1,652 research outputs found
Solidification in soft-core fluids: disordered solids from fast solidification fronts
Using dynamical density functional theory we calculate the speed of
solidification fronts advancing into a quenched two-dimensional model fluid of
soft-core particles. We find that solidification fronts can advance via two
different mechanisms, depending on the depth of the quench. For shallow
quenches, the front propagation is via a nonlinear mechanism. For deep
quenches, front propagation is governed by a linear mechanism and in this
regime we are able to determine the front speed via a marginal stability
analysis. We find that the density modulations generated behind the advancing
front have a characteristic scale that differs from the wavelength of the
density modulation in thermodynamic equilibrium, i.e., the spacing between the
crystal planes in an equilibrium crystal. This leads to the subsequent
development of disorder in the solids that are formed. For the one-component
fluid, the particles are able to rearrange to form a well-ordered crystal, with
few defects. However, solidification fronts in a binary mixture exhibiting
crystalline phases with square and hexagonal ordering generate solids that are
unable to rearrange after the passage of the solidification front and a
significant amount of disorder remains in the system.Comment: 18 pages, 14 fig
Cloud-resolving simulations of mercury scavenging and deposition in thunderstorms
This study examines dynamical and microphysical features of convective clouds that affect mercury (Hg) wet scavenging and concentrations in rainfall. Using idealized numerical model simulations in the Regional Atmospheric Modeling System (RAMS), we diagnose vertical transport and scavenging of soluble Hg species – gaseous oxidized mercury (GOM) and particle-bound mercury (HgP), collectively Hg(II) – in thunderstorms under typical environmental conditions found in the Northeast and Southeast United States (US). Mercury scavenging efficiencies from various initial altitudes are diagnosed for a case study of a typical strong convective storm in the Southeast US. Assuming that soluble mercury concentrations are initially vertically uniform, the model results suggest that 60% of mercury deposited to the surface in rainwater originates from above the boundary layer (> 2 km). The free troposphere could supply a larger fraction of mercury wet deposition if GOM and HgP concentrations increase with altitude. We use radiosonde observations in the Northeast and Southeast to characterize three important environmental characteristics that influence thunderstorm morphology: convective available potential energy (CAPE), vertical shear (0–6 km) of horizontal wind (SHEAR) and precipitable water (PW). The Southeast US generally has lower SHEAR and higher CAPE and PW. We then use RAMS to test how PW and SHEAR impact mercury scavenging and deposition, while keeping the initial Hg(II) concentrations fixed in all experiments. We found that the mercury concentration in rainfall is sensitive to SHEAR with the nature of sensitivity differing depending upon the PW. Since CAPE and PW cannot be perturbed independently, we test their combined influence using an ensemble of thunderstorm simulations initialized with environmental conditions for the Northeast and Southeast US. These simulations, which begin with identical Hg(II) concentrations, predict higher mercury concentrations in rainfall from thunderstorms forming in the environmental conditions over the Southeast US compared to the Northeast US. A final simulation of a stratiform rain event produces lower mercury concentrations than in thunderstorms forming in environments typical of the Southeast US. The stratiform cloud scavenges mercury from the lowest ~ 4 km of the atmosphere, while thunderstorms scavenge up to ~ 10 km
Infinite ergodic theory and Non-extensive entropies
We bring into account a series of result in the infinite ergodic theory that
we believe that they are relevant to the theory of non-extensive entropie
The Importance of Correlations and Fluctuations on the Initial Source Eccentricity in High-Energy Nucleus-Nucleus Collisions
In this paper, we investigate various ways of defining the initial source
eccentricity using the Monte Carlo Glauber (MCG) approach. In particular, we
examine the participant eccentricity, which quantifies the eccentricity of the
initial source shape by the major axes of the ellipse formed by the interaction
points of the participating nucleons. We show that reasonable variation of the
density parameters in the Glauber calculation, as well as variations in how
matter production is modeled, do not significantly modify the already
established behavior of the participant eccentricity as a function of collision
centrality. Focusing on event-by-event fluctuations and correlations of the
distributions of participating nucleons we demonstrate that, depending on the
achieved event-plane resolution, fluctuations in the elliptic flow magnitude
lead to most measurements being sensitive to the root-mean-square, rather
than the mean of the distribution. Neglecting correlations among
participants, we derive analytical expressions for the participant eccentricity
cumulants as a function of the number of participating nucleons,
\Npart,keeping non-negligible contributions up to \ordof{1/\Npart^3}. We
find that the derived expressions yield the same results as obtained from
mixed-event MCG calculations which remove the correlations stemming from the
nuclear collision process. Most importantly, we conclude from the comparison
with MCG calculations that the fourth order participant eccentricity cumulant
does not approach the spatial anisotropy obtained assuming a smooth nuclear
matter distribution. In particular, for the Cu+Cu system, these quantities
deviate from each other by almost a factor of two over a wide range in
centrality.Comment: 18 pages, 10 figures, submitted to PR
Universities and community-based research in developing countries: community voice and educational provision in rural Tanzania
The main focus of recent research on the community engagement role of universities has been in developed countries, generally in towns and cities and usually conducted from the perspectives of universities rather than the communities with which they engage. The purpose of this paper is to investigate the community engagement role of universities in the rural areas of developing countries, and its potential for strengthening the voice of rural communities. The particular focus is on the provision of primary and secondary education. The paper is based on the assumption that in order for community members to have both the capacity and the confidence to engage in political discourse for improving educational capacity and quality, they need the opportunity to become involved and well-versed in the options available, beyond their own experience. Particular attention is given in the paper to community-based research (CBR). CBR is explored from the perspectives of community members and local leaders in the government-community partnerships which have responsibility for the provision of primary and secondary education in rural Tanzania. The historical and policy background of the partnerships, together with findings from two case studies, provide the context for the paper
Cancer symptom awareness and barriers to symptomatic presentation in England – Are we clear on cancer?
Background: Low cancer awareness may contribute to delayed diagnosis and poor cancer survival. We aimed to quantify socio-demographic differences in cancer symptom awareness and barriers to symptomatic presentation in the English population.
Methods: Using a uniquely large data set (n=49?270), we examined the association of cancer symptom awareness and barriers to presentation with age, gender, marital status and socio-economic position (SEP), using logistic regression models to control for confounders.
Results: The youngest and oldest, the single and participants with the lowest SEP recognised the fewest cancer symptoms, and reported most barriers to presentation. Recognition of nine common cancer symptoms was significantly lower, and embarrassment, fear and difficulties in arranging transport to the doctor’s surgery were significantly more common in participants living in the most deprived areas than in the most affluent areas. Women were significantly more likely than men to both recognise common cancer symptoms and to report barriers. Women were much more likely compared with men to report that fear would put them off from going to the doctor.
Conclusions: Large and robust socio-demographic differences in recognition of some cancer symptoms, and perception of some barriers to presentation, highlight the need for targeted campaigns to encourage early presentation and improve cancer outcomes
A New Class of Changing-Look LINERs
We report the discovery of six active galactic nuclei (AGN) caught "turning
on" during the first nine months of the Zwicky Transient Facility (ZTF) survey.
The host galaxies were classified as LINERs by weak narrow forbidden line
emission in their archival SDSS spectra, and detected by ZTF as nuclear
transients. In five of the cases, we found via follow-up spectroscopy that they
had transformed into broad-line AGN, reminiscent of the changing-look LINER
iPTF 16bco. In one case, ZTF18aajupnt/AT2018dyk, follow-up HST UV and
ground-based optical spectra revealed the transformation into a narrow-line
Seyfert 1 (NLS1) with strong [Fe VII, X, XIV] and He II 4686 coronal lines.
Swift monitoring observations of this source reveal bright UV emission that
tracks the optical flare, accompanied by a luminous soft X-ray flare that peaks
~60 days later. Spitzer follow-up observations also detect a luminous
mid-infrared flare implying a large covering fraction of dust. Archival light
curves of the entire sample from CRTS, ATLAS, and ASAS-SN constrain the onset
of the optical nuclear flaring from a prolonged quiescent state. Here we
present the systematic selection and follow-up of this new class of
changing-look LINERs, compare their properties to previously reported
changing-look Seyfert galaxies, and conclude that they are a unique class of
transients well-suited to test the uncertain physical processes associated with
the LINER accretion state.Comment: Submitted to ApJ, 31 pages, 17 Figures (excluding Appendix due to
file size constraints but will be available in electronic version
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Sulfur K-Edge XAS and DFT Calculations on [Fe4S4]2+Clusters: Effects of H-bonding and Structural Distortion on Covalency and SpinTopology
Sulfur K-edge X-ray absorption spectroscopy of a hydrogen-bonded elongated [Fe{sub 4}S{sub 4}]{sup 2+} cube is reported. The data show that this synthetic cube is less covalent than a normal compressed cube with no hydrogen bonding. DFT calculations reveal that the observed difference in electronic structure has significant contributions from both the cluster distortion and from hydrogen bonding. The elongated and compressed Fe{sub 4}S{sub 4} structures are found to have different spin topologies (i.e., orientation of the delocalized Fe{sub 2}S{sub 2} subclusters which are antiferromagnetically coupled to each other). It is suggested that the H-bonding interaction with the counterion does not contribute to the cluster elongation. A magneto-structural correlation is developed for the Fe{sub 4}S{sub 4} cube that is used to identify the redoxactive Fe{sub 2}S{sub 2} subclusters in active sites of HiPIP and ferredoxin proteins involving these clusters
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