Nuclear magnetic resonance cryoporometry

Nuclear Magnetic Resonance (NMR) cryoporometry is a technique for non-destructively determining pore size distributions in porous media through the observation of the depressed melting point of a confined liquid. It is suitable for measuring pore diameters in the range 2 nm-1 mu m, depending on the absorbate. Whilst NMR cryoporometry is a perturbative measurement, the results are independent of spin interactions at the pore surface and so can offer direct measurements of pore volume as a function of pore diameter. Pore size distributions obtained with NMR cryoporometry have been shown to compare favourably with those from other methods such as gas adsorption, DSC thermoporosimetry, and SANS. The applications of NMR cryoporometry include studies of silica gels, bones, cements, rocks and many other porous materials. It is also possible to adapt the basic experiment to provide structural resolution in spatially-dependent pore size distributions, or behavioural information about the confined liquid

Characterisation of porous solids using small-angle scattering and NMR cryoporometry

The characteristics of several porous systems have been studied by the use of small-angle neutron scattering [SANS] and nuclear magnetic resonance [NMR] techniques. The measurements reveal different characteristics for sol-gel silicas, activated carbons and ordered mesoporous silicas of the MCM and SBA type. Good agreement is obtained between gas adsorption measurements and the NMR and SANS results for pore sizes above 10 nm. Recent measurements of the water/ice phase transformation in SBA silicas by neutron diffraction are also presented and indicate a complex relationship that will require more detailed treatment in terms of the possible effects of microporosity in the silica substrate. The complementarity of the different methods is emphasised and there is brief discussion of issues related to possible future developments

Thermal buckling of a free circular plate

The buckling of a free circular plate subjected to a temperature field, which varies only in the radial direction, is considered. The problem is first investigated experimentally and the mode of deflection and form of the temperature distribution are measured. Expressions are developed for the thermal stresses and the deflection mode of the plate, which are used for a theoretical small deflection energy analysis. This solution is found to compare favourably with the experimental results

Thermal buckling of a free circular plate

The buckling of a free circular plate subjected to a temperature field, which varies only in the radial direction, is considered. The problem is first investigated experimentally and the mode of deflection and form of the temperature distribution are measured. Expressions are developed for the thermal stresses and the deflection mode of the plate, which are used for a theoretical small deflection energy analysis. This solution is found to compare favourably with the experimental results

Clathrate formation and dissociation in vapor/water/ice/hydrate systems in SBA-15, sol-gel and CPG porous media, as probed by NMR relaxation, novel protocol NMR cryoporometry, neutron scattering and ab initio quantum-mechanical molecular dynamics simulation

The Gibbs-Thomson effect modifies the pressure and temperature at which clathrates occur, hence altering the depth at which they occur in the seabed. Nuclear magnetic resonance (NMR) measurements as a function of temperature are being conducted for water/ice/ hydrate systems in a range of pore geometries, including templated SBA-15 silicas, controlled pore glasses and sol-gel silicas. Rotator-phase plastic ice is shown to be present in confined geometry, and bulk tetrahydrofuran hydrate is also shown to probably have a rotator phase. A novel NMR cryoporometry protocol, which probes both melting and freezing events while avoiding the usual problem of supercooling for the freezing event, has been developed. This enables a detailed probing of the system for a given pore size and geometry and the exploration of differences between hydrate formation and dissociation processes inside pores. These process differences have an important effect on the environment, as they impact on the ability of a marine hydrate system to re-form once warmed above a critical temperature. Ab initio quantum-mechanical molecular dynamics calculations are also being employed to probe the dynamics of liquids in pores at nanometric dimensions

The anomalous abundance of cosmic ray nitrogen and oxygen nuclei at low energies

Recent measurements using a cosmic ray telescope on the Pioneer 10 spacecraft have revealed an anomalous spectrum of nitrogen and oxygen nuclei relative to other nuclei such as He and C, in the energy range 3-30 MeV/nuc. The intensity of nitrogen and oxygen nuclei is enhanced by a factor of up to 20 relative to their abundance in galactic or solar cosmic rays

Interplanetary MeV electrons of Jovian origin

Observations of low energy electron increases observed in interplanetary space on Pioneer 10 are reported as it approached Jupiter. These discrete bursts were several hundred times the normal quiet-time electron flux, and became more frequent as one approached Jupiter resulting in the quasi-continuous presence of large fluxes of these electrons in interplanetary space. It is noted that the integrated flux from quiet-time electrons is comparable to the integrated ambient electron flux itself. In addition, the spectrum of electrons observed in Jupiter's magnetosphere, on Pioneer 10 in interplanetary space near Jupiter, for the quiet-time increases near the earth, and for the ambient electron spectrum are all remarkably similar. These two lines of evidence suggest the possibility that Jupiter could be the source of most of the ambient electrons at low energies

Jovian protons and electrons: Pioneer 11

A preliminary account of the Pioneer 11 passage through the Jovian magnetosphere as viewed by particle detector systems is presented. Emphasis is placed on the region well within the Jovian magnetosphere using data from the LET-II telescope, which measured the proton flux from 0.2 to 21.2 MeV in seven energy intervals and electrons from 0.1 to 2 MeV in four energy intervals. The relative trajectories of Pioneer 10 and 11 are discussed and indicate that Pioneer 11 was exposed to a much lower total radiation dose than Pioneer 10, largely as a result of the retrograde trajectory which approached and exited the inner region of the magnetosphere at high latitudes. Angular distributions, calculations from Pioneer 11 magnetic field data, and the low-energy nucleon component are included in the discussion

The interplanetary acceleration of energetic nucleons

Co-rotating proton and electron streams are the dominant type of low-energy (0.1-10 MeV/nucleon) particle event observed at 1 A.U. The radial dependence of these events was studied between 1 and 4.6 A.U. using essentially identical low-energy detector systems on IMP 7, Pioneer 10 and Pioneer 11. It was expected that at a given energy, the intensity of these streams would decrease rapidly with heliocentric distance due to the effects of interplanetary adiabatic deceleration. Instead it was found that from event to event the intensity either remains roughly constant or increases significantly (more than an order of magnitude) between 1 and 3 A.U. It appears that interplanetary acceleration processes are the most plausible explanation. Several possible acceleration models are explored

Measurement of the fluxes of galactic cosmic ray H-2 and He-3 in 1972 - 1973

If a nearby source of low-energy helium is present, which has traversed a relatively small amount of matter and thus has not caused the production of a significant amount of H-2 or He-3, then these abundance ratios will be suppressed, particularly at low energies. This seems to be the most likely explanation for low ratios