406 research outputs found
Oxygen enhanced atomic chain formation
We report experimental evidence for atomic chain formation during stretching
of atomic-sized contacts for gold and silver, that is strongly enhanced due to
oxygen incorporation. While gold has been known for its tendency to form atomic
chains, for silver this is only observed in the presence of oxygen. With oxygen
the silver chains are as long as those for gold, but the conductance drops with
chain length to about 0.1 conductance quantum. A relation is suggested with
previous work on surface reconstructions for silver (110) surfaces after
chemisorption of oxygen.Comment: 4 pages, 4 figure
Vibrationally Induced Two-Level Systems in Single-Molecule Junctions
Single-molecule junctions are found to show anomalous spikes in dI/dV
spectra. The position in energy of the spikes are related to local vibration
mode energies. A model of vibrationally induced two-level systems reproduces
the data very well. This mechanism is expected to be quite general for
single-molecule junctions. It acts as an intrinsic amplification mechanism for
local vibration mode features and may be exploited as a new spectroscopic tool.Comment: 4 pages, 4 figure
Formation and properties of metal-oxygen atomic chains
Suspended chains consisting of single noble metal and oxygen atoms have been
formed. We provide evidence that oxygen can react with and be incorporated into
metallic one-dimensional atomic chains. Oxygen incorporation reinforces the
linear bonds in the chain, which facilitates the creation of longer atomic
chains. The mechanical and electrical properties of these diatomic chains have
been investigated by determining local vibration modes of the chain and by
measuring the dependence of the average chain-conductance on the length of the
chain. Additionally, we have performed calculations that give insight in the
physical mechanism of the oxygen-induced strengthening of the linear bonds and
the conductance of the metal-oxygen chains.Comment: 10 pages, 9 fig
Dynamics of hard-sphere suspension using Dynamic Light Scattering and X-Ray Photon Correlation Spectroscopy: dynamics and scaling of the Intermediate Scattering Function
Intermediate Scattering Functions (ISF's) are measured for colloidal hard
sphere systems using both Dynamic Light Scattering (DLS) and X-ray Photon
Correlation Spectroscopy (XPCS). We compare the techniques, and discuss the
advantages and disadvantages of each. Both techniques agree in the overlapping
range of scattering vectors. We investigate the scaling behaviour found by
Segre and Pusey [1] but challenged by Lurio et al. [2]. We observe a scaling
behaviour over several decades in time but not in the long time regime.
Moreover, we do not observe long time diffusive regimes at scattering vectors
away from the peak of the structure factor and so question the existence of a
long time diffusion coefficients at these scattering vectors.Comment: 21 pages, 11 figure
Electrical control of spin dynamics in finite one-dimensional systems
We investigate the possibility of the electrical control of spin transfer in
monoatomic chains incorporating spin-impurities. Our theoretical framework is
the mixed quantum-classical (Ehrenfest) description of the spin dynamics, in
the spirit of the s-d-model, where the itinerant electrons are described by a
tight-binding model while localized spins are treated classically. Our main
focus is on the dynamical exchange interaction between two well-separated
spins. This can be quantified by the transfer of excitations in the form of
transverse spin oscillations. We systematically study the effect of an
electrostatic gate bias V_g on the interconnecting channel and we map out the
long-range dynamical spin transfer as a function of V_g. We identify regions of
V_g giving rise to significant amplification of the spin transmission at low
frequencies and relate this to the electronic structure of the channel.Comment: 9 pages, 11 figure
Stationary quantum Markov process for the Wigner function
As a stochastic model for quantum mechanics we present a stationary quantum
Markov process for the time evolution of the Wigner function on a lattice phase
space Z_N x Z_N with N odd. By introducing a phase factor extension to the
phase space, each particle can be treated independently. This is an improvement
on earlier methods that require the whole distribution function to determine
the evolution of a constituent particle. The process has branching and
vanishing points, though a finite time interval can be maintained between the
branchings. The procedure to perform a simulation using the process is
presented.Comment: 12 pages, no figures; replaced with version accepted for publication
in J. Phys. A, title changed, an example adde
Roughening Induced Deconstruction in (100) Facets of CsCl Type Crystals
The staggered 6-vertex model describes the competition between surface
roughening and reconstruction in (100) facets of CsCl type crystals. Its phase
diagram does not have the expected generic structure, due to the presence of a
fully-packed loop-gas line. We prove that the reconstruction and roughening
transitions cannot cross nor merge with this loop-gas line if these degrees of
freedom interact weakly. However, our numerical finite size scaling analysis
shows that the two critical lines merge along the loop-gas line, with strong
coupling scaling properties. The central charge is much larger than 1.5 and
roughening takes place at a surface roughness much larger than the conventional
universal value. It seems that additional fluctuations become critical
simultaneously.Comment: 31 pages, 9 figure
Time-dependent embedding: surface electron emission
An embedding method for solving the time-dependent Schr\"odinger equation is
developed using the Dirac-Frenkel variational principle. Embedding allows the
time-evolution of the wavefunction to be calculated explicitly in a limited
region of space, the region of physical interest, the embedding potential
ensuring that the wavefunction satisfies the correct boundary conditions for
matching on to the rest of the system. This is applied to a study of the
excitation of electrons at a metal surface, represented by a one-dimensional
model potential for Cu(111). Time-dependent embedding potentials are derived
for replacing the bulk substrate, and the image potential and vacuum region
outside the surface, so that the calculation of electron excitation by a
surface perturbation can be restricted to the surface itself. The excitation of
the Shockley surface state and a continuum bulk state is studied, and the
time-structure of the resulting currents analysed. Non-linear effects and the
time taken for the current to arrive outside the surface are discussed. The
method shows a clear distinction between emission from the localized surface
state, where the charge is steadily depleted, and the extended continuum state
where the current emitted into the vacuum is compensated by current approaching
the surface from the bulk.Comment: 15 figure
Weak Randomness for large q-State Potts models in Two Dimensions
We have studied the effect of weak randomness on q-state Potts models for q >
4 by measuring the central charges of these models using transfer matrix
methods. We obtain a set of new values for the central charges and then show
that some of these values are related to one another by a factorization law.Comment: 8 pages, Latex, no figure
The molecular signature of highly conductive metal-molecule-metal junctions
The simplicity of single-molecule junctions based on direct bonding of a
small molecule between two metallic electrodes make them an ideal system for
the study of fundamental questions related to molecular electronics. Here we
study the conductance properties of six different molecules suspended between
Pt electrodes. All the molecular junctions show a typical conductance of about
1G0 which is ascribed to the dominant role of the Pt contacts. However, despite
the metallic-like conductivity, the individual molecular signature is
well-expressed by the effect of molecular vibrations in the inelastic
contribution to the conductance.Comment: 7 pages, 7 figures, 1 table. Related paper: J. Ferrer and V. M.
Garc\'ia-Su\'arez, Phys. Rev. B 80, 085426 (2009
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