Charge transfer complexes and radical cation salts of chiral methylated organosulfur donors

The single crystal X-ray structure of the all-axial conformer of the (R,R,R,R) enantiomer of the chiral donor tetramethyl-BEDT-TTF (TM-BEDT-TTF) was described and compared to the all-equatorial conformer. (S,S,S,S)-Tetramethyl-BEDT-TTF formed crystalline 1 : 1 complexes with TCNQ and TCNQ-F4, as well as a THF solvate of the TCNQ complex. Donors bis((2S,4S)-pentane-2,4-dithio)tetrathiafulvalene and (ethylenedithio)((2S,4S)-pentane-2,4-dithio)tetrathiafulvalene, which contain seven-membered rings bearing chirally oriented methyl groups, only formed complexes with TCNQ-F4. The TCNQ-F4 complexes contain planar organosulfur systems, in contrast to the TCNQ complexes in which there is minimal charge transfer. A variety of crystal packing modes were observed. Electrocrystallization experiments with both enantiomers and the racemic form of tetramethyl-BEDT-TTF afforded mixed valence radical cation salts with the AsF6 and SbF6 anions formulated as (TM-BEDT-TTF)2XF6 (X = As, Sb). Electrical conductivity was only found in one charge transfer complex, while the radical cation salts are all semiconducting

Synthesis of new chiral organosulfur donors with hydrogen bonding functionality and their first charge transfer salts

The syntheses of a range of enantiopure organosulfur donors with hydrogen bonding groups are described including TTF related materials with two, four, six and eight hydroxyl groups and multiple stereogenic centres and a pair of chiral N-substituted BEDT-TTF acetamides. Three charge transfer salts of enantiopure poly-hydroxy-substituted donors are reported, including a 4:1 salt with the meso stereoisomer of the dinuclear [Fe2(oxalate)5 ]4- anion in which both cation and anion have chiral components linked together by hydrogen bonding, and a semiconducting salt with triiodide

Spatial interference of coherent atomic waves by manipulation of the internal quantum state

A trapped 87Rb Bose-Einstein condensate is initially put into a superposition of two internal states. Under the effect of gravity and by means of a second transition, we prepare two vertically displaced condensates in the same internal state. These constitute two coherent sources of matter waves with adjustable spatial separation. Fringe patterns, observed after free expansion, are associated with the interplay between internal and external degrees of freedom and substantially agree with those for a double slit experiment

Quantum Revivals in Periodically Driven Systems close to nonlinear resonance

We calculate the quantum revival time for a wave-packet initially well localized in a one-dimensional potential in the presence of an external periodic modulating field. The dependence of the revival time on various parameters of the driven system is shown analytically. As an example of application of our approach, we compare the analytically obtained values of the revival time for various modulation strengths with the numerically computed ones in the case of a driven gravitational cavity. We show that they are in very good agreement.Comment: 14 pages, 1 figur

Doppler cooling and trapping on forbidden transitions

Ultracold atoms at temperatures close to the recoil limit have been achieved by extending Doppler cooling to forbidden transitions. A cloud of ^40Ca atoms has been cooled and trapped to a temperature as low as 6 \mu K by operating a magneto-optical trap on the spin-forbidden intercombination transition. Quenching the long-lived excited state with an additional laser enhanced the scattering rate by a factor of 15, while a high selectivity in velocity was preserved. With this method more than 10% of pre-cooled atoms from a standard magneto-optical trap have been transferred to the ultracold trap. Monte-Carlo simulations of the cooling process are in good agreement with the experiments

The diversity of bioactive proteins in Australian snake venoms

Australian elapid snakes are among the most venomous in the world. Their venoms contain multiple components that target blood hemostasis, neuromuscular signaling, and the cardiovascular system. We describe here a comprehensive approach to separation and identification of the venom proteins from 18 of these snake species, representing nine genera. The venom protein components were separated by two-dimensional PAGE and identified using mass spectrometry and de novo peptide sequencing. The venoms are complex mixtures showing up to 200 protein spots varying in size from 10. These include many proteins identified previously in Australian snake venoms, homologs identified in other snake species, and some novel proteins. In many cases multiple trains of spots were typically observed in the higher molecular mass range (> 20 kDa) (indicative of post-translational modification). Venom proteins and their post-translational modifications were characterized using specific kantibodies, phosphoprotein- and glycoprotein-specific stains, enzymatic digestion, lectin binding, and antivenom reactivity. In the lower molecular weight range, several proteins were identified, but the predominant species were phospholipase A(2) and alpha-neurotoxins, both represented by different sequence variants. The higher molecular weight range contained proteases, nucleotidases, oxidases, and homologs of mammalian coagulation factors. This information together with the identification of several novel proteins (metalloproteinases, vespryns, phospholipase A(2) inhibitors, protein-disulfide isomerase, 5'-nucleotidases, cysteinerich secreted proteins, C-type lectins, and acetylcholinesterases) aids in understanding the lethal mechanisms of elapid snake venoms and represents a valuable resource for future development of novel human therapeutics

Interference of Bose-Einstein condensates in momentum space

We suggest an experiment to investigate the linear superposition of two spatially separated Bose-Einstein condensates. Due to the coherent combination of the two wave functions, the dynamic structure factor, measurable through inelastic photon scattering at high momentum transfer $q$, is predicted to exhibit interference fringes with frequency period $\Delta\nu = q/md$ where $d$ is the distance between the condensates. We show that the coherent configuration corresponds to an eigenstate of the physical observable measured in the experiment and that the relative phase of the condensates is hence created through the measurement process.Comment: 4 pages and 2 eps figure

Enantiopure and racemic radical-cation salts of bis(2’-hydroxylpropylthio)(ethylenedithio)TTF with polyiodide anions

The chiral TTF-based donor molecule bis(2’-hydroxylpropylthio)(ethylenedithio)tetrathiafulvalene (BHPT-EDT-TTF) has produced enantiopure R,R and S,S radical-cation salts with polyiodide anions I3- and I82-. Enantiomorphic 6:6 donor:I3 phases grown from either the R,R or S,S donor are semiconducting with similar activation energies of 0.24-0.30 eV and 0.22-0.23 eV respectively, and contains three unique face-to-face donor pairs whose relative orientation is determined by side chain conformations and hydrogen bonding. Racemic material under the same conditions gave an insulating centrosymmetric phase with R,R and S,S donor cations in a face-to-face pair partnered with an octa-iodide dianion, and with a ca 3:1 disorder between the enantiomers. Enantiopure BHPT-EDT-TTF yielded two further insulating crystalline phases of composition 2:2 with triiodide and 2:1 with octa-iodide

Quantum Revivals in a Periodically Driven Gravitational Cavity

Quantum revivals are investigated for the dynamics of an atom in a driven gravitational cavity. It is demonstrated that the external driving field influences the revival time significantly. Analytical expressions are presented which are based on second order perturbation theory and semiclassical secular theory. These analytical results explain the dependence of the revival time on the characteristic parameters of the problem quantitatively in a simple way. They are in excellent agreement with numerical results

Interference scheme to measure light-induced nonlinearities in Bose-Einstein condensates

Light-induced nonlinear terms in the Gross-Pitaevskii equation arise from the stimulated coherent exchange of photons between two atoms. For atoms in an optical dipole trap this effect depends on the spatial profile of the trapping laser beam. Two different laser beams can induce the same trapping potential but very different nonlinearities. We propose a scheme to measure light-induced nonlinearities which is based on this observation.Comment: 2 figure