot be statistical owing to the short Ga–Ga contacts produced if neighboring ideal spinel and nonspinel sites are simultaneously occupied. To create an atomistic model to reconcile this situation, a 6 × 6 × 6 supercell of the crystal structure is constructed and refined against neutron total scattering data using a reverse Monte Carlo (RMC) approach. This accounts well for the local as well as long-range structure and reveals significant local distortion in the octahedral sites that resembles the structure of thermodynamically stable β-Ga<sub>2</sub>O<sub>3</sub>. <sup>71</sup>Ga solid-state NMR results reveal a octahedral:tetrahedral Ga ratio that is consistent with the model obtained from RMC. Nanocrystalline samples of γ-Ga<sub>2</sub>O<sub>3</sub> are produced by either a short solvothermal reaction (240 °C for 11 h in diethanolamine; ∼15 nm crystallites) or by precipitation from an ethanolic solution of gallium nitrate (∼5 nm crystallites). For these samples, the Bragg scattering profile is broadened by their smaller crystallite size, consistent with transmission electron microscopy results, and analysis of the relative Bragg peak intensities provides evidence that a greater proportion of tetrahedral versus octahedral sites are filled. In contrast, neutron total scattering shows the same average Ga–O distance with decreasing particle size, consistent with <sup>71</sup>Ga solid-state NMR results that indicate that all samples contain the same overall proportion of octahedral:tetrahedral Ga. It is postulated that increased occupation of tetrahedral sites within the smaller crystallites is balanced by an increased proportion of octahedral surface Ga sites, owing to termination by bound solvent or hydroxide
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