1,101 research outputs found
Orbital Degeneracy and Peierls Instability in Triangular Lattice Superconductor IrPtTe
We have studied electronic structure of triangular lattice
IrPtTe superconductor using photoemission spectroscopy and
model calculations. Ir core-level photoemission spectra show that Ir
charge modulation established in the low temperature phase of IrTe
is suppressed by Pt doping. This observation indicates that the suppression of
charge modulation is related to the emergence of superconductivity.
Valence-band photoemission spectra of IrTe suggest that the Ir charge
modulation is accompanied by Ir orbital reconstruction. Based on the
photoemission results and model calculations, we argue that the
orbitally-induced Peierls effect governs the charge and orbital instability in
the IrPtTe.Comment: 5 pages,4 figure
Flocculation phenomenon of a mutant flocculent Saccharomyces cerevisiae strain: Effects of metal ions, sugars, temperature, pH, protein-denaturants and enzyme treatments
The flocculation mechanism of a stable mutant flocculent yeast strain Saccharomyces cerevisiae KRM-1 was quantitatively investigated for potential industrial interest. It was found that the mutant flocculent strain was NewFlo phenotype by means of sugar inhibition test. The flocculation was completely inhibited by treatment with proteinase K, protein-denaturants and carbohydrate modifier. The absence of calcium ions significantly inhibited the flocculation, indicating that Ca2+ was specifically required for flocculation. The flocculation was stable when temperature below 70°C and pH was in the range of 3.0 - 6.0. The flocculation onset of the mutant flocculent strain was in the early stationary growth phase, which coincided with glucose depletion in the batch fermentation for the production of ethanol from kitchen refuse medium. The results are expected to help develop better strategies for the control of mutant flocculent yeast for future large-scale industrial ethanol fermentation
Evaluation of pressed shredded empty fruit bunch (EFB)-palm oil mill effluent (POME) anaerobic sludge based compost using Fourier transform infrared (FTIR) and nuclear magnetic resonance (NMR) analysis
Pressed-shredded empty fruit bunches (EFB) and palm oil mill effluent (POME) anaerobic sludge from a 500 m3 closed anaerobic digester system was utilized for the co-composting treatment. Scanning electron microscopy (SEM) analysis showed that the shredding-pressing treatment on EFB gave better results in removing the debris and silica bodies as compared to only shredding treatment. However, similar characteristics were detected in both physically-treated EFB samples by Fourier transform infrared (FTIR) analysis, mainly in the regions of 900 to 1740 and 2800 to 3400 cm-1. After the anaerobic digestion of fresh raw POME, the protein origin (Amide I) band appeared in the POME anaerobic sludge. Besides, the band intensities at 2925 and 2855 cm-1 which attributed to the composition of fat and lipid was decreased. The maturity of the composting material after 40 days of treatment was detected by the appearance of the nitrate band at 1376 cm-1 and the results corresponded to the final C/N ratio of 12.4. Solid state 13C CP/MAS nuclear magnetic resonance (NMR) was also used to reveal the characteristic changes of pressed-shredded EFB-POME anaerobic sludge based compost.Key words: Empty fruit bunch, palm oil mill effluent, compost
Ground State and Magnetization Process of the Mixture of Bond-Alternating and Uniform S=1/2 Antiferromagnetic Heisenberg Chains
The mixture of bond-alternating and uniform S=1/2 antiferromagnetic
Heisenberg chains is investigated by the density matrix renormalization group
method. The ground state magnetization curve is calculated and the exchange
parameters are determined by fitting to the experimentally measured
magnetization curve of \CuClBr(-pic). The low
field behavior of the magnetization curve and low temperature behavior of the
magnetic susceptibility are found to be sensitive to whether the
bond-alternation pattern (parity) is fixed all over the sample or randomly
distributed. The both quantities are compatible with the numerical results for
the random parity model.Comment: 5 pages, 7 figures. Final and enlarged version accepted for
publication in J. Phys. Soc. Jp
Catalytic activity of graphene-covered non-noble metals governed by proton penetration in electrochemical hydrogen evolution reaction
Antiferromagnetic Heisenberg chains with bond alternation and quenched disorder
We consider S=1/2 antiferromagnetic Heisenberg chains with alternating bonds
and quenched disorder, which represents a theoretical model of the compound
CuCl_{2x}Br_{2(1-x)}(\gamma-{pic})_2. Using a numerical implementation of the
strong disorder renormalization group method we study the low-energy properties
of the system as a function of the concentration, x, and the type of
correlations in the disorder. For perfect correlation of disorder the system is
in the random dimer (Griffiths) phase having a concentration dependent
dynamical exponent. For weak or vanishing disorder correlations the system is
in the random singlet phase, in which the dynamical exponent is formally
infinity. We discuss consequences of our results for the experimentally
measured low-temperature susceptibility of
CuCl_{2x}Br_{2(1-x)}(\gamma-{pic})_2
Effects of palm oil mill effluent (POME) anaerobic sludge from 500 m3 of closed anaerobic methane digested tank on pressed-shredded empty fruit bunch (EFB) composting process
In this study, co-composting of pressed-shredded empty fruit bunches (EFB) and palm oil mill effluent (POME) anaerobic sludge from 500 m3 closed anaerobic methane digested tank was carried out. High nitrogen and nutrients content were observed in the POME anaerobic sludge. The sludge was subjected to the pressed-shredded EFB to accelerate the co-composting treatment. In the present study, changes in the physicochemical characteristics of co-composting process were recorded and evaluated. The cocomposting treatment was completed in a short time within 40 days with a final C/N ratio of 12.4. The co-composting process exhibited a higher temperature (60 - 67°C) in the thermophilic phase followed by curing phase after four weeks of treatment. Meanwhile, pH of the composting pile (8.1 - 8.6) was almost constant during the process and moisture content was reduced from 64.5% (initial treatment) to52.0% (final matured compost). The use of pressed-shredded EFB as a main carbon source and bulking agent contributed to the optimum oxygen level in the composting piles (10 - 15%). The biodegradation of composting materials is shown by the reduction of cellulose (34.0%) and hemicellulose (27.0%) content towards the end of treatment. In addition, considerable amount of nutrients and low level of heavy metals were detected in the final matured compost. It can be concluded that the addition of POME anaerobic sludge into the pressed-shredded EFB composting process could produce acceptable and consistent quality of compost product in a short time
Effect of base–acid properties of the mixtures of water with methanol on the solution enthalpy of selected cyclic ethers in this mixture at 298.15 K
The enthalpies of solution of cyclic ethers: 1,4-
dioxane, 12-crown-4 and 18-crown-6 in the mixture of
water and methanol have been measured within the whole
mole fraction range at T = 298.15 K. Based on the obtained
data, the effect of base–acid properties of water–
methanol mixtures on the solution enthalpy of cyclic ethers
in these mixtures has been analyzed. The solution enthalpy
of cyclic ethers depends on acid properties of water–
methanol mixtures in the range of high and medium water
contents in the mixture. Based on the analysis performed, it
can be assumed that in the mixtures of high methanol
contents, cyclic ethe
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